Hostname: page-component-5c6d5d7d68-xq9c7 Total loading time: 0 Render date: 2024-08-28T22:54:22.513Z Has data issue: false hasContentIssue false
  • English
  • Français

Ethylene glycol and glycerol complexes of smectites and vermiculites

Published online by Cambridge University Press:  09 July 2018

G. W. Brindley
G. W. Brindley*
Affiliation:
Department of Geochemistry and Mineralogy, Pennsylvania State University, University Park, Pennsylvania
Get access Rights & Permissions [Opens in a new window]

Extract

The complexes formed by ethylene glycol, HOCH2.CH2OH, and by glycerol, HOCH2.CHOH.CH2OH, with smectites (montmorillonite-saponite group), and vermiculites have received more attention than any other group of organo-silicate complexes. This interest arose in the first place from their use for identification purposes as proposed by MacEwan (1944, 1946) and by Bradley (1945b). Over the years, increasing attention has been given to the manner in which these complexes vary with the nature of the mineral, the magnitude and source of the charge on the silicate layers, and the number and kind of the exchangeable cations between the layers. The layer charge is determined most reliably from the full chemical analysis of a mineral, but more commonly is estimated from a measurement of cation exchange capacity.

Type
Invited Review
Information
Clay Minerals , Volume 6 , Issue 4 , December 1966 , pp. 237 - 259
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1966

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barshad, I. (1950) Am. Miner. 35, 225.Google Scholar
Barshad, I. (1952) Proc. Soil Sci. Soc. Am. 16, 176.Google Scholar
Bradley, W.F. (1945a) J. Am. chem. Soc. 67, 975.Google Scholar
Bradley, W.F. (1945b) Am. Miner. 30, 704.Google Scholar
Bradley, W.F., Rowland, R.A.. Weiss, E.J. & Weaver, L.E. (1958) Clays Clay Miner. 5, 348.Google Scholar
Bradley, W.F., Weiss, E.J. & Rowland, R.A. (1963) Clays Clay Miner. 10, 117.Google Scholar
Bower, CA. & Goertzen, J.O. (1959) Soil Sci. 87, 289.Google Scholar
Bower, CA. & Gschwend, F.B. (1952) Proc. Soil Sci. Soc. Am. 16, 342.Google Scholar
Brindley, G.W. (1956) Am. Miner. 41, 91.Google Scholar
Brindley, G.W. & Hoffmann, R.W. (1962) Clays Clay Miner. 9, 546.Google Scholar
Brown, G. (1953) J. Soil Sci. 4, 229.Google Scholar
Brown, G. & Farrow, R. (1956) Clay Miner. Bull. 3, 44.Google Scholar
Brown, G. & Greene-Kelly, R. (1954) Acta crystallogr. 7, 101; 521.Google Scholar
Brunton, G. (1955) Am. Miner. 40, 124.Google Scholar
Brunton, G., Tettenhorst, R. & Beck, C.W. (1963) Clays Clay Miner. 11, 105.Google Scholar
Deeds, C.T. & Van Olphen, H. (1961) Advances in Chemistry Series. No. 33, p. 332. American Chemical Society.Google Scholar
Diamond, S. & Kinter, E.B. (1958) Clays Clay Miner. 5, 334.Google Scholar
Dyal, R.S. & Hendricks, S.B. (1950) Soil Sci. 69, 421.Google Scholar
Dyal, R.S. & Hendricks, S.B. (1952) Proc. Soil Sci. Soc. Am. 16, 45.CrossRefGoogle Scholar
Glaeser, R. (1948) C. r. hebd. Séanc. Acad. Sci., Paris. 226, 935.Google Scholar
Glaeser, R. (1954) Complexes Organo-argileux et Rôle des Cations Echangeables. Thése, Paris.Google Scholar
Glaeser, R. & Mering, J. (1953) Congr. Géol. internal. C.R. 19 ème Session, Alger. 1952, p. 117.Google Scholar
Greene-Kelly, R. (1952) Clay Miner. Bull. 1, 221.Google Scholar
Greene-Kelly, R. (1953) Clay Miner. Bull. 2, 51.Google Scholar
Greene-Kelly, R. (1955a) Mineralog. Mag. 30, 604.Google Scholar
Greene-Kelly, R. (1955b) Trans. Faraday Soc. 51, 412.Google Scholar
Haase, D.J., Weiss, E.J. & Steinfink, H. (1963) Am. Miner. 48, 261.Google Scholar
Harward, M.E. & Brindley, G.W. (1966) Clays Clay Miner. 13, 209.Google Scholar
Heller, L. (1965) 1st Int. Clay Conf. (Rosenqvist, I. Th. and Graff-Petersen, P., editors), Vol. 2, p. 105. Pergamon Press, Oxford.Google Scholar
Hoffmann, R.W. & Brindley, G.W. (1961) Am. Miner. 46, 450.Google Scholar
Hofmann, U. & Klemen, R. (1950) Z. anorg. allg. Chem. 262, 95.Google Scholar
Jackson, M.L. (1964) Soil Clay Mineralogy. (Rich, C. I. & Kunze, G. W., editors,) Chap. VIII, p. 245. University of North Carolina Press.Google Scholar
Kinter, E.B. & Diamond, S. (1958) Clays Clay Miner. 5, 318.Google Scholar
Kunze, G.W. (1955) Clays Clay Miner. 3, 88.Google Scholar
Macewan, D.M.C. (1944) Nature, Lond. 154, 577.Google Scholar
Macewan, D.M.C. (1946) J. Soc. chem. Ind., Lond. 65, 298.Google Scholar
Macewan, D.M.C. (1948) Trans. Faraday Soc. 44, 349.Google Scholar
Macewan, D.M.C. (1961) X-ray Identification and Crystal Structures of Clay Mineral. (Brown, G., editor), p. 143. Mineralogical Society, London.Google Scholar
Mackenzie, R.C. (1948) Trans. Faraday Soc. 44, 368.CrossRefGoogle Scholar
Martin, R.T. (1955) Proc. Soil Sci. Soc. Am. 19, 160.CrossRefGoogle Scholar
Mcneal, B.L. (1964) Soil Sci. 97, 96.Google Scholar
Mehra, O.P. & Jackson, M.L. (1959a) Proc. Soil Sci. Soc. Am. 23, 101.Google Scholar
Mehra, O.P. & Jackson, M.L. (1959b) Proc. Soil Sci. Soc. Am. 23, 351.Google Scholar
Milford, M.H. & Jackson, M.L. (1962) Science, N.Y. 135, 929.Google Scholar
Mortland, M.M. & Kemper, W.D. (1965) Methods of Soil Analysis. Part 1 (Black, C. A., editor-in-chief), Chapter 42, p. 532. American Society of Agronomy, Madison, Wisconsin.Google Scholar
Van Olphen, H. (1965) J .Colloid Sci. 20, 822.Google Scholar
Van Olphen, H. & Deeds, C.T. (1965) Nature Lond. 194, 176.CrossRefGoogle Scholar
Reynolds, R.C. (1965) Am. Miner. 50, 990.Google Scholar
Sor, K. & Kemper, W.D. (1959) Proc. Soil Sci. Soc. Am. 23, 105.Google Scholar
Tettenhorst, R. (1962) Am. Miner. 47, 769.Google Scholar
Tettenhorst, R., Beck, C.W. & Brunton, G. (1962) Clays Clay Miner. 9, 500.Google Scholar
Walker, G.F. (1957) Clay Miner. Bull. 3, 154.Google Scholar
Walker, G.F. (1958) Clay Miner. Bull. 3, 302.Google Scholar
Walker, G.F. (1965) 1st Int. Clay Conf. (Rosenqvist, I. Th. and Graff-Petersen, P., editors), Vol. 2, p. 259. Pergamon Press, Oxford.Google Scholar
Weir, A.H. & Greene-Kelly, R. (1962) Am. Miner. 47, 137.Google Scholar
White, J.L. (1956) Clays Clay Miner. 4, 133.Google Scholar
Woodside, K.H. & Ormsby, W.C. (1960) J. Am. Ceram. Soc. 43, 671.Google Scholar