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Diagenetic modification of detrital muscovite: an example from the Great Limestone Cyclothem (Carboniferous) of Co. Durham, UK

Published online by Cambridge University Press:  09 July 2018

S. F. Crowley*
Affiliation:
Department of Earth Sciences, University of Liverpool PO Box 147, Liverpool L69 3BX, UK

Abstract

Diagenetically modified muscovite grains occur as a frequent component of many Upper Palaeozoic and Mesozoic fluvial-deltaic sandstones and siltstones from Britain and the North Sea. Mineralogical, textural and chemical investigation of examples from the Great Limestone Cyclothem show that such grains consist simply of muscovite and kaolinite. No other sheet-silicate phases are involved. Diagenetic textures indicate that modified grains result from the displacive growth of kaolinite between opened cleavage sheets of detrital muscovite. Fabrics of this type should consequently be termed kaolinite-cemented. In contrast to similar sheet-silicate intergrowths reported from diagenetically altered biotite and chlorite, little or no alteration of muscovite is actually required to account for observed textures.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1991

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References

Ahn, J.H. & Peacor, D.R. (1986) Transmission and analytical electron microscopy of the smectite-to-illite transition. Clays Clay Miner., 34, 165–179.Google Scholar
AlDahan, A.A. & Morad, S. (1986) Chemistry of detrital biotites and their phyllosilicate intergrowths in sandstones. Clays Clay Miner., 34, 539–548.Google Scholar
Berner, R.A. (1971) Principles of Chemical Sedimentology. McGraw-Hill, New York.Google Scholar
Bjorlykke, K., Malm, O. & Elverhoi, A. (1979) Diagenesis in Mesozoic sandstones from Spitsbergen and the North Sea–a comparison. Geol. Rundsch., 68, 1151–1171.Google Scholar
Bjorlykke, K. & Brendsdal, A. (1986) Diagenesis of the Brent Sandstone in the Statfjord Field, North Sea. Pp. 157167 in: Roles of Organic Matter in Sediment Diagenesis(Gautier, D.L., editor). SEPM Spec. Pub. 38.Google Scholar
Boles, J.R. & Johnson, K.S. (1984) Influence of mica surfaces on pore-water pH. Chem. Geol., 43, 303–317.Google Scholar
Brady, P.V. & Walther, J. V. (1989) Controls on silicate dissolution rates in neutral and basic pH solutions at 25°;C. Geochim. Cosmochim. Acta, 53, 2823–2830.Google Scholar
Burgess, I.C. & Holliday, D.W. (1979) Geology of the Country around Brough-under-Stainmore. Sheet Memoir 31, 25/30, 131 pp. HMSO, London.Google Scholar
Burley, S.D. (1984) Distribution and origin of authigenic minerals in the Triassic Sherwood Sandstone Group, UK. Clay Miner., 19, 403441.Google Scholar
Curtis, C.D. (1983) The link between aluminium mobility and destruction of secondary porosity. Bull. Am. Assoc, Petrol. Geol., 67, 380–384.Google Scholar
Curtis, C.D. & Spears, D.A. (1971) Diagenetic development of kaolinite. Clays Clay Miner., 19, 219–227.CrossRefGoogle Scholar
Deer, W.A., Howie, R.A. & Zussman J, (1962) Rock-Forming Minerals. Vol. 3, Sheet Silicates., 270pp. Longmans, London.Google Scholar
Dimberline, A.J. (1986) Electron microscope and microprobe analysis of chlorite mica stacks in the Wenlock turbidities, mid Wales, UK. Geol. Mag., 23, 299–306.Google Scholar
Dunham, A.C. & Wilkinson, F.C.F. (1978) Accuracy, precision and detection limits of energy dispersive electron- microprobe analysis of silicates. X-ray Spectrometry, 7, 50–56.Google Scholar
Elliott, T. (1975) The sedimentary history of a delta lobe from a Yoredale (Carboniferous) cyclothem. Proc. Yorks, geol. Soc., 40, 505–536.CrossRefGoogle Scholar
Gawthorpe, R.L., Gutteridge, P. & Leeder, M.R. (1989) Late Devonian andDinantian basin evolution in northern England and North Wales. Pp. 124 in: The Role of Tectonics in Devonian and Carboniferous Sedimentation in the British Isles.(Artherton, R.S., Gutteridge, P. & Nolan, S.C., editors). Yorks. Geol. Soc. Occ. Publ. No. 6. Google Scholar
Helgeson, H.C., Delaney, J.M., Nesbitt, H.W. & Bird, D.K. (1978) Summary and critique of the thermodynamic properties of rock forming minerals. Am. J. Sci., 278-A, 1229.Google Scholar
Hower, J. & Mowatt, T.C. (1966) The mineralogy of illites and mixed-layer illite/montmorillonites. Am. Miner. 51, 825854.Google Scholar
Huggett, J.M. (1984) Controls on mineral authigenesis in Coal Measures sandstones of the East Midlands, UK. Clay Miner., 19, 343–358.Google Scholar
Huggett, J.M. (1986) An SEM study of phyllosilicate diagenesis in sandstones and mudstones in the Westphalian Coal Measures using back-scattered electron microscopy. Clay Miner., 21, 603–616.Google Scholar
Irwin, H. & Hurst, A. (1983) Applicationsof geochemistry to sandstone reservoir studies. Pp. 127146 in: Petroleum Geochemistry and Exploration of Europe (J. Brooks, , editor). Geol. Soc. Spec. Pub. 12.Google Scholar
Kantorowicz, J. (1984) Nature, origin and distribution of authigenic day minerals from Middle Jurassic clastic sediments, Ravenscar and Brent Group sandstones. Clay Miner., 19, 359–377.Google Scholar
Knauss, K.G. & Wolery T, J. (1986) Dependence of albite dissolution kinetics on pH and time at 25°C and 70°C. Geochim. Cosmochim. Acta, 50, 2481–2497.Google Scholar
Knauss, K.G. & Wolery, T J. (1989) Muscovite dissolution kinetics as a function of pH and time at 70°C. Geochim. Cosmochim. Acta, 53, 1493–1501.Google Scholar
Morad, S. (1986a) Mica-chlorite intergrowths in very low-grade metamorphosed sedimentary rocks from Norway. Neues Jahrb. Mineral. Abh., 154, 271287.Google Scholar
Morad, S. (1986b) Pyrite-chlorite and pyrite-biotite relations in sandstones. Sed. Geol., 49, 177–192.Google Scholar
Morad, S. & AlDahan, A.A. (1986) Diagenetic alteration of biotite in Proterozoic sedimentary rocks from Sweden. Sed. Geol., 47, 95–107.Google Scholar
Pye, K. & Krinsley, D.H. (1983) Inter-layered clay stacks in Jurassic shales. Nature, 304, 618–620.CrossRefGoogle Scholar
Pye, K. & Krinsley, D.H. (1986) Microfabric, mineralogy and early diagenetic history of the Whitby Mudstone Formation (Toarcian), Cleveland Basin, UK. Geol. Mag., 123, 191–203.Google Scholar
Stoessell, R.K. (1987) Mass transport around dissolving plagioclase grains. Geology, 15, 295–298.Google Scholar
Stumm, W., Furrer, G. & Kunz, B. (1983) The role of surface coordination in precipitation and dissolution of mineral phases. Croat. Chem. Acta, 56, 593–611.Google Scholar
Velbel, M.A. (1985) Geochemical mass balance and weathering rates in forest watersheds of the southern Blue Ridge. Am. J. ScL, 285, 904–930.Google Scholar
Velde, B. (1985) Clay Minerals: a Physico-chemical Explanation of their Occurrence.Developments in Sedimentology 40. 427pp. Elsevier Scientific Pub. Co., Amsterdam.Google Scholar
Walton, A.G. (1967) The Formation and Properties of Precipitates., 232pp. Interscience Publishers, New York.Google Scholar
Warren, E.A. (1987) The application of a solution-mineral equilibria model to the diagenesis of Carboniferous sandstones, Bothamsall, East Midlands, England. Pp. 5572 in: Diagenesis of Sedimentary Sequences(Marshall, J.D., editor). Geol. Soc. Spec. Pub. 36.Google Scholar
Weaver, C.E. & Pollard, L.D. (1973) The Chemistry of Clay Minerals. Developments in Sedimentology 15. 213pp. Elsevier Scientific Pub. Co., Amsterdam.Google Scholar
White, S.W., Shaw, H.F. & Huggett, J.M., (1984) The use of back-scattered electron imaging for the petrographic study of sandstones and shales. J. Sed. Pet., 54, 487494.Google Scholar
White, S.H., Huggett, J.M. & Shaw, H.F. (1985) Electron-optical studies of phyllosilicate intergrowths in sedimentary and metamorphic rocks. Mineral. Mag., 49, 413–423.Google Scholar