Thermodynamics deals with energy levels and the transfer of energy between states of matter, and is therefore fundamental to all branches of science. This new edition is specifically tailored to the interests of the Earth sciences, and emphasizes throughout the use of thermodynamics to construct mathematical simulations of real systems. Many computer programs are mentioned and used throughout the text, especially SUPCRT92, a widely used source of thermodynamic data. An associated website includes links to useful information sites, computer programs and problem sets.
Contents
Preface; 1. What is thermodynamics?; 2. Defining our terms; 3. The first law of thermodynamics; 4. The second law of thermodynamics; 5. Getting data; 6. Some simple applications; 7. Ideal solutions; 8. Fugacity and activity; 9. The equilibrium constant; 10. Real solutions; 11. The phase rule; 12. Redox reactions; 13. Equations of state; 14. Solid solutions; 15. Electrolyte solutions; 16. Rock-water systems; 17. Phase diagrams; 18. Process modelling; Appendices; References; Index.

