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The Colloid Science of Silica and Silicones

Published online by Cambridge University Press:  01 January 2024

Ernst A. Hauser*
Affiliation:
Massachusetts Institute of Technology, Cambridge, Massachusetts, USA

Abstract

A detailed explanation of the most important properties of natural and synthetic silica and silica gels is given. Specific reference is made to the differences between the formation of synthetic silica gels and of quartz and cristobalite. The effect exerted by the synthetic products is explained and the importance of their amorphous condition on their reactivity is also referred to. On the basis of ultra- and electron-microscopic studies it is demonstrated that these synthetic products are not crystalline, but amorphous aggregates, and it is also shown how their reactivity can be increased by appropriate dispersion before use.

The colloidal properties of silicone resins are then pointed out and their production explained. Their advantages over purely organic matter and the reasons for this difference are also referred to.

Finally, reasons are given why more attention must be paid to colloid science in any field where silica or silicones are studied or put to use.

Type
Article
Copyright
Copyright © The Clay Minerals Society 1955

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Footnotes

*

Deceased

References

Duclaux, J., 1908, Die Filtration kolloider Lösungen: Kolloid Zeitschrift, ν. 3, p. 126134.CrossRefGoogle Scholar
Hauser, E. A., 1955, The colloid science of important clay minerals: in Clays and clay minerals, Natl. Acad. Sci.-Natl. Res. Council, Pub. 395, p. 442472.Google Scholar
Hauser, E. A., 1955a, Silicic science: D. Van Nostrand Co., Inc., New York, 188 p.Google Scholar
Hauser, E. A., and Colombo, U., 1954, Colloid science of montmorillonites and bentonites: in Clays and clay minerals, Natl. Acad. Sci.—Natl. Res Council Pub. 327, p. 439461.Google Scholar
Hurd, C. B., 1938, Theories of the mechanism of the setting of silicic acid gels: Chem. Reviews, v. 22, p. 403422.CrossRefGoogle Scholar
Iler, R. K., 1955, The colloid chemistry of silica and silicates: Cornell University Press, Ithaca, New York, 324 p.Google Scholar
Marshall, C. E., 1949, The colloid chemistry of the silicate minerals: Academic Press, Inc., New York, 180 p.Google Scholar
Weyl, W. A., 1949, Surface structure and surface properties of crystals and glasses: Amer. Ceram. Soc. J., v. 32, p. 367374.CrossRefGoogle Scholar
Weyl, W. A., and Hauser, E. A., 1951, Bildung und Struktur von Silikagel: Koll. Zeits., v. 124, p. 7276.CrossRefGoogle Scholar