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Some Results of the Study of Clay Minerals in the U.S.S.R.

Published online by Cambridge University Press:  01 July 2024

F. V. Chukhrov
F. V. Chukhrov*
Affiliation:
Institute for Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Academy of Sciences of U.S.S.R., Staromonetniĭ pereulok, 35, Moscow, Zh-17, U.S.S.R.
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Abstract

Clay mineral studies in the U.S.S.R., mainly since 1960, are summarized. Electron diffraction techniques especially have been developed and used extensively. Methods have been developed for simultaneous recording of DTA curves and other properties. Polytypism of phyllosilicates has been studied intensively by Zvyagin and others. Much new information on the structure and morphology of halloysites has been obtained by electron-optical methods. Other clay minerals extensively studied include allophanes, kaolinites, chlorites (“donbassite” is preferred to “sudoite” for dioctahedral varieties), alushtite (or tosudite), monothermite, and various zinc-bearing clays. Much attention has been given to physico-chemical and colloid-chemical properties. The natural occurrence and alteration of clays and clay minerals are described in weathering and oxidation zones, in soils, and in Recent and Ancient sediments. Primary clay minerals of hydrothermal origin are described.

Résumé

Résumé

Des études sur les miné raux argileux en U.R.S.S. effectuées surtout depuis 1960, sont résumées ici. Des techniques employant la diffraction d’électrons ont été spécialement développées et utilisées de façon extensive. Des méthodes ont été développées pour l’enregistrement simultané de courbes DTA et antres propriétés. Les différents types sous lesquels se manifestent les phyllosilicates ont été étudiés intensément par Zvyagin et antres chercheurs. Une grande quantité d’informations nouvelles sur la structure et la morphologie d’halloysites a pu être obtenue par des méthodes optiques et employant les électrons. Les autres minéraux argileux qui ont été étudiés de manière extensive sont les allophanes, les kaolinites, les chlorures (“donbassite” est préféré à “sudoite” pour les variétés dioctraédriques), l’alushtite (ou tosudite), le monothermite et les différentes argiles porteuse de zinc. Une grande attention a été donné aux propriétés physico-chimiques et colloido-chimiques, k’apparition naturelle et l’altération des argiles et des minéraux argileux sont décrites pour les zones climatiques et d’oxidation, pour les sols, et pour les sédiments récents et anciens, Les premiers minéraux argileux d’origine hydrothermique sont décrits.

Kurzreferat

Kurzreferat

Es wird ein Überblick über die Tonmineralforschung in der Sowjet Union, vor allem seit 1960, gegeben. In erster Linie sind Elektronen-beugungstechniken entwickelt und in weitem Umfang angewendet, worden. Es wurden Methoden für die gleichzeitige Aufzeichnungen von DTA Kurven und anderer Eigenschaften entwickelt. Der Polytypismus von Phyllosilikaten wurde von Zvyagin und anderen gründlich studiert. Durch elektronen-optische Methoden konnten neue Erkenntnisse über den Aufbau und die Morphologie von Halloysiten gewonnen werden. Andere eingehend untersuchte Tonminerale umfassen Allophene, Kaolinite, Chlorite (für oktahedrale Sorten wird “Donbassit” an Stelle von “Sudoit” vorgezogen), Alushtit (oder Tosudit), Monothermit und verschiedene zinkhaltige Tone. Grosse Beachtung wurde den physikalisch-chemischen und kolloid-chemischen Eigenschaften geschenkt. Das natürliche Vorkommen und die Veränderungen des Tons und der Tonminerale in Verwitterungs-und Oxydations-zonen, in Böden und in neueren sowie in alten Ablagerungen werden behandelt. Primäre Tonminerale hydrothermalen Ursprungs werden beschrieben.

Резюме

Резюме

Приводится сводка работ, предпринятых в СССР по глинистым минералам, главным образом с 1960г. Преимущественно усовершенствовали методы электронной диффракции и они широко применяются. Усовершенствованы методы одновременной записи кривых DTА и других характеристик. Звягин и другие интенсивно исследовали политипизм филлосиликатов. Многие новые сведения о структуре и морфологии галлаузитов были получены, пользуясь приемами электронной оптики. Другие глинистые минералы, которые изучались в значительной степени, включают аллофаны, каолиниты, хлориты (причем предпочитают пользоваться донбасситом, а не судоитом для диоктоздрических разновидностей, алуштит (или тосудит), монотермит и разные цинк-содержащие глины. Много внимания уделяется физикохимическим и колоидно-химическим свойствам. Природное нахождcние и изменение глни и глинистых минералов описывается в зонах выветривания и окисления, в почвенных слоях, а также в недавних и древних осадках. Описываются первичные глинистые минералы гидротермального происхождения.

Type
Research Article
Information
Clays and Clay Minerals , Volume 16 , Issue 1 , June 1968 , pp. 3 - 14
Copyright
Copyright © 1968, The Clay Minerals Society

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Footnotes

*

An invited paper presented at the 16th Clay minerals Conference, Denver, Colorado.

References

Afanass'ev, A. P. (1966) Mineralogy of the preglacial weathering zone on the Kola peninsula and of associated vermiculite deposits: Nauka (Science Publishers); Moscow (Russian).Google Scholar
Arkhipenko, D. K., Grigor'eva, T. N. and Kovaleva, L. T. (1963) Comparison of oxonium content by X-rays and infrared spectroscopy: Rentgenografiya minera'nogo syria (Radiography of Minerals) 3, 78-84 (Russian).Google Scholar
Borovko, N. G. (1960) Halloysite from Tertiary deposits of Bashkiriya, Zapiski: Vsesoyuznogo Mineralog. Obschestva (Records of the All-Union Mineralogical Society) 89, 361-364 (Russian).Google Scholar
Chukhrov, F. V. (1960) Mineralogy and zonality of Eastern Kounrad: Trudy Instituta geologii rudnykh mestorozhdeniï, petrografii, mineralogii i geokhimii Akademii Nauk SSSR (Transactions of the Institute of geology of ore deposits, petrography, mineralogy and geochemistry of Academy of Sciences of U.S.S.R.) 50 (Russian).Google Scholar
Chukhrov, F. V., Berkhin, S. I., Ermilova, L. P., Moleva, V. A. and Rudnitskaya, E. S. (1965) Allophanes from some deposits of the U.S.S.R.: Proc. Intern. Clay Conf., Stockholm, Pergamon Press, New York 2, 19–28.Google Scholar
Chukhrov, F. V., Berkhin, S. I., Ermilova, L. P., Moleva, V. A. and Rudnitskaya, E. S. (1964). The problem of allophanes: Izv. Akad. Nauk SSSR, Ser. Geol. (Reports of the Academy of Sciences of U.S.S.R.) 4, 3-19 (Russian).Google Scholar
Chukhrov, F. V., Rudnitskaya, E. S., Moleva, V. A. and Ermilova, L. P. (1965) On phosphate allophanes: Izv. Akad. Nauk SSSR, Ser. Geol. (Reports of the Academy of Sciences of U.S.S.R.), 3, 51–57 (Russian).Google Scholar
Chukhrov, F. V. and Zvyagin, B. B. (1966) Halloysite, a crystallochemically and mineralogically distinct species: Proc. Intern. Clay Conf., Jerusalem 1, 11–25.Google Scholar
Chukhrov, F. V. (1962) Sur la genèse des minéraux argilleux dans la zone d'altération superficielle des gites métallifères. Genèse et Synthèse des Argiles. Paris Centre Nation. Rech. Scientif. 159–166.Google Scholar
Chukhrov, F. V., Zvyagin, V. V., Rudnitskaya, E. S. and Ermilova, L. P. (1966) On the nature and genesis of halloysites: Izv. Akad. Nauk SSSR, Ser. Geo). (Reports of the Academy of Sciences of U.S.S.R.) 5, 3-20 (Russian).Google Scholar
Demidova, N. G. (1959) On dickite from the Tibsk mercury deposit (Northern Caucasus): Vestn. Mosk. Univ. (Herald of Moscow State University), Ser. Biol., Pochvovde., Geol. i Geogr. 2, 135–140 (Russian).Google Scholar
D'yakonov, Yu. S. (1962) On a direct decipering of X- ray patterns of mixed-layer minerals by the Fourier conversion technique: Rentgenografiya mineral'nogo syria 1, 97–107 (Russian).Google Scholar
Drits, V. A. and Kossovskaya, A. G. (1963) Sangarite — A new clay mineral with ordered mixed-layer structure: Doki. Akad. Nauk SSSR (Reports of the Academy of Sciences of U.S.S.R.) 151, 934-937 (Russian).Google Scholar
Drits, V. A. and Lazarenko, E. K. (1967) Structural-mineralogical characteristics of donbassites: Minera-logicheski$$ sbornik L'vovsk. gosudarstv. univ. In press (Russian).Google Scholar
Drits, V. A., Murav'ev, V. I. and Shutov, V. D. (1966) New aspects of an optical study of phyllosilicates. Voprosy mineralogii osadochnykh obrazovani$$ (Problems of the mineralogy of sedimentary formations) Lvov State University Press 7, 15-31 (Russian).Google Scholar
Drits, V. A. and Shutov, V. D. (1966) New variety of mixed-layer mineral of the sudoite group: Litologiya i poleznye iskopaemye (Lithology and Mineral Resources), No. 4, 130-133 (Russian).Google Scholar
Drits, V. A., Zvyagin, V. V. and Tokmakov, P. P. (1966) Gümbelite — a 2 M2 dioctahedral mica: Doki Akad. Nauk SSSR 170, 1390–1393 (Russian).Google Scholar
Dsotsenidze, G. S. and Machabeli, G. A. (1963) The genesis of bentonites of Georgian SSR: Proc. Intern. Clay Conf, Stockholm 2, 203–210.Google Scholar
Fishkin, M. Yu.. (1963) Dickite from secondary quartzites of Beregovo foot-hills in Transcarpathia. Mineralogic- heski$$ shorn. L'vovsk. geol. obschestva 17, 214–220 (Russian).Google Scholar
Frank-Kamenetski$$, V. A., Logvinenko, N. V. and Drits, V. A. (1965) Tosudite —a new mineral, comprising the mixed-layer phase in alushtite: Proc. Intern. Clay Conf, Stockholm 2, 181–186.Google Scholar
Ginzburg, I. I. and Rukavishnikova, I. A. (1952) Pelicanites and opals of Kos-shoku (Northern Kazakhstan) and their comparison with the Ukrainian minerals: Kora vyvetrivaniya (The weathering zone) 1, 138-157 (Russian).Google Scholar
Golovanov, I. M. (1960) Zinc-bearingserpophyte —anew variety of serpophyte: Doki. Akad. Nauk Uz. SSR, No. 5, 19-23 (Russian).Google Scholar
Gorbunov, N. I. (1964) Clay and accompanying minerals of the primary soil types. Physika, khimia, biologia i mineralogia pochv SSSR, Nauka, Moscow, 316-324 (Russian).Google Scholar
Gorbunov, N. I., Gradusov, B. P. and Travnikova, L. S. (1964) Formation and properties of vermiculites in connection with their use in agriculture: Pochvovedenie (Soil Science), No. 11, 1-10 (Russian).Google Scholar
Gorskov, A. I. (1966) Use of microdiffraction in studying halloysite crystallites: Kristallografiya 11, 589–598 (Russian).Google Scholar
Gradusov, B. P. (1967) Rectorite in soils: Doki. Akad. Nauk SSSR, Ser. Geol 172, No. 1-3, 181-183 (Russian).Google Scholar
Gradusov, B. P., Gorbunov, N. I., Trapenznikova, L. S. and Zvereva, T. S. (1966) On the genesis and properties of a soil vermiculite: Issledovaniya prirodnogo i tech-nicheskogo mineraloobrazovaniya, Nauka, Moscow, 246–249 (Russian).Google Scholar
Gritsaenko, G. S. and Gorshkov, A. I. (1966) Electron- microscopic study of crystal lattices and their defects by direct observation and with the help of the moiré method: Fizicheskie metody issledovania mineralov osadochnykh porod. (Physical methods of investigation of minerals in sedimentary rocks).Google Scholar
Gritsaenko, G. S. and Samotoyin, N. D. (1966) The decoration method applied to the study of clay minerals: Proc. Intern. Clay Conf., Jerusalem 1, 391–399.Google Scholar
Gumenski$$, B. M. (1960) Role of water transformation in the physical condition of clay earths during vibration (for example, in vibratory drilling): Materialy k sobraniyu Mezhdunarodnoi Komissii po izucheniu glin (Data for a meeting of the international commission for the study of clays), 123-130 (Russian).Google Scholar
Il'inskaiya, G. G. (1966) On a study of microstructural and microtextural properties of clay and loess rocks by electron microscopy: Vestn. Mosk. Univ., Ser. 4, No. 6, 87-92 (Russian).Google Scholar
Ivkin, M. M., Kita$$gorodski$$, N. S., Kotel'nikov, D. D. and Korolev, Yu. M. (1959) Analogue of allevardite (from Daghestan): Zap. Vses. Mineralog. Obschestva 88, 554–563 (Russian).Google Scholar
Karpova, G. V. (1966) On paragonitic hydromicas in terrigenous rocks of the Great Donets Basin: Dokl. Akad. Nauk SSSR 171, No. 2, 443-445 (Russian).Google Scholar
Kashka$$, M. A. (1965) Petrology and metallogeny of Dashkesan: Nedra, Moscow, 509–513 (Russian).Google Scholar
Kossovskaya, A. G., Drits, V. A. and Alexandrova, V. A. (1965) On trioctahedral micas in sedimentary rocks: Proc. Intern. Clay Conf., Stockholm 2, 147–169.Google Scholar
Kovalev, G. A. (1947) X-ray determination of the modification of a Crimean mineral of the dickite group: Zap. Vses. Mineralog. Obshchestva 76, 229–238 (Russian).Google Scholar
Kruglitski$$, N. N. (1966) Control of structural-mechanical properties in clay mineral dispersions: Proc. Intern. Clay Conf, Jerusalem 1, 311–318.Google Scholar
Kruglitski$$, N. N. (1967) Physico-chemical principles for control of the properties of clay mineral dispersions: Akad. Nauk U.S.S.R., Kiev (Russian).Google Scholar
Kukovski$$, E. G. (1963) On mineralogical alterations in the weathering zone of crystalline rocks in the southern part of the Ukrainian shield: Kora vyvetrivaniya (The weathering zone) 5, 35–48.Google Scholar
Kychakov, A. Kh.. (1958) Problems of the use of clays from Troshkovsk deposit and the prospects of expanding the clay reserves of the Troshkovsk type: Mesto- rozhdeniya estestv. Stroit, materialov fliusovogo i glinistogo syria Vostochnoi Sibiri (Deposits of natural structural materials, of fluxing and clayey raw materials of Eastern Siberia). Akademiya Nauk, Moscow (Russian).Google Scholar
Lyashkevich, E. M. (1962) Sodium-containing variety of allevardite: Mineralogicheski$$ sbornik L'vovsk. geol. obshchestva 16, 421–430 (Russian).Google Scholar
Logvinenko, N. V. and Frank-Kamenetski$$, V. A. (1961) Essays on the mineralogy of clay minerals: Vestn. Leningr. Univ. (Herald of Leningrad State University), No. 24, Geol. and Geogr. Ser. 4, 42–56 (Russian).Google Scholar
Merabishvili, M. S. (1962) Bentonite clays: Gosgeol-tekhnizdat (State Publishing House for Geological- Technical Literature), Moscow (Russian).Google Scholar
Nakovnik, N.I. (1940) Dickite from secondary quartzites of the Kazakh steppe: Zap. Vses. Mineralog. Obshchestva 69, 472–476 (Russian).Google Scholar
Ovcharenko, F. D. (1961) Hydrophilicity of clays and clay minerals: Akad. Nauk U.S.S.R., Kiev (Russian).Google Scholar
Ovcharenko, F. D. (1961) The control of colloid- chemical properties of clay minerals: Proc. Intern. Clay Conf., Jerusalem 1, 299–310.Google Scholar
Ovcharenko, F. D., Kirichenko, N. G., Kovalenko, D. I. and Rastrenenko, A. I. (1958) Ukrainian bentonites: Akad. Nauk U.S.S.R., Kiev (Russian).Google Scholar
Ovcharenko, F. D., Kirichenko, N. G., Ostrovskaya, A. V. and Dovgi$$, M. G. (1966) Cherkassk deposit of bentonite and palygorskite clays: Nauk. dumka, Kiev (Russian).Google Scholar
Ovcharenko, F. D., Kukovski$$, E. G., Nichiporenko, S. P., Vdovenko, N. V., Tretinnik, V. Yu., Kruglitski$$, N. P. and Panasevich, A. P. (1963) Colloidal chemistry of palygorskite: Akad. Nauk U.S.S.R., Kiev (Russian).Google Scholar
Ovcharenko, F. D., Nichiporenko, S. N., Kruglitski$$, N. N. and Tretinnik, V. Yu. (1965) Research on the physico-chemical mechanics of clay mineral dispersion: Akad. Nauk U.S.S.R., Kiev (Russian).Google Scholar
Petrov, V. P. and Rubanov, I. V. (1960) The kaolins of Angren, their material composition, formation conditions and uses: Akad. Nauk Uz. SSR, Tashkent (Russian).Google Scholar
Petrov, V. P. (1967) Fundamentals of ancient weathering zones: Nedra, Moscow (Russian).Google Scholar
Petrov, V. P. and Tokmakov, P. P. (1965) On the nature of sungulite: Proc. Intern. Clay Conf, Stockholm 2, 211–217.Google Scholar
Priklonski$$, V. A., et al. (1958) Investigation of the engineering-geological properties of clays and clay rocks: Issledovanie i ispol'zovanie glin (The Study and Utilization of Clays). L'vov. univ., L'vov University Press, L'vov. 263–362 (Russian).Google Scholar
Rateev, M. A. (1964) Distribution and genesis of clay minerals in Recent and Ancient marine sediments: Nauka, Moscow (Russian).Google Scholar
Razumova, V. N. and Kheraskov, N. P. (1963) Geological types of weathering zones: Doklady Akademii Nauk SSSR 148, 1378–81.Google Scholar
Rozhkov, I. S. (1963) Ancient weathering zone on kimberlite rocks: The weathering zone 6, 203–225 (Russian).Google Scholar
Rukavishnikova, I. A. (1958) Some data on the weathering of serpentinites: Materiały po geologii, mineralogii i ispol'zovaniyu glin v SSSR (Data on the geology, mineralogy and use of clays in U.S.S.R.) Moscow (Russian).Google Scholar
Rus'ko, Yu. A. (1961) On the nature of monothermite: Mineralogichesk$$ sbornik L'vovskogo geol. obshchestva, No. 15, 239-254 (Russian).Google Scholar
Serb-Serbina, N. N. and Rebinder, P. A. (1958) Physico- chemical bases for controlling the structural and mechanical properties of clay and clay rocks: Materiały po geologii, mineralogii i isspol'zovaniyu glin v U.S.S.R. (Data on the geology, mineralogy and use of clays in U.S.S.R.). Akad. Nauk SSSR, Moscow, 115–130 (Russian).Google Scholar
Sergeev, E. M., Il'inskaya, G. G., Rekshinskaya, L. G. and Trofimov, V. G. (1963) On the development of clay minerals in connection with their engineering- geological study: Vestn. Mosk. Univ. No. 3, 3-9 (Russian).Google Scholar
Shutov, V. D., Alexandrova, V. A. and Losievskaya, S. A. (1966) Genetic interpretation of polymorphism in minerals of the kaolinite group in sedimentary rocks: Fizicheskie metody izucheniya minerálov osadochnykh porod (Physical methods of investigation of minerals of sedimentary rocks), Akad. Nauk SSSR, Moscow, 109–122 (Russian).Google Scholar
Smoľyaninova, N. N., Moleva, V. A. and Organova, N. I. (1960) New aluminum-free member of the mont- morillonite-sauconite series: Doki. k sobraniyu mezhdunarodno$$ komissii po izucheniyu glin (Report to the Meeting of the International Commission for the Study of Clays). Akademiya Nauk SSSR, Moscow, 45–51 (Russian).Google Scholar
Titkov, N. I., Petrov, V. P. and Neretina, A. Ya. (1964) Formation of minerals and structures in the electrochemical strengthening of unstable rocks: Nauka, Moscow (Russian).Google Scholar
Vikulova, M. F. and Zvyagin, B. B. (1965) Effect of conditions of formation of clay rocks upon the development and alteration of structural features in clay minerals: Sovetskaya geologiya, No. 5, 24-37 (Russian).Google Scholar
Vlasov, V. V. and Drits, V. A. (1967) Study of an endogenetic dioctahedral chlorite: Rentgenographiya mineral'nogo syria 6. In press (Russian).Google Scholar
Zubrilina, S. K. (1964) Dickite of the Aktash deposit: Nauchn. Tr. Tashkentskogo Univ. (Scientific Transactions of Tashkent State University) 234, Geology, 68-83 (Russian).Google Scholar
Zvyagin, B. B. (1964) Order-disorder and diffraction properties of sequences in closely contiguous layers forming the structure of phyllosilicates: Kristallografiya 9, 791–798 (Russian).Google Scholar
Zvyagin, B. B. (1967) Electron Diffraction Analysis of Clay Mineral Structures: Plenum Press, New York.CrossRefGoogle Scholar
Zvyagin, V. V. and Berkhin, S. I. (1966) Structural features of halloysite from X-ray and electron diffraction data: Rentgenografiya mineratnogo syria 5, 69–93 (Russian).Google Scholar
Zvyagin, V. V. and Gorshkov, A. I. (1966) Effects of secondary diffraction by mineral crystals superimposed with a relative rotation around the primary beam observed in selected area patterns: Proc. 6th Intern. Congress Electr. Microscopy. Kyoto.Google Scholar
Zvyagin, V. V. and Mishchenko, K. S. (1965) Diagnostics of single packet semiordered polymorphic chlorite modifications: Kristallografiya 10, 555–557 (Russian).Google Scholar
Zvyagin, V. V., Mishchenko, K. S. and Shitov, V. A. (1966) Investigation of polymorphic varieties of serpentine-like minerals by electron diffraction: Fizicheskie metody issledovaniya mineralov osadochnykh porod (Physical methods of investigation of the minerals in sedimentary rocks). Nauka, Moscow, 130–137 (Russian).Google Scholar
Zvyagin, V. V. and Shcheglov, A. D. (1962) Nacrite from a fluorite deposit of Western Transbaikal area and its structural features from electron diffraction data: Dokl. Akad. Nauk SSSR 142, 185–188 (Russian).Google Scholar