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Synthesis, crystal structure, and thermoelectric properties of a new layered carbide (ZrC)3[Al3.56Si0.44]C3

Published online by Cambridge University Press:  31 January 2011

Koichiro Fukuda ,
Miyuki Hisamura ,
Yusuke Kawamoto  and
Tomoyuki Iwata
Koichiro Fukuda*
Affiliation:
Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
Miyuki Hisamura
Affiliation:
Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
Yusuke Kawamoto
Affiliation:
Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
Tomoyuki Iwata
Affiliation:
Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
*
a)Address all correspondence to this author. e-mail: fukuda.koichiro@nitech.ac.jp
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Abstract

A new quaternary layered carbide, (ZrC)3[Al3.56Si0.44]C3, has been synthesized and characterized by x-ray powder diffraction and thermopower and electrical conductivity measurements. The crystal structure was successfully determined using direct methods and further refined by the Rietveld method. The crystal is trigonal (space group R3m*, Z = 3) with lattice dimensions a = 0.331389(7), c = 4.90084(7) nm, and V = 0.46610(1) nm3. The final reliability indices calculated from the Rietveld refinement were Rwp = 9.53% (S = 1.70), Rp = 7.22%, RB = 1.81%, and RF = 0.94%. The crystal structure is composed of the NaCl-type [Zr3C4] slabs separated by the Al4C3-type [Al0.89Si0.11C] layers. This material had thermoelectric properties comparable to the layered carbides (ZrC)2[Al3.56Si0.44]C3 (Zr2[Al3.56Si0.44]C5), (ZrC)2Al3C2, and (ZrC)3Al3C2 in the temperature range of 373–1273 K, with the maximal power-factor value of 6.6 × 10−5 W m−1K−2 at 545 K. The two quaternary carbides have been found to form a homologous series with the general formula of (ZrC)n[Al3.56Si0.44]C3 (n = 2 and 3).

Keywords

Crystallographic structureX-ray diffraction (XRD)Thermoelectricity
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 10 , October 2007 , pp. 2888 - 2894
Copyright
Copyright © Materials Research Society 2007

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References

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