Hostname: page-component-848d4c4894-v5vhk Total loading time: 0 Render date: 2024-06-28T22:23:11.017Z Has data issue: false hasContentIssue false
  • English
  • Français

Adsorption of crystal violet dye by a zeolite-montmorillonite nano-adsorbent: modelling, kinetic and equilibrium studies

Published online by Cambridge University Press:  23 September 2019

Malihe Sarabadan ,
Hadis Bashiri Open the ORCID record for Hadis Bashiri [Opens in a new window]  and
Seyed Mahdi Mousavi
Malihe Sarabadan
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Hadis Bashiri*
Affiliation:
Department of Physical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
Seyed Mahdi Mousavi
Affiliation:
Department of Applied Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
*
*Email: hbashiri@kashanu.ac.ir
Get access Rights & Permissions [Opens in a new window]

Abstract

A zeolite-montmorillonite (zeolite-Mt) nano-adsorbent was prepared by calcination at 600°C. The synthesized nano-adsorbent was tested for removal of a toxic and cationic dye (crystal violet) from water, and it was characterized by various techniques. The effects of variables such as pH, temperature, adsorbent dosage and initial dye concentration on the removal efficiency of the dye were investigated by response surface methodology (RSM). Experimental conditions were optimized by RSM to achieve the maximum dye removal efficiency. Optimum conditions for maximum removal of dye were obtained at pH 9, temperature of 25°C, adsorbent dosage of 2 g L−1 and initial dye concentration of 40 mg L−1. Under these conditions, the maximum removal efficiency obtained was 99.9%. Various isotherms were applied to study adsorption equilibrium, and of these, the Freundlich isotherm provided the best fit. In addition, the fractal-like integrated kinetic Langmuir model was the most appropriate among several kinetic models. The thermodynamic parameters were also determined. The zeolite-Mt prepared under optimum conditions displayed a greater adsorption capacity than activated carbon (manufactured by Merck) and than various other adsorbents.

Keywords

adsorbentkineticequilibriummontmorilloniteresponse surface methodologyzeolite
Type
Article
Information
Clay Minerals , Volume 54 , Issue 4 , December 2019 , pp. 357 - 368
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Miroslav Pospíšil

References

Alberti, G., Amendola, V., Pesavento, M. & Biesuz, R. (2012) Beyond the synthesis of novel solid phases: review on modelling of sorption phenomena. Coordination Chemistry Reviews, 256, 28–45.CrossRefGoogle Scholar
Alipanahpour Dil, E., Ghaedi, M., Ghaedi, A., Asfaram, A., Jamshidi, M. & Purkait, M.K. (2016) Application of artificial neural network and response surface methodology for the removal of crystal violet by zinc oxide nanorods loaded on activate carbon: Kinetics and equilibrium study. Journal of the Taiwan Institute of Chemical Engineers, 59, 210–220.Google Scholar
Alipanahpour Dil, E., Ghaedi, M. & Asfaram, A. (2017) The performance of nanorods material as adsorbent for removal of azo dyes and heavy metal ions: application of ultrasound wave, optimization and modeling. Ultrasonics Sonochemistry, 34, 792–802.Google Scholar
Amodu, O.S., Ojumu, T.V., Ntwampe, S.K. & Ayanda, O.S. (2015) Rapid adsorption of crystal violet onto magnetic zeolite synthesized from fly ash and magnetite nanoparticles. Journal of Encapsulation and Adsorption Sciences, 5, 191–203.CrossRefGoogle Scholar
Anirudhan, T.S., Suchithra, P.S. & Radhakrishnan, P.G. (2009) Synthesis and characterization of humic acid immobilized-polymer/bentonite composites and their ability to adsorb basic dyes from aqueous solutions. Applied Clay Science, 43, 336–342.CrossRefGoogle Scholar
Asfaram, A., Ghaedi, M., Goudarzi, A. & Rajabim, M. (2015) Response surface methodology approach for optimization of simultaneous dye and metal ion ultrasound-assisted adsorption onto Mn doped Fe3O4-NPs loaded on AC: kinetic and isothermal studies. Dalton Transactions, 44, 14707–14723.CrossRefGoogle ScholarPubMed
Atta, A.M., Al-Lohedan, H.A., Alothman, Z.A., Abdel-Khalek, A.A. & Tawfeek, A.M. (2015) Characterization of reactive amphiphilic montmorillonite nanogels and its application for removal of toxic cationic dye and heavy metals water pollutants. Journal of Industrial and Engineering Chemistry, 31, 374–384.CrossRefGoogle Scholar
Azizian, S. & Bashiri, H. (2008) Adsorption kinetics at the solid/solution interface: statistical rate theory at initial times of adsorption and close to equilibrium. Langmuir, 24, 11669–11676.CrossRefGoogle ScholarPubMed
Azizian, S., Haerifar, M. & Bashiri, H. (2009) Adsorption of methyl violet onto granular activated carbon: equilibrium, kinetics and modeling. Chemical Engineering Journal, 146, 36–41.CrossRefGoogle Scholar
Başar, C.A. (2006) Applicability of the various adsorption models of three dyes adsorption onto activated carbon prepared waste apricot. Journal of Hazardous Materials, 135, 232–241.CrossRefGoogle ScholarPubMed
Bashiri, H. & Eris, S. (2016) Statistical thermodynamic study of gas adsorption with different adsorption geometries on homogeneous solid surface. Chemical Engineering Communications, 203, 628–634.CrossRefGoogle Scholar
Bertolini, T.C.R., Izidoro, J.C., Magdalena, C.P. & Fungaro, D.A. (2013) Adsorption of crystal violet dye from aqueous solution onto zeolites from coal fly and bottom ashes. Orbital: The Electronic Journal of Chemistry, 5, 179–191.Google Scholar
Bhattacharyya, K.G., SenGupta, S. & Sarma, G.K. (2014) Interactions of the dye, Rhodamine B with kaolinite and montmorillonite in water. Applied Clay Science, 99, 7–17.CrossRefGoogle Scholar
Bujdák, J., Czímerová, A. & Iyi, N. (2008) Structure of cationic dyes assemblies intercalated in the films of montmorillonite. Thin Solid Films, 517, 793–799.CrossRefGoogle Scholar
Chen, L., Zhou, C.H., Fiore, S., Tong, D.S., Zhang, H., Li, C.S., Ji, S.F. & Yu, W.H. (2016) Functional magnetic nanoparticle/clay mineral nanocomposites: preparation, magnetism and versatile applications. Applied Clay Science, 127–128, 143–163.CrossRefGoogle Scholar
Chen, Z.X., Wang, T., Jin, X.Y., Chen, Z.L., Megharaj, M. & Naidu, R. (2013) Multifunctional kaolinite-supported nanoscale zero-valent iron used for the adsorption and degradation of crystal violet in aqueous solution. Journal of Colloid and Interface Science, 398, 59–66.CrossRefGoogle ScholarPubMed
Czímerová, A. & Ceklovský, A. (2017) Resonance energy transfer between rhodamine dyes in saponite thin films: a step towards novel photofunctional nanohybrids. Clay Minerals, 52, 263–273.CrossRefGoogle Scholar
Cohen, E., Joseph, T., Lapides, I. & Yariv, S. (2005) The adsorption of berberine by montmorillonite and thermo-XRD analysis of the organo-clay complex. Clay Minerals, 40, 223–232.CrossRefGoogle Scholar
Çoruh, S., Geyikçi, F. & Nuri Ergun, O. (2011) Adsorption of basic dye from wastewater using raw and activated red mud. Environmental Technology, 32, 1183–1193.CrossRefGoogle ScholarPubMed
de Sales, P.F., Magriotis, Z.M., Rossi, M.A.L.S., Resende, R.F. & Nunes, C.A. (2013) Optimization by response surface methodology of the adsorption of Coomassie blue dye on natural and acid-treated clays. Journal of Environmental Management, 130, 417–428.CrossRefGoogle ScholarPubMed
Eris, S. & Bashiri, H. (2016) Kinetic study of the adsorption of dyes onto activated carbon. Progress in Reaction Kinetics and Mechanism, 41, 109–119.CrossRefGoogle Scholar
Fahn, R. & Fenderl, K. (2018) Reaction products of organic dye molecules with acid-treated montmorillonite. Clay Minerals, 18, 447–458.CrossRefGoogle Scholar
Febrianto, J., Kosasih, A.N., Sunarso, J., Ju, Y.-H., Indraswati, N. & Ismadji, S. (2009) Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: a summary of recent studies. Journal of Hazardous Materials, 162, 616–645.CrossRefGoogle ScholarPubMed
Freundlich, H.M.F. (1906) Over the adsorption in solution. Journal of Physical Chemistry, 57, 385–470.Google Scholar
Gamoudi, S. & Srasra, E. (2018) Removal of cationic and anionic dyes using purified and surfactant-modified Tunisian clays: kinetic, isotherm, thermodynamic and adsorption-mechanism studies. Clay Minerals, 53, 159–174.CrossRefGoogle Scholar
García-Montaño, J., Pérez-Estrada, L., Oller, I., Maldonado, M.I., Torrades, F. & Peral, J. (2008) Pilot plant scale reactive dyes degradation by solar photo-Fenton and biological processes. Journal of Photochemistry and Photobiology A: Chemistry, 195, 205–214.CrossRefGoogle Scholar
Gautam, R.K., Mudhoo, A. & Chattopadhyaya, M.C. (2013) Kinetic, equilibrium, thermodynamic studies and spectroscopic analysis of Alizarin Red S removal by mustard husk. Journal of Environmental Chemical Engineering, 1, 1283–1291.CrossRefGoogle Scholar
Haerifar, M. & Azizian, S. (2012) Fractal-like adsorption kinetics at the solid/solution interface. Journal of Physical Chemistry C, 116, 13111–13119.CrossRefGoogle Scholar
Hamidzadeh, S., Torabbeigi, M. & Shahtaheri, S.J. (2015) Removal of crystal violet from water by magnetically modified activated carbon and nanomagnetic iron oxide. Journal of Environmental Health Science and Engineering, 13, 8.CrossRefGoogle ScholarPubMed
Ho, Y.S. & McKay, G. (1999) Batch lead(II) removal from aqueous solution by peat: equilibrium and kinetics. Process Safety and Environmental Protection, 77, 165–173.CrossRefGoogle Scholar
Humelnicu, I., Băiceanu, A., Ignat, M.-E. & Dulman, V. (2017) The removal of Basic Blue 41 textile dye from aqueous solution by adsorption onto natural zeolitic tuff: kinetics and thermodynamics. Process Safety and Environmental Protection, 105, 274–287.CrossRefGoogle Scholar
Iqbal, M., Iqbal, N., Bhatti, I.A., Ahmad, N. & Zahid, M. (2016) Response surface methodology application in optimization of cadmium adsorption by shoe waste: a good option of waste mitigation by waste. Ecological Engineering, 88, 265–275.CrossRefGoogle Scholar
Ishaq, M., Javed, F., Amad, I. & Ullah, H. (2016) Adsorption of crystal violet dye from aqueous solutions onto low-cost untreated and NaOH treated almond shell. Iranian Journal of Chemistry and Chemical Engineering, 35, 97–106.Google Scholar
Jamshidi, M., Ghaedi, M., Dashtian, K., Ghaedi, A.M., Hajati, S., Goudarzi, A. & Alipanahpour, E. (2016) Highly efficient simultaneous ultrasonic assisted adsorption of brilliant green and eosin B onto ZnS nanoparticles loaded activated carbon: artificial neural network modeling and central composite design optimization. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 153, 257–267.CrossRefGoogle ScholarPubMed
Lagergren, S. (1898) Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar, 24, 1–39.Google Scholar
Langmuir, I. (1916) The constitution and fundamental properties of solids and liquids. Part I. Solids. Journal of the American Chemical Society, 38, 2221–2295.CrossRefGoogle Scholar
Li, S. (2010) Removal of crystal violet from aqueous solution by sorption into semi-interpenetrated networks hydrogels constituted of poly(acrylic acid–acrylamide–methacrylate) and amylose. Bioresource Technology, 101, 2197–2202.CrossRefGoogle ScholarPubMed
Marczewski, A.W. (2010) Analysis of kinetic Langmuir model. Part I: integrated kinetic Langmuir equation (IKL): a new complete analytical solution of the Langmuir rate equation. Langmuir, 26, 15229–15238.CrossRefGoogle ScholarPubMed
Mousavi, S.M. & Nakhostin Panahi, P. (2016) Modeling and optimization of NH3-SCR performance of MnOx/γ-alumina nanocatalysts by response surface methodology. Journal of the Taiwan Institute of Chemical Engineers, 69, 68–77.CrossRefGoogle Scholar
Mousavi, S.M., Salari, D., Niaei, A., Panahi, P.N. & Shafiei, S. (2014) A modelling study and optimization of catalytic reduction of NO over CeO2–MnOx (0.25)–Ba mixed oxide catalyst using design of experiments. Environmental Technology, 35, 581–589.CrossRefGoogle ScholarPubMed
Peláez-Cid, A.-A., Herrera-González, A.-M., Salazar-Villanueva, M. & Bautista-Hernández, A. (2016) Elimination of textile dyes using activated carbons prepared from vegetable residues and their characterization. Journal of Environmental Management, 181, 269–278.CrossRefGoogle ScholarPubMed
Qiu, M., Qian, C., Xu, J., Wu, J. & Wang, G. (2009) Studies on the adsorption of dyes into clinoptilolite. Desalination, 243, 286–292.CrossRefGoogle Scholar
Rida, K., Bouraoui, S. & Hadnine, S. (2013) Adsorption of methylene blue from aqueous solution by kaolin and zeolite. Applied Clay Science, 83–84, 99–105.CrossRefGoogle Scholar
Sarma, G.K., Sen Gupta, S. & Bhattacharyya, K.G. (2016) Adsorption of crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension. Journal of Environmental Management, 171, 1–10.CrossRefGoogle ScholarPubMed
Satapathy, M.K. & Das, P. (2014) Optimization of crystal violet dye removal using novel soil–silver nanocomposite as nanoadsorbent using response surface methodology. Journal of Environmental Chemical Engineering, 2, 708–714.CrossRefGoogle Scholar
Senthilkumaar, S., Kalaamani, P. & Subburaam, C.V. (2006) Liquid phase adsorption of crystal violet onto activated carbons derived from male flowers of coconut tree. Journal of Hazardous Materials, 136, 800–808.CrossRefGoogle ScholarPubMed
Simonin, J.-P. (2016) On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics. Chemical Engineering Journal, 300, 254–263.CrossRefGoogle Scholar
Sips, R. (1948) On the structure of a catalyst surface. Journal of Chemical Physics, 16, 490–495.CrossRefGoogle Scholar
Sismanoglu, T., Kismir, Y. & Karakus, S. (2010) Single and binary adsorption of reactive dyes from aqueous solutions onto clinoptilolite. Journal of Hazardous Materials, 184, 164–169.CrossRefGoogle ScholarPubMed
Temkin, M.J. & Pyzhev, V. (1940) Recent modification to Langmuir isotherms. Acta Physiochim URSS, 12, 327–356.Google Scholar
Townsend, R.P. (1991) Ion exchange in zeolites. Pp. 359–390 in: Studies in Surface Science and Catalysis (van Bekkum, H., Flanigen, E.M. & Jansen, J.C., editors). Amsterdam, The Netherlands, Elsevier.Google Scholar
Tran, H.N., You, S.-J. & Chao, H.-P. (2016) Thermodynamic parameters of cadmium adsorption onto orange peel calculated from various methods: a comparison study. Journal of Environmental Chemical Engineering, 4, 2671–2682.CrossRefGoogle Scholar
Vimonses, V., Lei, S., Jin, B., Chow, C.W.K. & Saint, C. (2009) Kinetic study and equilibrium isotherm analysis of Congo red adsorption by clay materials. Chemical Engineering Journal, 148, 354–364.CrossRefGoogle Scholar
Wu, F.-C., Tseng, R.-L. & Juang, R.-S. (2009) Initial behavior of intraparticle diffusion model used in the description of adsorption kinetics. Chemical Engineering Journal, 153, 1–8.CrossRefGoogle Scholar
Yagub, M.T., Sen, T.K., Afroze, S. & Ang, H.M. (2014) Dye and its removal from aqueous solution by adsorption: a review. Advances in Colloid and Interface Science, 209, 172–184.CrossRefGoogle ScholarPubMed
Yang, H., Zhou, D., Chang, Z. & Zhang, L. (2014) Adsorption of crystal violet onto amino silica: optimization, equilibrium, and kinetic studies. Desalination and Water Treatment, 52, 6113–6121.CrossRefGoogle Scholar
Yavuz, Ö. & Aydin, A.H. (2006) Removal of direct dyes from aqueous solution using various adsorbents. Polish Journal of Environmental Studies, 15, 155–161.Google Scholar
Zhu, R., Chen, Q., Liu, H., Ge, F., Zhu, L., Zhu, J. & He, H. (2014) Montmorillonite as a multifunctional adsorbent can simultaneously remove crystal violet, cetyltrimethylammonium, and 2-naphthol from water. Applied Clay Science, 88–89, 33–38.CrossRefGoogle Scholar