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Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework

Published online by Cambridge University Press:  09 January 2012

Ye Yuan ,
Jia Liu ,
Hao Ren ,
Xiaofei Jing ,
Wei Wang ,
Heping Ma ,
Fuxing Sun  and
Huijun Zhao
Ye Yuan
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Jia Liu
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Hao Ren
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Xiaofei Jing
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Wei Wang
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Heping Ma
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Fuxing Sun*
Affiliation:
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Huijun Zhao
Affiliation:
Griffith School of Environment, Griffith University, Queensland 4222, Australia
*
a)Address all correspondence to this author. e-mail: zhugs@jlu.edu.cn
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Abstract

Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.

Keywords

CrystallinePolymerX-ray diffraction
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 10: Focus Issue: Crystallization Processes in Polymer-Based Materials , 28 May 2012 , pp. 1417 - 1420
Copyright
Copyright © Materials Research Society 2012

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