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Surface microtopography of rectorite (allevardite) from Allevard, France

Published online by Cambridge University Press:  09 July 2018

R. Kitagawa*
Affiliation:
Department of Earth and Planetary Systems Science, Faculty of Science, Hiroshima University, Kagamiyama, Higashihiroshima 739, Japan

Abstract

By means of transmission electron microscopy (TEM) and the gold decoration technique, the surface microtopography of rectorite (allevardite) crystals collected from Allevard, France was investigated. On the crystal surfaces, gold decoration successfully revealed growth steps of ∼20 Å in height. Only closed polygonal steps 20 Å high occur on the 001 surface of a thick platy crystal, although spiral growth patterns were not observed. Thick platy particles were easily split into thinner plates 20 Å thick in distilled water by means of ultrasonic vibration. No step patterns were observed on the surfaces of these thin plates which correspond to the cleavage plane. The growth of this rectorite, therefore, seems to be controlled by a layer nucleation mechanism.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1997

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References

Baronnet, A. (1972) Growth mechanism and polytypism in synthetic hydroxyl-bearing phlogopite. Am. Miner. 57, 12721293.Google Scholar
Baronnet, A. (1980) Polytypism in mica: A survey with emphasis on the crystal growth aspect. Pp. 447–548 in: Current Topics in Material Science, 5 (Kaldis, E., editor). North-Holland publishing Company, Amsterdam.Google Scholar
Bassett, A. (1958) A new technique for decoration of cleavage and slip steps on ionic crystal surfaces. Phil. Mag. 3, 10421045.CrossRefGoogle Scholar
Brown, G. & Weir, A.H. (1963) The identity of rectorite and allevardite. Proc. Int. Clay Conf., Stockholm, 1, 2735.Google Scholar
Fukushima, Y. (1984) X-ray diffraction study of aqueous montmorillonite emulsions. Clays Clay Miner. 32, 320326.CrossRefGoogle Scholar
Gritsaenko, G. & Samotoyin, N. (1966) The decoration method applied to the study of clay minerals. Proc. Int. Clay Conf. Jerusalem, 391-400.Google Scholar
Henin, S., Esquevin, J. & Caillere, S. (1954) Sur la fibrosite de certain mineraux de nature montmorillonitique. Bull. Soc. Franc. Min. 77, 491499.Google Scholar
Henning, K.H. & Storr, M. (1986) Electron Micrographs (TEM,SEM) of Clays and Clay Minerals, pp. 190-202. Akademie-Verlag Berlin.Google Scholar
Inoue, A. & Kitagawa, R. (1994) Morphological characteristics of illitic clay minerals from a hydrothermal system. Am. Miner. 79, 700711.Google Scholar
Inoue, A., Kohyama, N., Kitagawa, R. & Watanabe, T. (1987) Chemical and morphological evidence for the conversion of smectite to illite. Clays Clay Miner. 35, 111120.CrossRefGoogle Scholar
Inoue, A., Velde, B., Meunier, A. & Touchard, G. (1988) Mechanism of illite formation during smectite-toillite conversion in a hydrothermal system. Am. Miner. 73, 13251334.Google Scholar
Ivkin, N.M., Kitaigorodskii, N.S., Kotelnikov, D.D. & Korolev Yu. M. (1959) Analogue of allevardite (from Dagestan). Zap. Vses. Min., Obshch. 88, 554563.Google Scholar
Kitagawa, R., Inoue, A. & Kohyama, N. (1994) Surface microtopography of interstratified mica and smectite from the Goto pyrophyllite deposit, Japan. Clay Miner. 29, 709715.Google Scholar
Kitagawa, R., Takeno, S. & Sunagawa, I. (1983) Surface micro-topographies of sericite crystals formed in different environmental conditions. Miner. J. 11, 282296.CrossRefGoogle Scholar
Kitagawa, R. & Matsuda, T. (1992) Microtopography of regularly interstratified mica and smectite. Clays Clay Miner. 40, 114121.CrossRefGoogle Scholar
Korolev, Yu. M. (1961) The structure of allevardite. Soviet Phys. Cryst. 5, 848852.Google Scholar
Sato, H. (1979) Microstructure of mica cleavage surfaces. J. Japan Assoc. Mineral Petrol Econ. Geol. 64, 192198.CrossRefGoogle Scholar
Sunagawa, I. (1977) Natural crystallization. J. Cryst. Growth 42, 214223.CrossRefGoogle Scholar
Sunagawa, I. (1984) Growth of crystals in nature. Pp. 63-105 in: Material Science of Earth's Interior. (Sunagawa, I., Editor). Terrapub., Tokyo.Google Scholar
Sunagawa, I. & Koshino, Y. (1975) Growth spirals on kaolin group minerals. Am. Miner. 60, 407–412.Google Scholar
Sunagawa, I., Koshino, Y., Asakura, M. & Yamamoto, T. (1975) Growth mechanisms of some clay minerals. Fortscr. Miner. 52, 217224.Google Scholar
Tomita, K., Takahashi, H. & Watanabe, T. (1988) Quantification curves for mica/smectite interstratifications by X-ray powder diffraction. Clays Clay Miner. 36, 258262.CrossRefGoogle Scholar
Tomura, S., Kitamura, M. & Sunagawa, I. (1979) Surface micro- topography of metamorphic white micas. Phys. Chem. Min. 5, 6581.CrossRefGoogle Scholar
Velde, B. (1992) Introduction to Clay Minerals, pp. 24-29. Chapman & Hall, London.CrossRefGoogle Scholar