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Reaction Series for Dioctahedral Smectites

Published online by Cambridge University Press:  01 July 2024

Dennis Eberl
Dennis Eberl*
Affiliation:
Department of Geology, University of Illinois, Urbana, Ill. 61801
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Abstract

Several dioctahedral clay minerals are related through reaction series. These series can be produced hydro-thermally from beidellite gel and montmorillonite by making simple changes in interlayer and solution chemistry. The series are:

  • gel-K-beidellite-random illite/smectite-K-rectorite-illite

  • K-montmorillonite-K-rectorite-illite

  • Na-montmorillonite or beidellite-Na-rectorite-paragonite

  • Li-montmorillonite-Li-tosudite-Li-rectorite-cookeite(?)

  • Mg-montmorillonite-Mg-rectorite-tosudite-sudoite(?)

  • Ca-montmorillonite-Ca-rectorite-margarite(?)

  • Al-Ca-montmorillonite-kaolinite/smectite-kaolinite (150°C)

  • Al-Ca-montmorillonite-pyrophyllite/smectite-pyrophyllite (320°C).

Assuming stability for the mixed-layer phases, paragenesis is a function of P, T, and X conditions. If the phases are considered to be metastable, paragenesis is a function of the speed and path of reaction.

Резюме

Резюме

Несколько диоктаэдрических глинистых минералов связываются посредством реакционных серий. Эти серии могут быть получены гидротермически из бейделлитового геля и монтмориллонита в результате простых изменений в меж-слойных промежутках и в химии раствора. Этими сериями являются

гель—К-бейделлит —любой иллит/смектит—К-ректорит—иллит

К-монтмориллонит—К-ректорит—иллит

Na- монтмориллонит или бейделлит—Ыа-ректорит—парагонит

Li-монтмориллонит—Li-тосудит—Li-ректорит—кукеит(?)

Mg-монтмориллонит—Mg-ректорит—тосудит—судоит(?)

Ca-монтмориллонит—Са-ректорит—Маргарит(?)

Al-Ca-монтмориллонит—каолинит/смектит—каолинит(150°С)

Al-Ca-монтмориллонит—пирофиллит/смектит—пирофиллите 320°С)

Если предположить стабильность смешанно-слойных фаз,парагенезис является функцией условий Р,Т,Х. Если фазы рассматривать как неустойчивые,парагенезис является функцией скорости и пути реакции.

Kurzreferat

Kurzreferat

Mehrere dioktahedrische Tonmineralien gehören zu denselben Reaktionsserien. Diese Serien können aus Beidellitgel und Montmorillonit hydrothermisch hergestellt werden, indem einfache Änderungen in der Zwischenschicht-und Lösungschemie gemacht werden. Die Serien sind die folgenden:

Gel—K-Beidellit—nicht geordnetes Illit/Smektit—K-Rektorit—Illit

K-Montmorillonit—K-Rektorit—Illit

Na-Montmorillonit oder Beidellit—Na-Rektorit—Paragonit

Li-Montmorillonit—Li-Tosudit—Li-Rektorit—Cookeit (?)

Mg-Montmorillonit—Mg-Rektorit—Tosudit—Sudoit (?)

Ca-Montmorillonit—Ca-Rektorit—Margarit (?)

Al-Ca-Montmorillonit—Kaolinit/Smektit—Kaolinit (150°C)

Al-Ca-Montmorillonit—Pyrophyllit/Smektit—Pyrophyllit (320°C)

Wenn man annimmt, daß die gemischt-Schicht Phasen stabil sind, dann ist die Paragenesis eine Funktion der P,T,X Konditionen. Falls die Phasen für metastabil gehalten werden,dann ist die Paragenesis eine Funktion der Geschwind igkeit der Reaktion und des Reaktionsweges.

Résumé

Résumé

Plusieurs minéraux argileux dioctaèdraux sont apparentés par des suites de réaction. Ces suites peuvent être produites de manière hydrothermale à partir de gels de beidellite et de montmorillonite en faisant de simples changements dans la chimie interfeuillet et de solution. Ces suites sont:

gel—K-beidellite—illite/smectite—K-rectorite—illite

K-montmorillonite—K-rectorite—illite

Na-montmorillonite, beidellite—Na-rectorite—paragonite

Li-montmorillonite—Li-tosudite—Li-rectorite—cookeite(?)

Mg-montmorillonite—Mg-rectorite—tosudite—sudoite(?)

Ca-montmorillonite—Ca-rectorite—margarite(?)

Al-Ca-montmorillonite—kaolinite/smectite—kaolinite(150°C)

Al-Ca-montmorillonite—pyrophyllite/smectite—pyrophyllite(320°C)

Présumant un état de stabilité pour les phases à feuillets mélangés, la paragénèse est une fonction des conditions P,T,X. Si les phases sont considérées comme étant métastables, la paragénèse est une fonction de la vitesse et de la direction de réaction.

Keywords

BeidelliteCookeiteHydrothermalMixed-layerRectoriteSudoiteTosudite
Type
Research Article
Information
Clays and Clay Minerals , Volume 26 , Issue 5 , October 1978 , pp. 327 - 340
Copyright
Copyright © 1978, The Clay Minerals Society

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