A method has been developed for measuring N2O concentrations in the air extracted from the bubbles contained in ice cores. The air extraction is performed by cutting the ice into very small pieces with a rotating knife, in a controlled atmosphere. The N2O concentrations are measured by gas chromatography. The complete original procedure will be discussed, and the results of the different experimental tests given, with a discussion of the uncertainties.

This method has been used to perform about 40 measurements on Antarctic ice samples. Ten air samples from the D57 core date approximately from the beginning of the seventeenth and twentieth centuries. The others were taken from the Dome C core and date from the Holocene and the period around the Last Glacial Maximum. The D57 results are in agreement with those of Pearman and others (1986), leading to a similar pre-industrial N2O level (270-290 ppb volume). Furthermore, our Dome C results suggest that during the Last Glacial Maximum atmospheric N2O content was not drastically different from the recent period.