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Improvement of the Smoothing Procedure Via Preliminary Logarithmic Transformation of the X-Ray Spectrum

Published online by Cambridge University Press:  06 March 2019

Krassimir N. Stoev
Affiliation:
Bulgarian Academy of Sciences Institute of Nuclear Research and Nuclear Energy Blvd. “Trakia” 72, 1784 Sofia, Bulgaria
Joseph E. Dlouhy
Affiliation:
Environment Canada Environment Technology Center 3439 River Road, Ottawa, Ontario K1A 0H3, Canada
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Extract

Spectrum processing is a critical step in energy-dispersive X-ray fluorescence analysis, with very strong influence on the final performance of the method. Spectrum processing includes two major procedures: (i) preliminary processing (which deals mainly with reduction of random and systematic noise); and (ii) evaluation of peak parameters (most often peak area, and in some cases also peak position, amplitude and width). Preliminary processing solves two main problems: (i) search and correction of erroneous channel contents (outlier values); and (ii) random noise reduction. Several procedures for search and correction of outlier values have been proposed for Raman, gamma and X-ray spectra.

Type
IX. XRS Mathematical Methods, Trace Analysis and Other Applications
Copyright
Copyright © International Centre for Diffraction Data 1994

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