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Amorphous Clay Minerals in Some Scottish Soil Profiles

Published online by Cambridge University Press:  14 March 2018

B. D. Mitchell
Affiliation:
The Macaulay Institute for Soil Research, Aberdeen
V. C. Farmer
Affiliation:
The Macaulay Institute for Soil Research, Aberdeen
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Abstract

Examination of clays from surface and basal horizons of four Scottish soils by differential thermal analysis, before and after heating to 600°C and by infra-red spectroscopy indicates that these contain a proportion of highly hydrated amorphous material, resembling allophane in its properties, and that this component is particularly high in clays from the surface horizons with the greatest organic matter content. This conclusion is consistent with the cation-exchange capacities of the clays and with the amounts of silica and alumina extractable from them by hot sodium carbonate solutions. The ratio of silica to alumina in these extracts indicates that the amorphous material is highly siliceous.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1962

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References

Birrell, K. S., and Fieldes, M., 1952. J. Soil Sci., 3, 156.CrossRefGoogle Scholar
Brown, G. (editor), 1961. The X-ray Identification of Clay Minerals. Mineralogical Society, London.Google Scholar
De, mumbrum L. E., 1960. Proc. Soil Sci. Soc. Amer., 24, 185.Google Scholar
Duff, R. B., Webley, D. M., and Scott, R. O., 1962. Soil Sei., in Press.Google Scholar
Farmer, V. C., 1958. Miner. Map., 31, 29.Google Scholar
Fieldes, M., 1955. N.Z.J. Sci. Teeh., B37, 336.Google Scholar
Fieldes, M., 1957. N.Z.J. Sci. Tech., B38, 534.Google Scholar
Glenn, R. C., Jackson, M. L., Hole, F. D., and Lee, G. B., 1960. Clays and Clay Minerals (Swineford, A., editor). Pergamon Press, London, p. 63.Google Scholar
Grim, R. E., 1953. Clay Mineralogy. McGraw-Hill, New York.Google Scholar
Hunt, J. M., Wisherd, M. P., and Bonham, L. C., 1950. Analyt. Chem., 22, 1478.CrossRefGoogle Scholar
Ishii, J., and Mori, T., 1959. J. geol. Soc. Japan, 65, 357.Google Scholar
Kanno, J., 1959. Nendokaguku no Shimpo, 1, 213.Google Scholar
Launer, P. J., 1952. ,Amer. Min., 37, 764.Google Scholar
Lovering, T. S., 1959. Bull. geol. Soc. ,Amer., 70, 781.CrossRefGoogle Scholar
Mattson, S., 1931. Soil Sei., 30, 459.Google Scholar
Matsui, T., 1959. Nendokaguku no Shimpo , 1, 244.Google Scholar
Mcdonald, R. S., 1958. J. phys. Chem., 62, 1168.CrossRefGoogle Scholar
Mackenzie, R. C., 1951. J. Colloid Sr 6, 219.Google Scholar
Milkey, R. G., 1960. Amer. Min., 45, 990.Google Scholar
Mitchell, B. D., and Jarvls, R. A., 1956. The Soils of the Country round Kilmarnock. Mem. Soil Surv. Scot., H.M.S.O., Edinburgh.Google Scholar
Mitchell, B. D., and Mackenzie, R. C., 1954. Soil Sei., 77, 173.CrossRefGoogle Scholar
Mitchell, B. D., and Mackenzie, R. C., 1959. Clay Min. Bull., 4, 31.CrossRefGoogle Scholar
Ross, C. S., and Kerr, P. F., 1934. Prof. Pap. U.S. geol. Surv., No. 185-G, p. 135.Google Scholar
Salvetat, L. A., 1851. Ann. Chim. (Phys.), 31, 102.Google Scholar
Svdo, T., 1954. Clay Min. Bull., 2, 96.Google Scholar
White, W. A., 1953. Amer. Min. 38, 634.Google Scholar