Hostname: page-component-7479d7b7d-rvbq7 Total loading time: 0 Render date: 2024-07-13T19:37:20.787Z Has data issue: false hasContentIssue false

Dye adsorption by hydrous alumina in soils

Published online by Cambridge University Press:  27 March 2009

H. H. Croucher
Affiliation:
(Imperial College of Tropical Agriculture, Trinidad, B.W.I.)

Extract

1. A historical review of the dye adsorption method for the estimation of soil colloids is presented, and the method is criticised chiefly from the point of view of the isoelectric theory.

2. A procedure for the detection of hydrous alumina in soils is described, involving the demonstration of the isoelectrio point of hydrous alumina by means of preferential dye adsorption in suspensions of various pH values.

3. Satisfactory results were obtained with a mixture of acidic Biebrich Scarlet and basic Iodine Green. The former is adsorbed by hydrous alumina only on the acid side of its isoelectric point, and the latter only on the alkaline side.

4. The characteristics of an ideal dye for use in studies such as those described are tabulated.

5. The applicability of the mixture of dye-stuffs finally selected is demonstrated for a series of soils of varying basic ratio, and including examples of lateritic soils and clays.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1928

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

(1)Rohland, Glasind (1915), 26; Chem. Abs. 9, 2701.Google Scholar
(2)Graf Zu, Leiningen. Koll. Z. (1916), 19,165; Chem. Abs. 11, 3076.Google Scholar
(3)Hardy, . J. Phys. Chem. (1926), 30, 254.CrossRefGoogle Scholar
(4)Way, J.Roy. Agri. Soc. (1850), 11, 313379; Ashley. U.S. Geol. Survey Bull. (1909), 388.Google Scholar
(5)Warington, J. Chem. Soc. (1868), 6, 1.CrossRefGoogle Scholar
(6)Tschermak, Zeit. Phys. Chem. (1905), 53, 349; J. Chem. Soc. Abs. 2, 88, 816.CrossRefGoogle Scholar
(7)Ashley, U.S. Geol. Survey Bull. (1909), 388.Google Scholar
(8)Beaumont, Mem. 21, Cornell Univ. Agr. Expt. Sta. (1919).Google Scholar
(9)Wood, and Wooller, . J. Soc. Dyers and Col. (1925), 41, 47; J. Chem. Soc. Abs. 2, 128, 285.CrossRefGoogle Scholar
(10)Bancroft, J. Phys. Chem. (1914), 18, 118; J. Chem. Soc. Abs. 2, 106, 250.CrossRefGoogle Scholar
(11)Wilkinson, and Hoff, . J. Phys. Chem. (1925), 29, 808.CrossRefGoogle Scholar
(12)Testoni, Ann. Chim. Appl. (1926), 16, 45; Chem. Abs. 20, 1931.Google Scholar
(13)Bechold, Koll. Z. (1918), 23, 35; J. Chem. Soc. Abs. 1, 114, 516.CrossRefGoogle Scholar
(14)Sjollema, J. Landw. (1905), 53, 67; J. Chem. Soc. Abs. 2, 88, 195.Google Scholar
(15)Rohland, Z. Anorg. Chem. (1914), 89, 164; J. Chem. Soc. Abs. 2, 108, 424 Koll. Z. 15, 180; J. Chem. Soc. Abs. 2, 108, 234.CrossRefGoogle Scholar
(16)Hanley, J. Agric. Sci. (1914), 6, 58.CrossRefGoogle Scholar
(17)Gile, Middleton, Robinson, Fry, and Anderson, U.S. Dept. Agric. (1924), Bull. 1193.Google Scholar