Hostname: page-component-7479d7b7d-c9gpj Total loading time: 0 Render date: 2024-07-12T15:46:55.488Z Has data issue: false hasContentIssue false

Surface microtopography of interstratified mica and smectite from the Goto pyrophyllite deposit, Japan

Published online by Cambridge University Press:  09 July 2018

R. Kitagawa
Affiliation:
Department of Earth and Planetary Systems Science, Faculty of Science, Hiroshima University, Kagamiyuma, Higashihiroshima 724
A. Inoue
Affiliation:
Geological Institute, College of Arts and Sciences, Chiha University, Chiba 263
N. Kohyama
Affiliation:
National Institute of Industrial Health, Tama-ku, Kawasaki 214, Japan

Abstract

By means of a gold decoration transmission electron microscopy (TEM) technique, interlaced spiral steps with a 10 A step height were observed on (001) surfaces of lath-shaped or elongated hexagonal rectorite crystals, i.e. interstratihed mica-smectite minerals, from the Goto pyrophyllite deposit in Nagasaki Prefecture, Japan. This is the first direct evidence to demonstrate that the growth of interstratified mica-smectite takes place by the spiral growth mechanism. The interlacing pattern is interpreted as appearing by co-operation of two hexagonal spiral layers of mica and smectite-like layers which have originated from a single dislocation and are stacked by rotation of 60°.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Baronnet, A. (1972) Growth mechanism and polytypism in synthetic hydroxyl-bearing phlogopite. Am. Miner. 57, 12721293.Google Scholar
Baronnet, A. (1980) Polytypism in mica: A survey with emphasis on the crystals growth aspect. Pp. 447-548 in: Current topics in Material Science, 5 (Kaldis, E., editor). North-Holland publishing Company, Amsterdam.Google Scholar
Bassett, G. (1958) A new technique for decoration of cleavage and slip steps on ionic crystal surfaces. Phil. Mag. 3, 10421045.Google Scholar
Gritsaenko, G. & Samotoyin, N. (1966) The decoration method applied to the study of clay minerals. Proc. Int. Clay Conf, Jerusalem 391-400.Google Scholar
Güven, N. (1972) Electron optical observations on marblehead illite. Clays Clay Miner. 20, 8388.CrossRefGoogle Scholar
Henning, K.H. & Storr, M. (1986) Electron Micrographs (TEM, SEM) of Clays and Clay Minerals, pp. 190202. Akademie-Verlag Berlin.Google Scholar
Inoue, A., Kohyama, N., Kitagawa, R. & Watanabk, T. (1987) Chemical and morphological evidence for the conversion of smectite to illite. Clays Clay Miner. 35, 111120.Google Scholar
Inoue, A., Veldk, B., Meunier, A. & Touchard, G. (1988) Mechanism of illite formation during smectite-to-illite conversion in a hydrothermal system. Am. Miner. 73, 13251334.Google Scholar
Iwao, S. & Udagawa, S. (1969) Pyrophyllite and “Roseki’ clays. Proc. Int. Clay Conf.. Japan. 61-87.Google Scholar
Keller, W.D. (1976) Scan electron micrographs of kaolins collected from diverse environments of origin-I. Clays Clay Miner. 24, 107113.Google Scholar
Kitagawa, R. & Kakitani, S. (1981) Lath-shaped mica clay mineral. J. Miner. Soc. Japan 15, 107115.Google Scholar
Kitagawa, R. & Matsuda, T. (1992) Microtopography of regularly interstratified mica and smectite. Clays Clay Miner. 40, 114121.Google Scholar
Kitagawa, R., Takeno, S. & Sunagawa, I. (1983) Surface microtopographies of sericite crystals formed in different environmental conditions. Miner. J. 11, 282296.Google Scholar
Nadhau, P.H. & Tait, J.M. (1987) Transmission electron microscopy. Pp. 209-247 in: A Handbook of Determinative Methods in Clay Mineralogy (Wilson, M.J., editor). Blackie, Chapman & Hall, New York.Google Scholar
Skodon, J. & Eberl, D.D. (1984) Illite. Pp. 495-544 in: Reviews in Mineralogy, vol. 13 ‘Micas'. (Bailey, S.W., editor). Mineralogical Society of America, Washington.Google Scholar
Sunagawa, I. (1977) Natural crystallization. J. Cryst. Growth, 42, 214223.Google Scholar
Sunagawa, I. (1984) Growth of crystals in nature. Pp. 63-105 in: Material Science of the Earth's Interior. (Sunagawa, I., editor). Terrapub., Tokyo.Google Scholar
Sunagawa, I. & Koshino, Y. (1975) Growth spirals on kaolin group minerals. Am. Miner. 60, 407–112.Google Scholar
Sunagawa, I., Koshino, Y., Asakura, M. & Yamamoto, T. (1975) Growth mechanisms of some clay minerals. Fortschr. Miner. 52, 217224.Google Scholar
Tomita, K., Takahashi, H. & Watanabk, T. (1988) Quantification curves for mica/smectite interstratifications by Xray powder diffraction. Clays Clay Miner. 36, 258262.Google Scholar
Tomura, S., Kitamura, M. & Sunagawa, I. (1979) Surface microtopography of metamorphic white micas. Phys. Chem. Min. 5, 6581.CrossRefGoogle Scholar
Velde, B. (1992) Introduction to Clay Minerals, pp. 24-29, Chapman & Hall, London.CrossRefGoogle Scholar