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Advances in High-Resolution Studies of the Chemical Effects in the Molybdenum L Heavy-Ion-Induced X-Ray Satellite Emission (HIXSE) Spectra*

Published online by Cambridge University Press:  06 March 2019

T. M. Rosseel ,
J. M. Dale ,
L. D. Hulett ,
P. L. Pepmiller ,
C. R. Vane ,
T. A. Walkiewicz  and
J. P. Young
T. M. Rosseel
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
J. M. Dale
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
L. D. Hulett
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
P. L. Pepmiller
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
C. R. Vane
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
T. A. Walkiewicz
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
J. P. Young
Affiliation:
Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831
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Abstract

High-resolution measurements of the molybdenum L heavy-ion-induced X-ray satellite emission (HIXSE) spectra of a series of Mo alloys and compounds have been obtained with a new, high-efficiency, high-resolution Bragg crystal spectrometer in the von Hamos geometry. The improved resolution (5 eV at 2.3 keV) is sufficient to reveal the LnMm configuration lines in the Lα and Lβ hypersatellite bands. Both sets of lines exhibit the same trend in the variation of the relative yield distribution with the chemical environment as was observed for KLn lines of lower Z targets. Difference spectra, using elemental molybdenum as a subtrahend, enhance the systematic variation. These results confirm the analysis and conclusions of lower resolution studies. They also indicate a potential for even greater sensitivity to the chemical environment.

Type
V. XRF Applications; Fuels and Lubricants, Metals and Alloys, Geological, Heavy Element, Other
Information
Advances in X-Ray Analysis , Volume 30: Thirty-Fifth Annual Conference on Applications of X-ray Analysis, August 4-8, 1986 , 1986 , pp. 257 - 264
Copyright
Copyright © International Centre for Diffraction Data 1986

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Footnotes

**

Visitor from Edinboro State College, PA.

*

Research sponsored by the U.S. Department of Energy, Office of Energy Research, under contract DE-AC05-840R21400 with Martin Marietta Energy Systems, Inc.

References

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