Hostname: page-component-848d4c4894-4rdrl Total loading time: 0 Render date: 2024-07-07T16:00:54.414Z Has data issue: false hasContentIssue false
  • English
  • Français

Fe-metalloids bulk glassy alloys with high Fe content and high glass-forming ability

Published online by Cambridge University Press:  31 January 2011

Akihiro Makino ,
Takeshi Kubota ,
Chuntao Chang ,
Masahiro Makabe  and
Akihisa Inoue
Akihiro Makino
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Takeshi Kubota*
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Chuntao Chang
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Masahiro Makabe
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
Akihisa Inoue
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan
*
a)Address all correspondence to this author. e-mail: kubott@imr.tohoku.ac.jp
Get access

Abstract

The coexistence of high Fe content and high glass-forming ability (GFA) has been earnestly desired from academia to industry. We report a novel Fe76Si9B10P5 bulk metallic glass with an unusual combination of high magnetization of 1.51 T due to high Fe content as well as high GFA leading to a glassy rod with a diameter of 2.5 mm despite not containing any glass-forming metal elements. This alloy composed of familiar and low-priced elements, also exhibiting very excellent magnetic softness, has a great advantage for engineering and industry, and thus should make a contribution to energy saving and conservation of earth’s resources and environment.

Keywords

AmorphousFerromagneticMagnetic properties
Type
Articles
Information
Journal of Materials Research , Volume 23 , Issue 5 , May 2008 , pp. 1339 - 1342
Copyright
Copyright © Materials Research Society 2008

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Inoue, A.Shen, B.L.: New Fe-based bulk glassy alloys with high saturated magnetic flux density of 1.4–1.5 T. Mater. Sci. Eng., A 375–377, 302 2004CrossRefGoogle Scholar
2Inoue, A.Park, R.E.: Soft magnetic properties and wide supercooled liquid region of Fe–P–B–Si base amorphous alloys. Mater. Trans., JIM 37, 1715 1996CrossRefGoogle Scholar
3Mizushima, T., Ikarashi, K., Makino, A.Inoue, A.: Structure and magnetic properties of bulky Fe–Al–Ga–P–C–B–Si glassy alloys in a ringed form prepared by copper mold casting. IEEE Trans. Mag. 35, 3361 1999CrossRefGoogle Scholar
4Koshiba, H., Inoue, A.Makino, A.: Fe-based soft magnetic amorphous alloys with a wide supercooled liquid region. J. Appl. Phys. 85, 5136 1999CrossRefGoogle Scholar
5Shen, B.L., Akiba, M.Inoue, A.: Effect of Si and Mo additions on glass-forming in FeGaPCB bulk glassy alloys with high saturation magnetization. Phys. Rev. B 73, 104204 2006CrossRefGoogle Scholar
6Makino, A., Inoue, A.Mizushima, T.: Soft magnetic properties of Fe-based bulk amorphous alloys. Mater. Trans., JIM 41, 1471 2000CrossRefGoogle Scholar
7Makino, A., Bitoh, T., Inoue, A.Greer, A.L.: Soft magnetic bulk glassy alloy synthesized by flux melting and water quenching. Mater. Sci. Forum 539–543, 1921 2007CrossRefGoogle Scholar
8Inoue, A., Shen, B.L.Chang, C.T.: Super-high strength of over 4000 MPa for Fe-based bulk glassy alloys in [(Fe1−xCox)0.75B0.2Si0.05]96Nb4 system. Acta Mater. 52, 4093 2004CrossRefGoogle Scholar
9Chang, C.T., Shen, B.L.Inoue, A.: FeNi-based bulk glassy alloys with superhigh mechanical strength and excellent soft-magnetic properties. Appl. Phys. Lett. 89, 051912 2006CrossRefGoogle Scholar
10Okamoto, P.R., Lam, N.Q.Rehn, L.E.: Physics of crystal-to-glass transformations in Solid State Physics edited by H. Ehrenreich and F. Spaepen, Academic Press San Diego, CA 1999 Vol. 52, 1–133Google Scholar
11Fujimori, H., Ohta, S., Masumoto, T.Nakajima, K.: Magnetic after-effect on soft magnetic properties of amorphous ferromagnets in Rapidly Quenched Metals III, edited by B. Cantor The Metal Society London, UK 1978 Vol. 2, 232–239Google Scholar
12Kronmüller, H.: Micromagnetism and microstructure of amorphous alloys. J. Appl. Phys. 52, 1859 1981CrossRefGoogle Scholar
13Kronmüller, H.: Theory of the coercive field in amorphous ferromagnetic alloys. J. Magn. Magn. Mater. 24, 159 1981CrossRefGoogle Scholar
14Bitoh, T., Makino, A.Inoue, A.: Origin of low coercivity of Fe–(Al, Ga)–(P, C, B, Si, Ge) bulk glassy alloys. Mater. Trans. 44, 2020 2003CrossRefGoogle Scholar
15Bitoh, T., Makino, A.Inoue, A.: Origin of low coercivity of (Fe0.75B0.15Si0.1)100−xNbx (x = 1 to 4) glassy alloys. J. Appl. Phys. 99, 08F102 2006CrossRefGoogle Scholar
16Inoue, A., Shinohara, Y.Gook, J.S.: Thermal and magnetic properties of bulk Fe-based glassy alloys prepared by copper mold casting. Mater. Trans., JIM 36, 1427 1995CrossRefGoogle Scholar
17Inoue, A., Takeuchi, A., Zhang, T., Murakami, A.Makino, A.: Soft magnetic properties of bulk Fe-based amorphous alloys prepared by copper mold casting. IEEE Trans. Magn. 32, 4866 1996CrossRefGoogle Scholar
18Zhang, T.Inoue, A.: Bulk glassy alloys in (Fe, Co, Ni)–Si–B system. Mater. Trans. 42, 1015 2001CrossRefGoogle Scholar
19Song, D.D., Kim, J-H., Fleury, E., Kim, W.T.Kim, D.H.: Synthesis of ferromagnetic Fe-based bulk glassy alloys in the Fe–Nb–B–Y system. J. Alloys Compd. 389, 159 2005CrossRefGoogle Scholar
20Lu, Z.P., Tan, H., Li, Y.Ng, S.C.: The correlation between reduced glass transition temperature and glass forming ability of bulk metallic glasses. Scripta Mater. 42, 667 2000CrossRefGoogle Scholar
21Lu, Z.P.Liu, C.T.: A new glass-forming ability criterion for bulk metallic glasses. Acta Mater. 50, 3501 2002CrossRefGoogle Scholar