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Hydrothermal Synthesis of Submicron SnO Crystallites

Published online by Cambridge University Press:  31 January 2011

Dien-Shi Wu  and
Nae-Lih Wu
Dien-Shi Wu
Affiliation:
Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan 106, Republic of China
Nae-Lih Wu*
Affiliation:
Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan 106, Republic of China
*
a)Address all correspondence to this author.
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Abstract

SnO crystallites having a size ranging 0.1–0.2 μm were synthesized by a hydrothermal process, which consisted of prolonged solution aging under pH = 1.0, followed by hydrothermal treatment under pH = 9 to 10 at 75–95 °C. Oxidation of Sn+2 to Sn+4 during the hydrothermal stage was effectively inhibited by increasing the solution-aging time. This was attributed to the formation, upon aging, of polymeric hydrous SnO colloids, which are more oxidation resistant than aquo-hydroxo tin complex monomers. For solutions with a sufficiently long (≥240 h) aging time, the SnO yield increased with increasing pH and temperature during the hydrothermal treatment.

Type
Rapid Communications
Information
Journal of Materials Research , Volume 15 , Issue 7 , July 2000 , pp. 1445 - 1448
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

1.Idota, Y., Matsufuji, A., Maekawa, Y., and Miyasaka, T., Science 276, 1395 (1997).CrossRefGoogle Scholar
2.Wang, J., Raistrick, I.D., and Huggins, R.A., J. Electronchem. Soc. 133, 457 (1986).CrossRefGoogle Scholar
3.Courtney, I.A. and Dahn, J.R., J. Electrochem. Soc. 144, 2045 (1997).CrossRefGoogle Scholar
4.Courtney, I.A. and Dahn, J.R., J. Electrochem. Soc. 144, 2943 (1997).CrossRefGoogle Scholar
5.Sakamoto, J.S., Huang, C.K., Surampudi, S., Smart, M., and Wolfenstine, J., Mater. Lett. 33, 327 (1998).CrossRefGoogle Scholar
6.Wolfenstine, J., Sakamoto, J.S., and Huang, C.K., J. Power Sources 75, 181 (1998).Google Scholar
7.Fujita, K., Nakamura, C., Matsuda, K., and Mitsuzawa, S., Bull. Chem. Soc. Jpn. 63, 2718 (1990).CrossRefGoogle Scholar
8.Wu, N.L. and Wu, L.F., J. Am. Ceram. Soc. 82, 67 (1999).CrossRefGoogle Scholar
9.Brinker, C.J. and Scherer, G.W., Sol-Gel Science (Academic Press, San Diego, CA, 1990), pp. 22–59.Google Scholar
10.Wu, N.L., Wu, L.F., Yang, Y.C., and Huang, S.J., J. Mater. Res. 11, 813 (1996).CrossRefGoogle Scholar