Hostname: page-component-77c89778f8-vsgnj Total loading time: 0 Render date: 2024-07-22T11:13:03.594Z Has data issue: false hasContentIssue false
  • English
  • Français

Formation of Bulk Glassy Fe75–x–yCrxMoyC15B10 Alloys and Their Corrosion Behavior

Published online by Cambridge University Press:  31 January 2011

Shujie Pang ,
Tao Zhang ,
Katsuhiko Asami  and
Akihisa Inoue
Shujie Pang
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
Tao Zhang
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
Katsuhiko Asami
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
Akihisa Inoue
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
Get access

Abstract

Formation of bulk Fe-based glassy alloys with high corrosion resistance was succeeded in the Fe75–x–yCrxMoyC15B10 alloy system. A large temperature interval of supercooled liquid region (ΔTx) of 40–90 K was obtained over a wide composition range for the Fe75?x–yCrxMoyC15B10 alloys. The Fe75–x–yCrxMoyC15B10 alloys were prepared in a bulk glassy form with diameters of 1.0–2.5 mm by copper mold casting. The bulk glassy Fe75–x–yCrxMoyC15B10 alloys exhibited high corrosion resistance in 1 N HCl solution. The glassy alloys containing Cr were spontaneously passivated with a wide passive region before the transpassive dissolution of Cr. The passive current density decreased significantly with an increase of alloying Cr content, indicating that the addition of Cr was effective on enhancing the corrosion resistance. Excess addition of Mo for replacing Fe in the present alloys was detrimental for the corrosion resistance.

Type
Articles
Information
Journal of Materials Research , Volume 17 , Issue 3 , March 2002 , pp. 701 - 704
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Inoue, A., Ohtera, K., Kitta, K., and Masumoto, T., J. Appl. Phys. 27, L2248 (1988).Google Scholar
Inoue, A., Zhang, T., and Masumoto, T., Mater. Trans. JIM 30, 965 (1989).CrossRefGoogle Scholar
Inoue, A., Zhang, T., and Masumoto, T., Mater. Trans. JIM 31, 177 (1990).CrossRefGoogle Scholar
Peker, A. and Johnson, W.L., Appl. Phys. Lett. 63, 2342 (1993).CrossRefGoogle Scholar
Inoue, A., Shinobara, Y., and Gook, G.S., Mater. Trans. JIM 36, 1427 (1995).CrossRefGoogle Scholar
Inoue, A., Zhang, T., and Takeuchi, A., Appl. Phys. Lett. 71, 464 (1997).CrossRefGoogle Scholar
Inoue, A. and Wang, X.M., Acta Mater. 48, 1383 (2000).CrossRefGoogle Scholar
Naka, M., Hashimoto, K., and Masumoto, T., J. Jpn. Inst. Metals 38, 835 (1974).CrossRefGoogle Scholar
Naka, M., Hashimoto, K., and Masumoto, T., Sci. Rep. RITU A26, 283 (1977).Google Scholar
Naka, M., Hashimoto, K., Inoue, A., and Masumoto, T., J. Non-cryst. Solids 31, 347 (1979).CrossRefGoogle Scholar
Asami, K., Kawashima, K., and Hashimoto, K., Mater. Sci. Eng. 99, 475 (1988).CrossRefGoogle Scholar
Habazaki, H., Kawashima, A., Asami, K., and Hashimoto, K., Corros. Sci. 33, 225 (1992).CrossRefGoogle Scholar
Li, X.Y., Akiyama, E., Habazaki, H., Kawashima, A., Asami, K., and Hashimoto, K., Corros. Sci. 41, 1095 (1999).CrossRefGoogle Scholar
Inoue, A. and Gook, J.S., Mater. Trans. JIM 36, 1282 (1995).CrossRefGoogle Scholar
Inoue, A., Zhang, T., Itoi, T., and Takeuchi, A., Mater. Trans. JIM 38, 359 (1997).CrossRefGoogle Scholar
Inoue, A., Mater. Trans. JIM 36, 866 (1995).CrossRefGoogle Scholar
Metals Databook, edited by Japan Inst. Metals (Maruzen, Tokyo, Japan, 1993), pp. 1–8.Google Scholar
Boer, F.R. de, Boom, R., Mattens, W.C.M., Miedema, A.R., and Niessen, A.K., Cohesion in Metals (North-Holland, Amsterdam, The Netherlands, 1989), pp. 103–637.Google Scholar
Pang, S.J., Zhang, T., Asami, K., and Inoue, A., Corros. Sci., in press.Google Scholar
Asami, K., Naka, M., Hashimoto, K., and Masumoto, T., J. Electrochem. Soc. 127, 2130 (1980).CrossRefGoogle Scholar