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Suzhou kaolin as a FCC catalyst

Published online by Cambridge University Press:  09 July 2018

Shu-Qin Zheng*
Affiliation:
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences, Lanzhou 730000, P.R. China Petrochemical Institute, Lanzhou Petroleum and Chemical Corporation, Lanzhou 730060, P.R. China
Shu-Hong Sun
Affiliation:
Petrochemical Institute, Lanzhou Petroleum and Chemical Corporation, Lanzhou 730060, P.R. China
Zhi-Feng Wang
Affiliation:
Petrochemical Institute, Lanzhou Petroleum and Chemical Corporation, Lanzhou 730060, P.R. China
Xiong-Hou Gao
Affiliation:
Petrochemical Institute, Lanzhou Petroleum and Chemical Corporation, Lanzhou 730060, P.R. China
Xian-Lun Xu
Affiliation:
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences, Lanzhou 730000, P.R. China

Abstract

The chemical and mineralogical compositions, the pore-diameter distribution, and the X-ray diffraction, scanning electron microscopy, thermogravimetric analysis and infrared spectroscopy of kaolin from Suzhou, China, and the physicochemical and catalytic properties of a catalyst prepared from that kaolin, are presented in this paper. Crystallized microspheres (CMR) containing ~30% NaY zeolite can be prepared from the Suzhou kaolin. The catalyst produced performs better than a standard commercial catalyst in terms of activity, attrition resistance, resistance to passivation by Ni and V and better gasoline and coke selectivity.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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References

Alfonse, M. (1994) Advanced FCC Catalyst Matrix Technology for Reduced Coke and Slurry Yields, USA. NPRA Annual Meeting. pp. 1-7.Google Scholar
Barrer, R.M. (1978) Zeolites and Clay Minerals as Sorbents and Molecular Sieves. Academic Press, London, pp. 23-44.Google Scholar
Breck, D.W. (1974) Zeolites: Molecular Sieves - Structure, Chemistry and User. John Wiley & Sons Inc., New York, pp. 313-320, 731-738.Google Scholar
Drag, E.B., Miecznikowski, A., Abo-Lemon, F. & Rutkowski, M. (1985) Synthesis of A, X, Y Zeolite from Clay Minerals. Zeolite-Synthesis, Structure, Technology and Applicatio. (B. Brzaj, S. Hocevar & S. Pejovnik, editors). Elsevier, Amsterdam-Oxford-New York-Tokyo, pp. 147-154.Google Scholar
Mitchell, B.R. (1980) Metal contamination of cracking catalysts 1. Synthetic metals deposition on fresh catalysts. Industrial & Engineering Chemistry Product Research and Development. 19, 209213.Google Scholar
Newman, A.C.D. (1987) Chemistry of Clays and Clay Minerals. Monograph 6, Mineralogical Society, London, pp. 22-26.Google Scholar
Rocha, J. & Klinowski, J. (1990) Solid State NMR Studies of the Structure and Reactivity of Metakaolinite. Angewante Chemie International, English edition, 29, 553-554.Google Scholar
Sun, S.-H., Zheng, S.-Q., Wang, Z.-F., Zhang, Y.-H. and Ma, J.-T. (2005) Sulphur reduction additive prepared from caustic-modified kaolin. Clay Minerals. 40, 311316 Google Scholar
Zhang, X.Q. (1988) Kaolin. Light Industry Publishing Company, Beijing, China, pp. 10–15.Google Scholar
Zhang, Y.M., Tang, R.R., Liu, H.H., Zheng, S.Q & Shen, J.H. (1995) The preparation and characterization of novel type of FCC catalysts. Journal of Molecular Catalysis (China). 9, 424434.Google Scholar
Zhang, Y.M., Tang, R.R., Zheng, S.Q & Liu, H.H. (1997) Relation between crystalline structure of kaolin and the performance of its in-situ crystallization cracking catalyst. Petroleum Processing and Petrochemicals (China). 28, 5156.Google Scholar