Hostname: page-component-77c89778f8-cnmwb Total loading time: 0 Render date: 2024-07-22T15:36:49.572Z Has data issue: false hasContentIssue false
  • English
  • Français

Mechanical and water barrier properties of corn-protein-based biodegradable plastics

Published online by Cambridge University Press:  31 January 2011

Lodovico di Gioia ,
Bernard Cuq  and
Stéphane Guilbert
Lodovico di Gioia
Affiliation:
Unitdé Technologie des Céréales et des Agro-polymères, ENSA.M/INRA, 2 Place Viala, 34060 Montpellier Cedex 1, France
Bernard Cuq
Affiliation:
Unitdé Technologie des Céréales et des Agro-polymères, ENSA.M/INRA, 2 Place Viala, 34060 Montpellier Cedex 1, France
Stéphane Guilbert*
Affiliation:
Unitdé Technologie des Céréales et des Agro-polymères, ENSA.M/INRA, 2 Place Viala, 34060 Montpellier Cedex 1, France
*
a)Address all correspondence to this author.guilbert@ensam.inra.fr
Get access

Abstract

Experiments were performed to evaluate the mechanical and water barrier properties of corn-protein-based materials that were compression molded from thermoplastic resins. The influence of varying concentrations of water, glycerol, and octanoic acid was studied. At 0% relative humidity, the material exhibited a linear elastic deformation and a brittle fracture at any glycerol or octanoic acid content. Raising relative humidity from 0% to 97.3%, progressively decreased the tensile strength (from 24.1 to 2.2 MPa and 19.4 to 1.0 MPa), and the modulus of elasticity (from 1.67 to 0.03 GPa and 1.87 to 0.13 GPa), respectively, for the octanoic acid- or glycerol-plasticized materials. Increasing water content did not increase the tensile strain at break of the glycerol-plasticized material, whereas this parameter changed from 1.6 to 52.3% for octanoic-acid-plasticized material. This last material was waterproof during 21 h and its water transmission rate was then 0.05 mmolmm-2 s -1. Differences in water absorption were related to plasticizer solubility and material structure.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 12 , December 2000 , pp. 2612 - 2619
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Gontard, N. and Guilbert, S., in Food Packaging and Preservation, edited by Mathlouthi, M. (Blackie Academic and Professional, Glasgow, 1994), pp. 159–181.CrossRefGoogle Scholar
2.Nawrath, C., Poirier, Y., and Somerville, C., Mol. Breed. 1, 105 (1995).CrossRefGoogle Scholar
3.Borcherding, A. and Luck, T., in Plant Proteins from European Crops, Food and Non-Food Applications, edited by Guéguen, J. and Popineau, Y. (Springer-Verlag, Berlin, 1998), pp. 313–318.CrossRefGoogle Scholar
4.Cuq, B., Gontard, N., and Guilbert, S., Cereal Chem. 75, 1 (1998).CrossRefGoogle Scholar
5.Guilbert, S. and Graille, J., in Valorisations non alimentaires des grandes productoins agricoles, Les colloques no. 71, edited by Gueguen, J. (INRA Editions, Paris, 1994), pp. 195–206.Google Scholar
6.Watson, S.A., in Starch—Chemistry and Technology—II Industrial Aspects, edited by Whistler, R.L. and Pashall, E.F. (Academic Press, New York, 1967), pp. 1–51.Google Scholar
7.Landry, J., Delahaye, S., and Di Gioia, L., Cereal Chem. 76, 503 (1999).CrossRefGoogle Scholar
8.Di Gioia, L., Cuq, B., and Guilbert, S., Cereal Chem. 75, 514 (1998).CrossRefGoogle Scholar
9.Di Gioia, L., Cuq, B., and Guilbert, S., Int. J. Biol. Macromol. 24, 341 (1999).CrossRefGoogle Scholar
10.Rathmann, D.M., Zein, an Annoted Bibliography, 1891–1953, Mellon Institute Bibliographic Series, Bulletin No. 7, (Mellon Institute, Pittsburgh, 1954).Google Scholar
11.Reiners, R.A., Wall, J.S., and Inglett, G.E., in Industrial Uses of Cereals, edited by Pomeranz, Y. (Symp. Proc. of the 58th annual meeting of AACC, St. Louis, MO, 1973), pp. 285–302.Google Scholar
12.di Gioia, L. and Guilbert, S., J. Agric. Food Chem. 47, 1254 (1999).CrossRefGoogle Scholar
13.Hasegawa, N., Suzuki, K., Ishii, T., Hayashi, M., and Danno, G.. Japanese Patent No. 6,192,577 (1994).Google Scholar
14.Sears, J.K. and Darby, J.R., The Technology and Plasticizers (Wiley Interscience, New York, 1982), pp. 35–77.Google Scholar
15.Galietta, G., di Gioia, L., Guilbert, S., and Cuq, B., J. Dairy Sci. 81, 3123 (1998).CrossRefGoogle Scholar
16.Gontard, N., Guilbert, S., and Cuq, J-L., J. Food Sci. 58, 206 (1993).CrossRefGoogle Scholar
17.Lai, H.M., Padua, G.W., and Wei, L.S., Cereal Chem. 74, 83 (1997).CrossRefGoogle Scholar
18.Schilling, C.H., Babcock, T., Wang, S., and Jane, J., J. Mater. Res. 10, 2197 (1995).CrossRefGoogle Scholar
19.Somanathan, N., Naresh, V., Arumugam, V., Ranganathan, T.S., and Sanjeevi, R., Polym. J. 24, 603 (1992).CrossRefGoogle Scholar
20.Cuq, B., Gontard, N., Cuq, J-L., and Guilbert, S., J. Agric. Food Chem. 45, 622 (1997).CrossRefGoogle Scholar
21.Jane, J-L., Lim, S-T., and Paetau, I., in Biodegradable Polymers and Packaging, edited by Ching, C., Kaplan, D.L., and Thomas, E.L. (Technomic, Lancaster, United Kingdom, 1993), pp. 64–73.Google Scholar
22.ASTM, Annual Book of ASTM Standards (American Society for Testing and Material, Philadelphia, PA, 1989).Google Scholar
23.Lawton, J.W., Cereal Chem. 69, 351 (1992).Google Scholar
24.Lai, H.M. and Padua, G.W., Cereal Chem. 74, 771 (1997).CrossRefGoogle Scholar
25.Belitz, H-D., Kieffer, R., Seilmeier, W., and Wieser, H., Cereal Chem. 63, 336 (1986).Google Scholar
26.Herrmann, A.S., Nickel, J., and Riedel, U., Polym. Degrad. Stab. 59, 251 (1998).CrossRefGoogle Scholar
27.Woebcken, W., International Plastics Handbook, edited by Haim, J. and Hyatt, D. (Hanser Publishers, Munich, 1995).Google Scholar
28.Swallen, L.C., Ind. Eng. Chem. 33, 394 (1941).CrossRefGoogle Scholar