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Interactions of imidacloprid with organicand inorganic- exchanged smectites

Published online by Cambridge University Press:  09 July 2018

L. Cox ,
M. C. Hermosin ,
W. C. Koskinen  and
J. Cornejo
L. Cox
Affiliation:
Instituto de Recursos Naturales y Agrobiologia de Sevilla, CSIC, Apartado 1052, Sevilla 41080, Spain
M. C. Hermosin*
Affiliation:
Instituto de Recursos Naturales y Agrobiologia de Sevilla, CSIC, Apartado 1052, Sevilla 41080, Spain
W. C. Koskinen
Affiliation:
Soil Water Management Research Unit, ARS-USDA, 1991 Upper Buford Circle, St Paul, Minnesota 55108, USA
*
*E-mail: mchermosin@irnase.csic .es
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Abstract

Sorption of the polar insecticide imidacloprid on organic-saturated octadecylammonium (C18) and dioctadecyldimethylammonium (DOD) and inorganic- (Fe- ) saturated Wyoming (W) and Arizona (A) montmorillonites has been investigated. Sorption isotherms were fitted to the Freundlich equation. Imidacloprid-montmorillonite complexes were studied by X-ray diffraction and FT-IR techniques. Imidacloprid sorption coefficients, Kf, decreased in the order WC18> AC18> WFe> WDOD≥ ADOD. The low layer charge and saturation by primary alkylammonium cation facilitates sorption of imidacloprid in the interlayer of the smectite, corroborated by the increase in basal spacing observed in X-ray diffraction patterns and by the presence of absorption band shifts in FT-IR spectra. Imidacloprid sorbs in the interlayer space of smectite mainly by hydrophobic interactions with the alkyl chains in organic smectites and with the uncharged siloxane surface in Fe(III)-smectite. Further polar bonds between the NO2 group of imidacloprid and the NH of the primary alkyl cations and protonation of imidacloprid in Fe-smectites enhanced sorption in these cases.

Keywords

alkylammonium cationsmontmorillonitesorptiondesorption
Type
Research Article
Information
Clay Minerals , Volume 36 , Issue 2 , June 2001 , pp. 267 - 274
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2001

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References

Aguer, J.P., Hermosín, M.C., Calderón, M.J. & Cornejo, J. (2000) Fenuron sorption on homoionic natural and modified smectites. J. Environ. Sci. Health B, 35, 279–296.Google Scholar
Beck, A.J. , Johnston, A.E.J. & Jones, K.C. (1993) Movement of nonionic organic chemicals in agricultural soils. Crit. Rev. Environ. Sci. Tecnol. 23, 219–248.Google Scholar
Bellamy, L.J (1980) The Infrared Spectra of Complex Molecules, Vol. 1. Chapman & Hall, London and New York.Google Scholar
Carrizosa, M.J., Calderón, M.J., Hermosín, M.C. & Cornejo, J. (2000) Organosmectites as sorbent and carrier of the herbicide bentazone. Sci. Total Environ. 247, 285–293.Google Scholar
Celis, R., Cornejo, J., Hermosín, M.C. & Koskinen, W.C. (1998) Sorption of atrazine and simazine by model associations of soil colloids. Soil Sci. Soc. Am. J. 62, 165–171.Google Scholar
Celis, R., Koskinen, W.C., Hermosín, M.C., Ulibarri, M.A. & Cornejo, J. (2000) Triadimefon interactions with organoclays and organohydrotalcites. Soil Sci. Soc. Am. J. 64, 36–43.Google Scholar
Cox, L. , Hermosín, M.C. & Cornejo, J. (1994) Interactions of methomyl with montmorillonites. Clay Miner. 29, 767–774.Google Scholar
Cox, L., Hermosín, M.C. & Cornejo, J. (1995) Adsorption mechanisms of thiazafluron in mineral soil clay components. Eur. J. Soil Sci. 46, 431–438.Google Scholar
Cox, L., Koskinen, W.C. & Yen, P.Y. (1997) Sorptiondesorption of imidacloprid and its metabolites in soils. J. Agric. Food Chem. 45, 1468–1472.CrossRefGoogle Scholar
Cox, L., Koskinen, W.C. & Yen, P.Y. (1998a) Influence of soil properties on sorption-desorption of imidacloprid. J. Environ. Sci. Health B, 33, 123–134.Google Scholar
Cox, L., Koskinen, W.C., Yen, P.Y., Hermosín, M.C. & Cornejo, J. (1998b) Sorption of imidacloprid on soil clay mineral and organic components. Soil Sci. Soc. Am. J. 62, 911–915.Google Scholar
Cox, L., Celis, R., Hermosín, M.C. & Cornejo, J. (2000) Use of natural soil colloids to retard simazine and 2,4-D leaching in soil. J. Agric. Food Chem. 48, 93–99.Google Scholar
El-Nahhal, Y., Nir, S., Polubesova, T., Margulis, L. & Rubin, B. (1998) Leaching, phytotoxicity, and weed control of new formulations of alachlor. J. Agric. Food Chem. 46, 3305–3313.Google Scholar
González-Pradas, E., Fernández-Pérez, M., Villafranca- Sánchez, M., Martínez-Lópes, F. & Flores-Céspedes, F. (1999) Use of bentonite and humic acid as modifying agents in alginate-based controlled-release formulations of imidacloprid. Pestic. Sci. 55, 546–552.Google Scholar
Hermosín, M.C., Roldán, I. & Cornejo, J. (1991) Maleic hydrazide interaction with soil clay surfaces. Chemosphere, 23, 473–483.Google Scholar
Hermosín, M.C. & Cornejo, J. (1992) Removing 2,4-D from water by organo-clays. Chemosphere, 24, 1493–1503.Google Scholar
Hermosín, M.C. & Cornejo, J. (1993) Binding mechanism of 2,4-dichlorophenoxyacetic acid by organoclays. J. Environ. Qual. 22, 325–331 CrossRefGoogle Scholar
Hermosín, M.C., Aguer, J.P., Cornejo, J. & Calderón, M.J. (1997) A slow-release formulation for herbicides:organoclay- fenuron. 11th Int. Clay Conf. Ottawa, Canada. Abstracts, A36.Google Scholar
Jaynes, W.F. and Boyd, S.A. (1991) Clay mineral type and organic compound sorption by hexadecyltrimethylammonium- exchanged clays. Soil Sci. Soc. Am. J. 55, 43–48.Google Scholar
Lagaly, G. & Weiss, A. (1982) Layer charge heterogeneity in vermiculites. Clays Clay Miner. 30, 215–222.Google Scholar
Margulies, L., Stern, T. & Rubin, B. (1994) Slow release of s-ethyl dipropylcarbamothiote from clay surfaces. J. Agric. Food Chem. 46, 1223–1227.Google Scholar
Park, D.J., Jackson, W.R., McKinnon, I.R. & Marzhall, M. (1999) Controlled release of pesticides from microparticles. Pp. 89–136 in: Controlled -Release Delivery Systems for Pesticides (Scher, H.B., editor). Marcel Dekker Inc., New York.Google Scholar
Wagner, J., Chen, H., Brownawell, B.J. & Westall, J.C. (1994) Use of cationic surfactants to modify soil surfaces to promote sorption and retard migration of hydrophobic organic compounds. Environ. Sci. Technol. 28, 231–237 Google Scholar
Xu, S., Sheng, G. & Boyd, S.A. (1997) Use of organoclays in pollution abatement. Adv. Agron. 59, 25–62.Google Scholar
Yelverton, F.H., Weber, J.B., Peedin, G. & Smith, W.D. (1990) Using activated charcoal to inactivate agricultural chemical spills. AG-442, Agricultural Extension Service North Carolina State University, Raleigh, NC, USA.Google Scholar
Zhao, H., Jaynes, W.F. Vance, G.F. (1996) Sorption of the ionizable organic, compound, dicamba (3,6-dichloro- 2-methoxy benzoic acid), by organoclays. Chemosphere, 10, 2089–2100.Google Scholar