The standard addition method is often useful for singleelement analyses in matrices of unknown composition or those difficult to reproduce. Results are good at low concentrations where concentration vs. intensity is approximately linear, but serious errors occur at higher concentrations. A method is shown here for greatly extending the range of the standard addition approach by combining it with with matrix correction models. Expressions incorporating the well-known alpha-or beta-correction coefficients are derived for the observed intensities before and after addition of the analyte. K-ratio measurements on the saraple plus a single standard addition allow the calculation of the correction coefficient and analyte concentration. Several standard addition levels can also be used and concentration obtained from non-linear regression analysis. A computer program has been developed to perform these calculations. Analyses of CuO on silica and of four metals in a metal oxide catalyst over a wide range of concentrations gave results with a relative accuracy generally within ±5%.