Hostname: page-component-77c89778f8-gq7q9 Total loading time: 0 Render date: 2024-07-20T14:27:31.018Z Has data issue: false hasContentIssue false
  • English
  • Français

Lead titanate glass-ceramics derived from a silicate-based melt

Published online by Cambridge University Press:  03 March 2011

P. Sooksaen ,
I.M. Reaney  and
D.C. Sinclair
P. Sooksaen*
Affiliation:
Department of Engineering Materials, University of Sheffield, Sheffield S1 3JD, United Kingdom
I.M. Reaney
Affiliation:
Department of Engineering Materials, University of Sheffield, Sheffield S1 3JD, United Kingdom
D.C. Sinclair
Affiliation:
Department of Engineering Materials, University of Sheffield, Sheffield S1 3JD, United Kingdom
*
a) Address all correspondence to this author. e-mail: p_sooksaen@hotmail.com
Get access

Abstract

Glass composition 39PbO–1BaO–25TiO2–9.8Al2O3–24.2SiO2–1B2O3 (mol%) crystallized on heat treatment at ≥600 °C to form glass-ceramics whose majority phase was PbTiO3 (PT). At 600 °C, nano-size PT crystals (∼20–50 nm) with a c/a ratio of 1.000(1) were observed, but as heat-treatment temperature increased to 1000 °C, the crystal size and c/a ratio increased to ∼1.2 μm and 1.056(4), respectively. Permittivity measurements as a function of temperature revealed a broad peak at ∼400 °C associated with the nanocrystalline PT crystals, but it sharpened and increased in temperature as heat treatment temperature increased to 1000 °C. The causes of peak broadening and shift of Tc are believed to be due to either clamping of PT crystals by glass matrix, finite size effects due to their intrinsically small size, or the incorporation of dopant impurities such as Al, Si, or Ba ions in the PT phase.

Keywords

CrystalDielectric propertiesGlass
Type
Articles
Information
Journal of Materials Research , Volume 20 , Issue 5 , May 2005 , pp. 1316 - 1323
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Lines, M.E. and Glass, A.M.: Principles and Applications of Ferroelectrics and Related Materials (Oxford University Press, Oxford, U.K., 1979).Google Scholar
2.Herbert, J.M.: Ceramic Dielectrics and Capacitors (Gordon and Breach, New York, 1985).Google Scholar
3.Moulson, A.J. and Herbert, J.M.: Electroceramics, Materials-Properties-Applications (Chapman & Hall, London, U.K., 1996).Google Scholar
4.Jiang, B., Peng, J.L. and Bursill, L.A.: Size effects on ferroelectricity of ultrafin particles of PbTiO3. J. Appl. Phys. 8, 3462 (2000).CrossRefGoogle Scholar
5.Heartling, G.H.: Ferroelectric ceramics: History and technology. J. Am. Ceram. Soc. 82, 798 (1999).Google Scholar
6.Jaffe, B., Cook, W.R. Jr., and Jaffe, H.: Piezoelectric Ceramics (Academic Press, Inc., London, U.K., 1971).Google Scholar
7.Lee, S.W. and Shim, K.B.: Ferroelectric anomaly in the differential thermal analysis of PbTiO3 glass. Mater. Lett. 38, 356 (1999).CrossRefGoogle Scholar
8.Phillips, N.J., Calzada, M.L., and Milne, S.J.: Sol-gel-derived lead titanate films. Journal of Non-Crystalline Solids Proceedings of the International Workshop on Glasses and Ceramics from Gels, Oct 6-11 1991, 1992, 147-48, pp. 285–290.Google Scholar
9.Zhang, P.L., Zhong, W.L., Wang, S.L., Wang, Y.G. and Ding, Z.Y.: Sol-gel derived PbTiO3 films on a polar glass ceramic substrate. Integrated Ferroelectrics 4, 45 (1994).CrossRefGoogle Scholar
10.Jiwei, Z., Xi, Y. and Liangying, Z.: The high frequency properties and crystallisation of PbTiO3 glass-ceramics by sol-gel process. J. Electroceram. 5(3), 211 (2000).CrossRefGoogle Scholar
11.Blum, J.B. and Gurkovich, R.R.: Sol-gel-derived PbTiO3. J. Mater. Sci. 20, 4479 (1985).CrossRefGoogle Scholar
12.Zhu, T., Han, G., Zhao, G., Ding, Z. and Zhengfu, H.: Preliminary Raman investigation of the lead titanate thin films via sol gel process. J. Mater. Sci. Technol. 13(4), 306 (1997).Google Scholar
13.Yao, K. and Zhang, L.: Preparation and structure of BaTiO3 ferroelectric glass-ceramics. Chin. Sci. Bull. 40, 694 (1995).Google Scholar
14.Herczog, A.: Microcrystalline BaTiO3 by crystallization from glass. J. Am. Ceram. Soc. 47(3), 107 (1964).CrossRefGoogle Scholar
15.Strnad, Z.: Glass-Ceramic Materials, Glass Science and Technology, Vol. 8. (Elsevier, Prague, Czechoslovakia, 1986).Google Scholar
16.McMillan, P.W.: Glass-Ceramics (Academic Press, London, U.K., 1964).Google Scholar
17.Layton, M.M. and Herzog, A.: Nucleation and crystallization of NaNbO3 from glasses in the Na2O–Nb2O5–SiO2 system. J. Am. Ceram. Soc. 50, 369 (1967).CrossRefGoogle Scholar
18.Cable, M. and Parker, J.M.: High Performance Glasses (Chapman and Hall, New York, 1992).Google Scholar
19.Wu, M. and Zhu, P.: Piezoelectricity, pyroelectricity and ferroelectricity in glass-ceramics based on PbTiO3. J. Non-Cryst. Solids 84, 344 (1986).Google Scholar
20.Bergeron, C.G. and Russell, C.K.: Nucleation and growth of lead titanate from a glass. J. Non-Cryst. Solids 48(3), 115 (1965).Google Scholar
21.Bergeron, C.G. and Russell, C.K.: Structural changes preceding growth of a crystalline phase in lead silicate glass. J. Am. Ceram. Soc. 48, 162 (1965).Google Scholar
22.Ding, Y., Osaka, A. and Miura, Y.: Surface crystallization of lead titanate from glass enhanced by ultrasonic treatment with suspension. J. Non-Cryst. Solids 176, 200 (1994).CrossRefGoogle Scholar
23.Grossman, D.G. and Isard, J.O.: Lead titanate glass-ceramics. J. Am. Ceram. Soc. 52 4(1969).CrossRefGoogle Scholar
24.Grossman, D.G. and Isard, J.O.: Crystal clamping in PbTiO3 glass-ceramics. J. Mater Sci. 4, 1059 (1969).CrossRefGoogle Scholar
25.Kokubo, T. and Tashiro, M.: Dielectric properties of fine-grained PbTiO3 crystals precipitated in a glass. J. Non-Cryst. Solids 13, 328 (1973).CrossRefGoogle Scholar
26.Kui, Y. and Liangying, Z.: Characterization of PbTiO3 crystallites in-situ confined grown in amorphous silica. Ferroelectric Lett. 19, 113 (1995).CrossRefGoogle Scholar
27.Lodder, J.C. and Burggraaf, A.J.: Microstructure development and crystallization kinetics of PbTiO3 from PbO–TiO2–Al2O3–SiO2 glass. Glass Technol. 15(16), 143 (1974).Google Scholar
28.Shyu, J.J. and Yang, Y.S.: Crystallization of a PbO–BaO– TiO2–Al2O3–SiO2 glass. J. Am. Ceram. Soc. 78(6), 1463 (1995).CrossRefGoogle Scholar
29.Shyu, J.J. and Yang, Y.S.: Crystallization and properties of a perovskite glass-ceramic. J. Mater. Sci. 31, 4859 (1996).CrossRefGoogle Scholar
30.Arlt, G. and Hennings, D.: Dielectric properties of fine-grained barium titanate ceramics. J. Appl. Phys. 58 4(1985).CrossRefGoogle Scholar
31.Lynch, S.M. and Shelby, J.E.: Crystal clamping in lead titanate glass-ceramics. J. Am. Ceram. Soc. 67 6(1984).CrossRefGoogle Scholar
32.Martirena, H.T. and Burfoot, J.C.: Grain size effects on properties of some ferroelectric ceramics. J. Phys. C: Solid State. Phys. 7, 3182 (1974).CrossRefGoogle Scholar
33.Ruiz-Valdes, J.J., Gorokhovsky, A.V. and Escalante-Garcia, J.I.: Glass-ceramic materials with regulated dielectric properties based on the system BaO–PbO–TiO2–B2O3–Al2O3. J. Eur. Ceram. Soc. 24, 1505 (2004).CrossRefGoogle Scholar
34.Binder, K.: Finite size effects on phase transition. Ferroelectrics 73, 43 (1987).CrossRefGoogle Scholar
35.Ishikawa, K.: Size effect on the phase transition in ferroelectric fine particles, in Integrated Ferroelectrics, Proceedings of the 1996 International Symposium on Applications of Ferroelectric Thin Films, 1998.20(1–4), pp. 273–274.Google Scholar
36.Wada, S., Suzuki, T. and Noma, T.: Hydrothermal synthesis of nm-sized lead titanate crystallite and its size effect. Key Eng. Mater. 169–170, 253 (1999).CrossRefGoogle Scholar