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Hydrogen storage properties of mono- and bidentate MOF structured orotate complexes

Published online by Cambridge University Press:  10 January 2014

Zeynel Ozturk ,
Dursun Ali Kose ,
Abdurrahman Asan ,
Banu Ozturk ,
Omer Andac  and
Goksel Ozkan
Zeynel Ozturk*
Affiliation:
Department of Chemical Engineering, Hitit University, 19030 Corum, Turkey
Dursun Ali Kose
Affiliation:
Department of Chemistry, Hitit University, 19030 Corum, Turkey
Abdurrahman Asan
Affiliation:
Department of Chemical Engineering, Hitit University, 19030 Corum, Turkey
Banu Ozturk*
Affiliation:
Department of Chemistry, Hitit University, 19030 Corum, Turkey
Omer Andac
Affiliation:
Department of Chemistry, Ondokuz Mayıs University, 55139 Samsun, Turkey
Goksel Ozkan
Affiliation:
Department of Chemical Engineering, Gazi University, 06520 Ankara, Turkey
*
a)Address all correspondence to this author. e-mail: zeynelozturk61@yahoo.com, zeynelozturk@hitit.edu.tr
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Abstract

One of the barriers for wide usage of hydrogen energy system is efficient storage. To store more hydrogen efficiently, physisorption is a choice among the others with high storage performance, reversibility, and lifecycles. Metal organic framework (MOF) structured organometallic orotate-Co(II) complexes could serve as sorbents which store hydrogen by physisorption. In this work, mono- and bidentate MOF structured orotate-Co(II) complexes are synthesized, characterized, and then investigated for hydrogen storage experimentally and theoretically. It is found that these compounds could store hydrogen. Especially, the monodentate complex could uptake hydrogen better than the other. Storage performances for mono- and bidentate complexes were 0.80 and 1.15 wt% at 77 K and approximately 80 bars experimentally, 1.03 and 1.16 wt% theoretically for the same conditions.

Keywords

orotate complexmono- and bidentateMOFshydrogen storage
Type
Articles
Information
Journal of Materials Research , Volume 29 , Issue 2 , 28 January 2014 , pp. 215 - 220
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Nijkamp, M.G., Raaymakers, J.E.M.J., van Dillen, A.J., and Jong, K.P.: Hydrogen storage using physisorption - materials demands. Appl. Phys. A 72, 619–623 (2001).Google Scholar
Cirujano, F.G., Xamena, F.X.L., and Corma, A.: MOFs as multifunctional catalysts: One-pot synthesis of menthol from citronellal over a bifunctional MIL-101 catalyst. Dalton Trans. 41, 4249–4254 (2012).Google Scholar
Liu, B.: Metal–organic framework-based devices: Separation and sensors. J. Mater. Chem. 22, 10094 (2012).Google Scholar
Li, J.R., Kuppler, R.J., and Zhou, H.C.: Selective gas adsorption and separation in metal–organic frameworks. Chem. Soc. Rev. 38, 1477 (2009).Google Scholar
El-Safty, S.: Organic–inorganic hybrid mesoporous monoliths for selective discrimination and sensitive removal of toxic mercury ions. J. Mater. Sci. 44, 6764 (2004).CrossRefGoogle Scholar
Li, Y. and Yang, R.T.: Gas adsorption and storage in metal−organic framework MOF-177. Langmuir 23(26), 12937 (2007).CrossRefGoogle ScholarPubMed
An, J. and Rosi, N.L.: Tuning MOF CO2 adsorption properties via cation exchange. J. Am. Chem. Soc. 132(16), 5578 (2010).Google Scholar
Wu, H., Zhou, W., and Yildirim, T.: High-capacity methane storage in metal-organic frameworks M2(dhtp): The important role of open metal sites. J. Am. Chem. Soc. 131(13), 4995 (2009).Google Scholar
Rosi, N.L., Eckert, J., Eddaoudi, M., Vodak, D.T., Kim, J., O’Keeffe, M., and Yaghi, O.M.: Hydrogen storage in microporous metal-organic frameworks. Science 300(5622), 1127 (2003).CrossRefGoogle ScholarPubMed
Zheng, B., Yun, R., Bai, J., Lu, Z., Du, L., and Li, Y.: Expanded porous MOF-505 analogue exhibiting large hydrogen storage capacity and selective carbon dioxide adsorption. Inorg. Chem. 52(6), 2823 (2013).Google Scholar
Singh, A.K. and Yakobson, B.I.: First principles calculations of H-storage in sorption materials. J. Mater. Sci. 47, 7356 (2012).CrossRefGoogle Scholar
Lim, W.X., Thornton, A.W., Hill, A.J., Cox, B.J., Hill, J.M., and Hill, M.R.: High performance hydrogen storage from be-BTB metal–organic framework at room temperature. Langmuir 29(27), 8524 (2013).Google Scholar
Yang, Q. and Zhong, C.: Molecular simulation of adsorption and diffusion of hydrogen in metal-organic frameworks. J. Phys. Chem. B 109(24), 11862 (2005).Google Scholar
Jorgensen, W.L., Maxwell, D.S., and Tirado-Rives, J.: Development and testing of the OPLS all-atom force field on conformational energetics and properties of organic liquids. J. Am. Chem. Soc. 118, 11225 (1996).Google Scholar
Lencioni, S., Pellerito, A, Fiore, T., Giuliani, A.M., Pellerito, L., Cambria, M.T., and Mansueto, C.: Organometallic complexes with biological molecules. X: Dialkyltin(IV) and trialkyltin(IV) orotates: Spectroscopic and in vivo investigations. Appl. Organometal. Chem. 13(3), 145 (1999).3.0.CO;2-6>CrossRefGoogle Scholar
Darensbourg, A.J., Larkins, D.L., and Reibenspies, J.H.: Bis(triphenylphosphine)copper(I) complexes of orotate and L-dihydroorotate. Inorg. Chem. 37(23), 6125 (1998).CrossRefGoogle Scholar
Kose, D.A., Zumreoglu, K.B., Sahin, O., and Buyukgungor, O.: Transition metal(II) complexes of vitamin B13 with monodentate orotate(1−) ligands. J. Mol. Struct. 789(1–3), 147 (2006).Google Scholar
Sahin, O., Buyukgungor, O., Kose, D.A., Zumreoglu, K.B., and Necefoglu, H.: Catena-poly[[[triaquacobalt(II)]-mu-2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylato(2-)] 1.72-hydrate]. Acta Cryst. C62, 513 (2006).Google Scholar
Kaye, S.S., Dailly, A., Yaghi, O.M., and Long, J.R.: Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5). J. Am. Chem. Soc. 129, 14176 (2007).Google Scholar
Rouquerol, J., Avnir, D., Fairbridge, C.W., Everett, D.H., Haynes, J.M., Pernicone, N., Ramsay, J.D.F., Sing, K.S.W., and Unger, K.K.: Recommendations for the characterization of porous solids (technical report). Pure Appl. Chem. 66(8), 1739 (1994).Google Scholar
Assfour, B., Leoni, S., Yurchenko, S., and Seifert, G.: Hydrogen storage in zeolite imidazolate frameworks. A multiscale theoretical investigation. Int. J. Hydrogen Energy 36(10), 6005 (2011).Google Scholar