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Hydration Structure of Exchangeable Cu2+ in Vermiculite and Smectite

Published online by Cambridge University Press:  01 July 2024

Murray McBride*
Affiliation:
Department of Agronomy, Cornell University, Ithaca, NY 14853, U.S.A.

Abstract

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Type
Notes
Copyright
Copyright © 1976 The Clay Minerals Society

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References

Berkheiser, V. and Mortland, M. M. (1975) Variability in exchange ion position in smectite: dependence on interlayer solvent: Clays & Clay Minerals 23, 404410.CrossRefGoogle Scholar
Clementz, D. M., Pinnavaia, T. J. and Mortland, M. M. (1973) Stereochemistry of hydrated copper (II) ions on the interlamellar surfaces of layer silicates. An electron spin resonance study: J. phys. Chem. 77, 196200.CrossRefGoogle Scholar
Farmer, V. C. and Russell, J. D. (1971) Interlayer complexes in layer silicates. The structure of water in lamellar ionic solutions: Trans. Farad. Soc. 67, 27372749.CrossRefGoogle Scholar
Kivelson, D. and Neiman, R. (1961) Esr studies on the bonding in copper complexes: J. chem. Phys. 35, 149155.CrossRefGoogle Scholar
McBride, M. B. and Mortland, M. M. (1974) Copper (II) interactions with montmorillonite: evidence from physical methods: Soil Sci. Soc. Am. Proc. 38, 408415.CrossRefGoogle Scholar
McBride, M. B., Pinnavaia, T. J. and Mortland, M. M. (1975) Electron spin resonance studies of cation orientation in restricted water layers on phyllosilicate (smectite) surfaces: J. phys. Chem. 79, 24302435.CrossRefGoogle Scholar
Poupko, R. and Luz, Z. (1972) Esr and nmr in aqueous and methanol solutions of copper (II) solvates. Temperature and magnetic field dependence of electron and nuclear spin relaxation: J. chem. Phys. 57, 33113318.CrossRefGoogle Scholar