Hostname: page-component-77c89778f8-swr86 Total loading time: 0 Render date: 2024-07-19T02:58:01.923Z Has data issue: false hasContentIssue false
  • English
  • Français

Differential Release of Potassium from Interstratified Mica Clay Minerals as Related to Probable Differences in Their Mica Layer Components

Published online by Cambridge University Press:  01 July 2024

G. J. Ross  and
H. Kodama
G. J. Ross
Affiliation:
Soil Research Institute, Canada Department of Agriculture, Ottawa, Ontario, Canada
H. Kodama
Affiliation:
Soil Research Institute, Canada Department of Agriculture, Ottawa, Ontario, Canada
Get access Rights & Permissions [Opens in a new window]

Abstract

Release of potassium by extraction with solutions containing sodium tetraphenyl boron or by leaching with 0·1 N barium chloride seemed to be related to the nature of the mica layers in the interstratified minerals studied. The rate of potassium release was lower when the calculated Si/AlIV ratio of the mica component layers resembled muscovite and higher when this ratio was intermediate between muscovite and pyrophyllite. This supported a recent hypothesis that the composition and structure of the mica component layers may vary in different interstratified minerals of similar total chemical composition.

Résumé

Résumé

Dans les minéraux interstratifiés observés, la libération de potassium par extraction avec des solutions contenant du tétraphényl-bore de sodium, ou par lavage avec du chlorure de barium 0,1N semble être en relation avec le nature des couches de mica. Le taux de libération du potassium diminue lorsque le rapport Si/AlIV calculé des couches de mica ressemble à celui de la muscovite, et augmente quand ce rapport est intermédiaire entre celui de la niuscovite et de la pyrophillite. Ceci appuie une récente hypothèse selon laquelle la composition et structure des couches de mica peuvent varier dans des différents minéraux interstratifiés de composition chimique totale similaire.

Kurzreferat

Kurzreferat

Die Freigabe von Kalium durch Extraktion mit Natriumtetraphenylbor enthaltende Lösungen oder durch Auslaugen mit 0,1 N Bariumchlorid stand scheinbar in Beziehung zu der Natur der Glimmerschichten in den zur Untersuchung gelangenden zwischengelagerten Mineralen. Die Geschwindigkeit der Kaliumfreigabe war niedriger wenn das errechnete Si/AlIV Verhältnis der Glimmerbestandteilschichten dem Muskowit ähnelte und höher wenn dieses Verhältnis zwischen Muskowit und Pyrophyllit lag. Das bekräftigt eine vor kurzem aufgestellte Hypothese, wonach die Zusammensetzung und das Gefüge der Glimmerbestandteilschichten in verschiedenen zwischengelagerten Mineralen ähnlicher chemischer Gesamtsusammensetzung veränderlich sein kann.

Резюме

Резюме

Экстракция калия растворами, содержащими натриевый тетрафенил-бор, или растворами 0,1 N хлорида бария, по-видимому, зависит от природы слюдяных слоев изученных смешаннослойных минералов. Скорость извлечения калия была ниже, если вычисленное отношение Si/AlIV слюдяного компонента было близким к мусковитовому; при значении указанного отношения между мусковитовым и пирофиллитовым скорость извлечения калия была выше. Это подтверждает недавно сформулированную гипотезу, согласно которой состав и структура слюдяного компонента слоев может варьировать в различных смешаннослойных минералах одного и того же валового химического состава.

Type
Research Article
Information
Clays and Clay Minerals , Volume 18 , Issue 3 , August 1970 , pp. 151 - 156
Copyright
Copyright © The Clay Minerals Society 1970

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

*

Contribution No. 315.

References

Bassett, W. A., (1959) The origin of the vermiculite deposit at Libby, Montana: Am. Mineralogist 44, 282–299.Google Scholar
Brown, G. and Weir, A. H. (1963) An addition to the paper “The identity of rectorite and allevardite”: international Clay Conference 1963, 2, 87–90. Pergamon Press, Oxford.Google Scholar
Cook, M. G. and Rich, C. I. (1962) Weathering of sodium-potassium mica in soils of the Virginia Piedmont: Soil Sci. Soc. Am. Proc. 26, 591–595.CrossRefGoogle Scholar
Kodarna, H. (1966) The nature of the component layers of rectorite: Am. Mineralogist 51, 1035–1055.Google Scholar
Kodarna, H. and Brydon, J. E. (1968) Dehydroxylation of microcrystalline muscovite: Trans. Faraday Soc. 64, 3112–3119.Google Scholar
Kodarna, H., Shimoda, S. and Sudo, T. (1969) Hydrous mica complexes: their structure and chemical composition: International Clay Conference 1969 1, 185–196. Israel Universities Press, Jerusalem.Google Scholar
Newman, A. C. D. and Brown, G. (1969) Delayed exchange of potassium from some edges of mica flakes: Nature 223, 175–176.CrossRefGoogle Scholar
Reed, M. G. and Scott, A. D. (1966) Chemical extraction of potassium from soils and micaceous minerals with solutions containing sodium tetraphenylboron: IV Muscovite: Proc. Soil Sci. Soc. Am. 30, 185–188.CrossRefGoogle Scholar
Rich, C. I. (1968) Mineralogy of soil potassium, In The role of potassium in agriculture (Edited by Kilmer, V. J., Younts, S. E. and Brady, N. C.). {Am. Soc. Agron., Wisconsin, U.S.A.).Google Scholar
Scott, A. D. (1968) Effect of particle size on interlayer potassium exchange in micas: Ninth international Congress of Soil Science 1968, 2, 649–660.Google Scholar
Scott, A. D., Hunziker, R. R. and Hanway, J. J. (1960) Chemical extraction of potassium from soils and micaceous minerals with solutions containing sodium tetraphenylboron. I. Preliminary Experiments: Proc. Soil Sci. Soc. Am. 24, 191–194.CrossRefGoogle Scholar
Schwertmann, U. (1962) Eigenschaften und Bildung aufweitbarer (quellbarer) Dreischicht-Tonminerale in Böden aus Sedimenten: Beiträge zur Mineral und Petrogr. 8, 199–209.Google Scholar
Sudo, T., Hayashi, H. and Shimoda, S. (1962) Mineralogical problems of intermediate clay minerals: Clays and Clay Minerals. 9, 378–392. (Pergamon Press, New York).CrossRefGoogle Scholar
Weir, A. H. and Greene-Kelly, R. (1962) Beidellite: Am. Mineralogist 47, 137–146.Google Scholar