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LECTURE XVII

Published online by Cambridge University Press:  05 March 2012

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Summary

Molecular

§ 23. Hitherto in all our views we have seen nothing of absolute dimensions in molecular structure, and have been satisfied to consider the distance between neighbouring molecules in gases, or liquids, or crystals, or non-crystalline solids to be very small in comparison with the shortest wave-length of light with which we have been concerned. Even in respect to dispersion, that is to say, difference of propagational velocity for different wave-lengths, it has not been necessary for us to accept Cauchy's doctrine that the spheres of molecular action are comparable with the wavelength. We have seen that dispersion can be, and probably in fact is, truly explained by the periods of our waves of light being not infinitely great in comparison with some of the periods of molecular vibration; and, with this view, the dimensions of molecular structure might, so far as dispersion is concerned, be as small as we please to imagine them, in comparison with wavelengths of light. Nevertheless it is exceedingly interesting and important for intelligent study of molecular structures and the dynamics of light, to have some well-founded understanding in respect to probable distances between centres of neighbouring molecules in all kinds of ponderable matter, while for the present at all events we regard ether as utterly continuous and structureless. It may be found in some future time that ether too has a molecular structure, perhaps much finer than any structure of ponderable matter; but at present we neither see nor imagine any reason for believing ether to be other than continuous and homogeneous through infinitely small contiguous portions of space void of other matter than ether.

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Publisher: Cambridge University Press
Print publication year: 2010
First published in: 1904

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  • LECTURE XVII
  • William Thomson, Baron Kelvin
  • Book: Baltimore Lectures on Molecular Dynamics and the Wave Theory of Light
  • Online publication: 05 March 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511694523.021
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  • LECTURE XVII
  • William Thomson, Baron Kelvin
  • Book: Baltimore Lectures on Molecular Dynamics and the Wave Theory of Light
  • Online publication: 05 March 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511694523.021
Available formats
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Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • LECTURE XVII
  • William Thomson, Baron Kelvin
  • Book: Baltimore Lectures on Molecular Dynamics and the Wave Theory of Light
  • Online publication: 05 March 2012
  • Chapter DOI: https://doi.org/10.1017/CBO9780511694523.021
Available formats
×