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Solid-state mechanical alloying of plastic crystals

Published online by Cambridge University Press:  31 January 2011

J. Font ,
J. Muntasell ,
E. Cesari  and
J. Pons
J. Font
Affiliation:
Departament de Física i Eng. Nuclear, Univ. Politècnica de Catalunya, Avda. Diagonal 647, E-08028 Barcelona, Spain
J. Muntasell
Affiliation:
Departament de Física i Eng. Nuclear, Univ. Politècnica de Catalunya, Avda. Diagonal 647, E-08028 Barcelona, Spain
E. Cesari
Affiliation:
Departament de Física, Univ. Illes Balears, Crtra. de Valldemossa km 7.5, E-07071 Palma de Mallorca, Spain
J. Pons
Affiliation:
Departament de Física, Univ. Illes Balears, Crtra. de Valldemossa km 7.5, E-07071 Palma de Mallorca, Spain
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Abstract

Ball milling has been used as a solid-state mechanical alloying technique in two binary systems of plastic crystals: neopentylglycol/pentaglycerin (NPG/PG), showing a partial solubility in the ordered phase, and 2-amino-2-methyl-1,3-propanediol/tris(hydroxymethyl) (AMP/TRIS) whose immiscibility in this ordered solid phase is almost total. For the AMP/TRIS system the stable state at room temperature was reached by milling. Contrarily, for NPG/PG, DSC measurements reveal that an annealing period is required after milling. These results have been compared with those of the pentaglycerin/pentaerythritol (PG/PE) binary system, previously studied, whose miscibility is total at room temperature.

Type
Articles
Information
Journal of Materials Research , Volume 12 , Issue 12 , December 1997 , pp. 3254 - 3259
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1.Font, J. and Muntasell, J., Mater. Res. Bull. XXIX, 1091 (1994).Google Scholar
2.Barrio, M., Font, J., López, D. O., Muntasell, J., Tamarit, J. Ll., and Haget, Y., J. Chim. Phys. 91, 189 (1994).CrossRefGoogle Scholar
3.Barrio, M., Font, J., López, D. O., Muntasell, J., Tamarit, J. Ll., Chanh, N. B., and Haget, Y., J. Chim. Phys. 87, 1835 (1990).CrossRefGoogle Scholar
4.Barrio, M., Font, J., Muntasell, J., Tamarit, J. Ll., Chanh, N. B., and Haget, Y., J. Chim. Phys. 87, 255 (1990).CrossRefGoogle Scholar
5.Font, J. and Muntasell, J., Mater. Res. Bull. XXX, 479 (1995).CrossRefGoogle Scholar
6.Pochet, P., Tominez, E., Chaffron, L., and Martin, G., Phys. Rev. B 52, 4006 (1995).CrossRefGoogle Scholar
7.Schwarz, R. B. and Rubin, J. B., J. Alloys Compounds 194, 189 (1993).CrossRefGoogle Scholar
8.Zielinski, P. A., Schulz, R., Kaliaguine, S., and Van Neste, A., J. Mater. Res. 8, 2985 (1993).Google Scholar
9.Zaluski, L., Tessier, P., Ryan, D. H., Doner, C. B., Zaluska, A., Ström-Olsen, J. O., Trudeau, M. L., and Schulz, R., J. Mater. Res. 8, 3059 (1993).CrossRefGoogle Scholar
10.Font, J., Muntasell, J., Cesari, E., and Pons, J., J. Mater. Res. 11, 1069 (1996).CrossRefGoogle Scholar
11.Barrio, M., Font, J., López, D. O., Muntasell, J., Tamarit, J. Ll., Negrier, P., and Haget, Y.. J. Phys. Chem. Solids 55, 1295 (1994).CrossRefGoogle Scholar
12.Font, J. and Muntasell, J., J. Mater Chem. 5, 1137 (1995).CrossRefGoogle Scholar