Polymeric nanostructures can be synthesized where the catalytic motif is covalently attached within the core domain and protected from the environment by a polymeric shell. Such nanoreactors can be easily recycled, and have shown unique properties when catalyzing reactions under pseudohomogeneous conditions. Many examples of how these catalytic nanostructures can act as nanosized reaction vessels have been reported in the literature. This prospective will focus on the exclusive features observed for these catalytic systems and highlight their potential as enzyme mimics, as well as the importance of further studies to unveil their full potential.

The Cu precipitation in a quench-aged high-strength low-alloy steel is studied at the atomic scale by atom probe tomography and high-resolution transmission electron microscopy. The results indicate that the Cu precipitates greatly correlate with carbides in the aspect of distributional character, i.e., the two phases are prone to coprecipitate on the dislocations and/or interfaces (low angle boundaries of the martensite laths). The crystallographic defects have a significant effect on the sizes, morphology and composition of Cu precipitates with Ni and Mn segregation shell.

Recently, we reported on the facile synthesis of a number of two-dimensional early transition metal carbides and nitrides, derived from the MAX phases, that we labeled MXenes. Herein, we report on the electronic and elastic properties—investigated by first principles calculations utilizing the generalized gradient approximation within the density functional theory—of the following two-dimensional transition metal carbides: Ti2C, Ti3C2, Ti4C3, V2C, Cr2C, Zr2C, Hf2C, and Ta2C, Ta3C2, and Ta4C3. Similar to the MAX phases, the MXenes are found to be metallic and possess high elastic moduli when stretched along the basal planes.

Intrinsic energy resolution in γ-radiation detectors is limited by nonlinear quenching that varies as the second or third power of local excitation density. Using a numerical model for local light yield depending on measured quenching rates, kinetic order, and carrier mobilities, we employ Monte Carlo simulations of energy deposited at each local excitation density to calculate electron energy response that can be directly compared with Compton coincidence and K-dip experiments. Agreement is found for NaI:Tl and SrI2:Eu using thermalized carrier diffusion and linear quenched fraction deduced from total light yield. This lays the groundwork for testing refinements with recent hot-electron extensions of the model.

Silver nanoparticle inks printed on temperature-sensitive substrates can be converted into structures with high electrical conductivities within fractions of a second by photonic flash sintering. The key principle is the selective heating of the ink by the absorption of strongly focused pulsed light for which the substrate is transparent. The influence of process parameters like intensity and flashing frequency on the sintering speed is investigated. Furthermore, a setup is demonstrated for monitoring the temperature development in an ink during flash sintering, revealing that the substrate's glass transition point is exceeded only for very short time intervals, which prevents deformation.

Development of universal biosensors based on electrical readout is currently limited by the difficulty of electrical signal transduction upon capture of neutral analytes. Kelley and co-workers demonstrate an elegant approach wherein an amplified electrical current flows to a multiplexed electrode array in proportion with the binding of nucleic acids, proteins, and small molecules—regardless of their inherent charge. Here we present a commentary on the strengths and limitations of this method.