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Evaporation of volatile-liquid lenses floating on an immiscible-liquid surface: effects of the surface age and fluid purities in n-pentane/water system

Published online by Cambridge University Press:  21 April 2006

T. Nosoko
Affiliation:
Department of Mechanical Engineering, Keio University, Yokohama 223, Japan
T. Ohyama
Affiliation:
Department of Mechanical Engineering, Keio University, Yokohama 223, Japan
Y. H. Mori
Affiliation:
Department of Mechanical Engineering, Keio University, Yokohama 223, Japan

Abstract

This paper describes a fundamental study of evaporation of volatile-liquid lenses due to the heat supply from the substrate of an immiscible, less-volatile liquid under the atmosphere of the common vapours of the two fluid substances. Experiments were performed with single n-pentane lenses placed on the surface of an otherwise quiescent pool of water. The behaviour of each lens throughout its life was observed in detail using laser shadowgraphy. It was found that the time required for complete evaporation of each lens and the behaviour of the lenses change, in a peculiar but rather regular way, with the age of the water surface. This ageing effect is more significant when fluids of higher purities are used, and it is thought to be due to the quantity of contaminants at the surface increasing with its age.

Type
Research Article
Copyright
© 1985 Cambridge University Press

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References

Bentwich, M., Landau, U. & Sideman, S. 1970 Direct contact heat transfer with change of phase: evaporation of discrete volatile films from the surface of a stagnant immiscible liquid. Intl J. Heat Mass Transfer 13, 945956.Google Scholar
Chandrasekhar, S. 1981 Hydrodynamic and Hydromagnetic Stability, pp. 3436. Dover.
Detwiler, A. & Blanchard, D. C. 1978 Aging and bursting bubbles in trace-contaminated water. Chem. Engng Sci. 33, 913.Google Scholar
Higeta, K., Mori, Y. H. & Komotori, K. 1979 Condensation of a single vapor bubble rising in another immiscible liquid. AIChE Symp. Ser. 75–189, 256265.Google Scholar
Iaps (International Association of the Properties of Steam) 1976 Release on Surface Tension of Water Substance.
Kaneko, M. 1982 Heat transfer to an evaporating lens of volatile liquid floating on a stagnant immiscible liquid (in Japanese). M.Engng thesis, Keio University, Yokohama.
Kaneko, M. & Mori, Y. H. 1984 Evaporation of a volatile-liquid lens floating on the surface of a stagnant immiscible liquid. Intl Comm. Heat Mass Transfer 11, 209218.Google Scholar
Kitchener, J. A. & Cooper, C. F. 1959 Current concepts in the theory of foaming. Q. Rev. 13, 7197.Google Scholar
Kodres, C. A., Jacobs, H. R. & Boehm, R. F. 1979 Heat transfer to an evaporating, floating lens. ASME Paper 79-HT-13. Presented at the 18th Nat. Heat Transfer Conf., San Diego, Calif.
Kodres, C. A., Jacobs, H. R. & Boehm, R. F. 1980 A numerical method for determining direct-contact heat transfer rates to a superheated evaporating floating droplet. Numer. Heat Transfer 3, 2134.Google Scholar
Langmuir, I. 1933 Oil lenses on water and the nature of monomolecular expanded films. J. Chem. Phys. 1, 756776.Google Scholar
Mori, Y. H., Tsui, N. & Kiyomiya, M. 1984 Surface and interfacial tensions and their combined properties in seven binary, immiscible liquid-liquid-vapor systems. J. Chem. Engng Data 29, 407412.Google Scholar
Mysels, K. J. & Florence, A. T. 1970 Techniques and criteria in the purification of aqueous surfaces. In Clean Surfaces: Their Preparation and Characterization For Interfacial Studies (ed. G. Goldfinger), pp. 227268. Marcel Dekker.
Sparrow, E. M., Goldstein, R. J. & Jonsson, V. K. 1964 Thermal instability in a horizontal fluid layer: effect of boundary conditions and non-linear temperature profile. J. Fluid Mech. 18, 513528.Google Scholar
Yang, W.-J. & Nouri, A. 1981 Interfacial turbulence in minute drops evaporating on a flat plate. Lett. Heat Mass Transfer 8, 115125.Google Scholar