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Empirical Approaches for the Treatment of Interelement Effects

Published online by Cambridge University Press:  06 March 2019

K. F. J. Heinrich*
Affiliation:
National Bureau of Standards Washington, D. C. 20234
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Abstract

Empirical algorithms for the treatment of interelement effects in x-ray fluorescence spectrometry are reviewed. It is recommended that the effects of tertiary x-ray emission be treated separately from those of x-ray absorption, and that standard reference materials of composition close to that of the specimen be used.

Type
Mathematical Correction Procedures for X-Ray Spectrochemical Analysis
Copyright
Copyright © International Centre for Diffraction Data 1975

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References

1. Claisse, F. and Samson, C., “Heterogeneity Effects in X-ray Analysis,” in Advances in X-ray Analysis, Vol. 2, University of Denver, Plenum Press, New York, 335354 (1960).Google Scholar
2. Claisse, F., Letter to the Editor, Norelco Reporter, Vol. 4, No. 3, 9596 (1957).Google Scholar
3. Müller, R. O., “Spectrochemical Analysis by X-ray Fluorescence,” Plenum Press, New York (1972).Google Scholar
4. Rasberry, S. D. and Heinrich, K. F. J., “Calibration for Interelement Effects in X-ray Fluorescence Analysis,” Anal. Chem. 46, 8l (1974).Google Scholar
5. Foakes, G. E., “An Absolute Method of X-ray Fluorescence Analysis Applied to Stainless Steels,” American Society for Testing and Materials, Special Technical Publication No. 157s 5762 (1954).Google Scholar
6. Birks, L. S., “X-ray Spectrochemical Analysis,” Inter science Publication, New York and London (1959).Google Scholar
7. Beattie, H. J. and Brissey, R. M., “Calibration Method for X-ray Fluorescence Spectrometry,” Anal.Chem. 36, 980 (1954).Google Scholar
8. Ziebold, T. O. and Ogilvie, R. E., “An Empirical Method for Electron Microanalysis,” Anal. Chem. 36 , 322 (1964).Google Scholar
9. Andrews, E. A., Talk given at the 9th X-ray Anal. Conf., Exeter, U.K., 1974.Google Scholar
10. Claisse, F. and Quintin, M., “Generalization of the Lachance-Traill Method for the Correction of the Matrix Effect in X-ray Fluorescence Analysis,” Can. Spectrose.12 , 129133 (1967).Google Scholar
11. Tertian, R., this volume.Google Scholar
12. Heinrich, K. F. J. and Rasberry, S. D., “X-ray Fluorescence Analysis of High-Temperature Super alloys- Calibration and Standards,” in Advances in X-ray Analysis, Vol. 17, 309 (1974).Google Scholar