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Solvothermal route to Bi3Se4 nanorods at low temperature

Published online by Cambridge University Press:  31 January 2011

Yuan-fang Liu ,
Jing-hui Zeng ,
Wei-xin Zhang ,
Wei-chao Yu ,
Yi-tai Qian ,
Jin-bo Cao  and
Wan-qun Zhang
Yuan-fang Liu
Affiliation:
Structure Research Laboratory, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
Jing-hui Zeng
Affiliation:
Structure Research Laboratory, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
Wei-xin Zhang
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
Wei-chao Yu
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
Yi-tai Qian*
Affiliation:
Structure Research Laboratory, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
Jin-bo Cao
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
Wan-qun Zhang
Affiliation:
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, 230026, The People's Republic of China
*
a)Address all correspondence to this author. e-mail: ytqian@ustc.edu.cn
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Extract

Nanorods Bi3Se4 were synthesized directly through the reaction between BiCl3 and elemental selenium in an autoclave with hydrazine hydrate as solvent at 165 °C for 10 h. X-ray powder diffraction patterns, x-ray photoelectron spectra, and transmission electron microscope images show that the products are well-crystallized hexagonal Bi3Se4 nanorods. The solvent hydrazine hydrate played an important role in formation and growth of Bi3Se4 nanorods. The possible reaction mechanism was proposed.

Type
Articles
Information
Journal of Materials Research , Volume 16 , Issue 12 , December 2001 , pp. 3361 - 3365
Copyright
Copyright © Materials Research Society 2001

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