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Synthesis and characterization of monodisperse metalloporphyrin nanospheres

Published online by Cambridge University Press:  31 January 2011

Chunhui Li ,
Wanjie Wang  and
Yanxia Cao
Chunhui Li*
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
Yanxia Cao
Affiliation:
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
*
a) Address all correspondence to this author. e-mail: lch@zzu.edu.cn
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Abstract

Uniform monodisperse nanospheres of tetra-kis(4-methoxylphenyl) porphynatemanganese (III) chloride [MnIII(TMOPP)Cl] of about 200 nm have been synthesized through a facile surfactant-assisted reprecipitation method at room temperature. Scanning electron microscopy, transmission electron microscope, infrared spectrum, ultraviolet–visible spectrum, and elemental analysis were adopted to characterize the as-prepared metalloporphyrin nanostructures. The influence factors in the reaction to the sizes and morphologies of porphyrin nanoparticles were discussed. The sizes of porphyrin nanoparticles were affected mainly by the porphyrin concentration and only monodisperse nanoshperes with high uniformity in sizes and shapes can self-assemble to form order two-dimensional superstructures.

Keywords

CompositeNanostructureSelf-assembly
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 12 , December 2009 , pp. 3510 - 3515
Copyright
Copyright © Materials Research Society 2009

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