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An optical dustbin made by the subwavelength-induced super-black carbon aerogels

Published online by Cambridge University Press:  05 September 2017

Hongqiang Wang
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Ai Du*
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Zhihua Zhang*
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Bin Zhou
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
Jun Shen
Affiliation:
Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China
*
a)Address all correspondence to these authors. e-mail: duai@tongji.edu.cn
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Abstract

Super-black carbon aerogel sleeves (CAS) with different reflectivities and a clear aperture had been made, by the sol–gel polycondensation of resorcinol (R) and formaldehyde (F) under the catalysis of sodium carbonate (C), and was used to eliminate stray light. We explained that the subwavelength structure is the main factor that leads to the low reflectivity of CA and constructed a simple optical system to measure the exit power from CAS in different directions. We proved that different CASs have different matting effects, and all of these CASs have better matting effects than that of monolithic graphite that has higher reflectivity. To show the fine angular resolution ability of CAS, we measured the faculae from the reflected light of a compact disc and found that the CAS with a clear aperture of 1.0 mm is the best. The super-black CAS could be used in precision optical instruments and to eliminate stray light in the optical.

Type
Invited Paper
Copyright
Copyright © Materials Research Society 2017 

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Footnotes

Contributing Editor: Winston V. Schoenfeld

References

REFERENCES

Pekala, R.W.: Organic aerogels from the polycondensation of resorcinol with formaldehyde. J. Mater. Sci. 24, 3221 (1989).Google Scholar
Schwan, M. and Ratke, L.: Flexible carbon aerogels. Carbon 2, 22 (2016).Google Scholar
Li, W. and Guo, S.: Preparation of low-density carbon aerogels from a cresol/formaldehyde mixture. Carbon 38, 1520 (2000).Google Scholar
Wu, D., Fu, R., Zhang, S., Dresselhaus, M.S., and Dresselhaus, G.: Preparation of low-density carbon aerogels by ambient pressure drying. Carbon 42, 2033 (2004).CrossRefGoogle Scholar
Wu, D., Fu, R., Sun, Z., and Yu, Z.: Low-density organic and carbon aerogels from the sol–gel polymerization of phenol with formaldehyde. J. Non-Cryst. Solids 351, 915 (2005).Google Scholar
Feng, J., Feng, J., Jiang, Y., and Zhang, C.: Ultralow density carbon aerogels with low thermal conductivity up to 2000 °C. Mater. Lett. 65, 3454 (2011).CrossRefGoogle Scholar
Feng, J., Feng, J., and Zhang, C.: Thermal conductivity of low density carbon aerogels. J. Porous Mater. 19, 551 (2012).CrossRefGoogle Scholar
Sun, H., Xu, Z., and Gao, C.: Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels. Adv. Mater. 25, 2554 (2013).Google Scholar
Guo, K., Hu, Z., Song, H., Du, X., Zhong, L., and Chen, X.: Low-density graphene/carbon composite aerogels prepared at ambient pressure with high mechanical strength and low thermal conductivity. RSC Adv. 5, 5197 (2014).Google Scholar
Biener, J., Stadermann, M., Suss, M., Worsley, M.A., Biener, M.M., Rose, K.A., and Baumann, T.F.: Advanced carbon aerogels for energy applications. Energy Environ. Sci. 4, 656 (2011).Google Scholar
Elkhatat, A.M. and Al-Muhtaseb, S.A.: Advances in tailoring resorcinol-formaldehyde organic and carbon gels. Adv. Mater. 23, 2887 (2011).Google Scholar
Job, N., Théry, A., Pirard, R., Marien, J., Kocon, L., Rouzaud, J-N., Béguin, F., and Pirard, J-P.: Carbon aerogels, cryogels and xerogels: Influence of the drying method on the textural properties of porous carbon materials. Carbon 43, 2481 (2005).Google Scholar
Al-Muhtaseb, S.A. and Ritter, J.A.: Preparation and properties of resorcinol–formaldehyde organic and carbon gels. Adv. Mater. 15, 101 (2003).CrossRefGoogle Scholar
Zubizarreta, L., Menéndez, J.A., Job, N., Marco-Lozar, J.P., Pirard, J.P., Pis, J.J., Linares-Solano, A., Cazorla-Amorós, D., and Arenillas, A.: Ni-doped carbon xerogels for H2 storage. Carbon 48, 2722 (2010).Google Scholar
Singh, S., Bhatnagar, A., Dixit, V., Shukla, V., Shaz, M.A., Sinha, A.S.K., Srivastava, O.N., and Sekkar, V.: Synthesis, characterization and hydrogen storage characteristics of ambient pressure dried carbon aerogel. Int. J. Hydrogen Energy 41, 3561 (2016).Google Scholar
Lin, K-S., Mai, Y-J., Chiu, S-W., Yang, J-H., and Chan, S.L.I.: Synthesis and characterization of metal hydride/carbon aerogel composites for hydrogen storage. J. Nanomater. 2012, 1 (2012).Google Scholar
Tian, H.Y., Buckley, C.E., Sheppard, D.A., Paskevicius, M., and Hanna, N.: A synthesis method for cobalt doped carbon aerogels with high surface area and their hydrogen storage properties. Int. J. Hydrogen Energy 35, 13242 (2010).Google Scholar
Wencui Li, G.R. and Fricke, J.: Carbon aerogels derived from cresol resorcinol formaldehyde for supercapacitors. Carbon 40, 2955 (2001).Google Scholar
Pröbstle, H., Wiener, M., and Fricke, J.: Carbon aerogels for electrochemical double layer capacitors. J. Porous Mater. 10, 213 (2003).Google Scholar
Kim, S.J., Hwang, S.W., and Hyun, S.H.: Preparation of carbon aerogel electrodes for supercapacitor and their electrochemical characteristics. J. Mater. Sci. 40, 725 (2005).Google Scholar
Lai, F., Miao, Y-E., Zuo, L., Zhang, Y., and Liu, T.: Carbon aerogels derived from bacterial cellulose/polyimide composites as versatile adsorbents and supercapacitor electrodes. Chem. Nanostruct. Mater. 2, 212 (2016).Google Scholar
Zu, G., Shen, J., Zou, L., Wang, F., Wang, X., Zhang, Y., and Yao, X.: Nanocellulose-derived highly porous carbon aerogels for supercapacitors. Carbon 99, 203 (2016).Google Scholar
Catalão, R.A., Maldonado-Hódar, F.J., Fernandes, A., Henriques, C., and Ribeiro, M.F.: Reduction of NO with metal-doped carbon aerogels. Appl. Catal., B 88, 135 (2009).Google Scholar
Tian, H., Wu, J., Zhang, W., Yang, S., Li, F., Qi, Y., Zhou, R., Qi, X., Zhao, L., and Wang, X.: High performance of Fe nanoparticles/carbon aerogel sorbents for H2S removal. Chem. Eng. J. 313, 1051 (2016).Google Scholar
Meier, S.R., Korwi, M.L., and Merzbacher, C.I.: Carbon aerogel a new nonreflective material for the infrared. Appl. Opt. 39, 3940 (2000).Google Scholar
Merzbacher, C.I., Meier, S.R., Pierce, J.R., and Korwin, M.L.: Carbon aerogels as broadband non-reflective materials. J. Non-Cryst. Solids 285, 210 (2001).Google Scholar
Vukusic, P., Sambles, J.R., and Lawrence, C.R.: Structurally assisted blackness in butterfly scales. Proc. Biol. Sci. 271(Suppl. 4), S237 (2004).Google Scholar
Chen, Q., Hubbard, G., Shields, P.A., Liu, C., Allsopp, D.W.E., Wang, W.N., and Abbott, S.: Broadband moth-eye antireflection coatings fabricated by low-cost nanoimprinting. Appl. Phys. Lett. 94, 263118 (2009).Google Scholar
Zhao, Q., Fan, T., Ding, J., Zhang, D., Guo, Q., and Kamada, M.: Super black and ultrathin amorphous carbon film inspired by anti-reflection architecture in butterfly wing. Carbon 49, 877 (2011).Google Scholar
Zhu, J., Yang, X., Fu, Z., Wang, C., Wu, W., and Zhang, L.: Facile fabrication of ultra-low density, high-surface-area, broadband antireflective carbon aerogels as ultra-black materials. J. Porous Mater. 23, 1217 (2016).Google Scholar
Yang, Z-P., Hsieh, M-L., Bur, J.A., Ci, L., Hanssen, L.M., Wilthan, B., Ajayan, P.M., and Lin, S-Y.: Experimental observation of extremely weak optical scattering from an interlocking carbon nanotube array. Appl. Opt. 50, 1850 (2011).Google Scholar
Sun, W., Du, A., Feng, Y., Shen, J., Huang, S., Tang, J., and Zhou, B.: Super black material from low-density carbon aerogels with subwavelength structures. ACS Nano 10, 9123 (2016).CrossRefGoogle ScholarPubMed
Ganesan, K., Dennstedt, A., Barowski, A., and Ratke, L.: Design of aerogels, cryogels and xerogels of cellulose with hierarchical porous structures. Mater. Des. 92, 345 (2016).Google Scholar
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