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Kelvin Probe Microscopy of Localized Electric Potentials Induced in Insulating Materials by Electron Irradiation

Published online by Cambridge University Press:  01 December 2004

Marion A. Stevens-Kalceff
Affiliation:
School of Physics & Electron Microscope Unit, University of New South Wales, Sydney, NSW 2052 Australia
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Abstract

Kelvin probe microscopy (KPM) is a specialized atomic force microscopy technique in which long-range Coulomb forces between a conductive atomic force probe and a specimen enable the electrical potential at the surface of a specimen to be characterized with high spatial resolution. KPM has been used to characterize nonconductive materials following their exposure to stationary electron beam irradiation in a scanning electron microscope (SEM). Charged beam irradiation of poorly conducting materials results in the trapping of charge at either preexisting or irradiation-induced defects. The reproducible characteristic surface potentials associated with the trapped charge have been mapped using KPM. Potential profiles are calculated and compared with observed potential profiles giving insight into the charging processes and residual trapped charge distributions.

Type
Research Article
Copyright
© 2004 Microscopy Society of America

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References

REFERENCES

ASI Instruments Inc. (2002). Dielectric Constant Reference Guide. Houston, TX: ASI Instruments Inc.
Belhaj, M., Jbara, O., Filippov, M.N., Rau, E.I., & Andrianov, M.V. (2001). Analysis of two methods of measurement of surface potential of insulators. Applied Surface Science 177, 5865.Google Scholar
Binnig, G., Roher, H., Gerber, C., & Weibel, E. (1982). Surface studies by scanning tunneling microscopy. Phys Rev Lett 49, 5760.Google Scholar
Binnig, G., Quate, C.F., & Gerber, C. (1986). Atomic force microscope. Phys Rev Lett 56, 930933.Google Scholar
Bonnell, D.A. (2001). Scanning Probe Microscopy and Spectroscopy: Theory, Techniques and Applications. New York: Wiley-VCH.
Bottom, V.E. (1972). Dielectric constants of quartz. J Appl Phys 43, 14931495.Google Scholar
Cazaux, J. (1986a). Some considerations on the electric field induced in insulators by electron bombardment. J Appl Phys 59, 14181430.Google Scholar
Cazaux, J. (1986b). Electrostatics of insulators charged by incident electron beams. J Microsc Spectr Electr 11, 293312.Google Scholar
Cazaux, J. (1996). Electron probe microanalysis of insulating materials. X-ray Spectrometry 25, 265281.Google Scholar
Cazaux, J. (2004). About the mechanisms of charging in EPMA, SEM and ESEM with their time evolution. Microsc Microanal 10, 670684 (this issue).Google Scholar
Goldberg, M., Barfels, T., & Fitting, H.-J. (1998). Cathodoluminescence depth analysis in SiO2-Si systems. Fresenius J Anal Chem 361, 560561.Google Scholar
Joy, D.C. & Joy, C.S. (1995). Dynamic charging in the low voltage SEM. J Micros Soc America 1, 109112.Google Scholar
Kalinin, S.V. & Bonnell, D.A. (2001). Electrostatic and magnetic force microscopy. In Scanning Probe Microscopy and Spectroscopy: Theory, Techniques and Applications, Bonnell, D.A. (Ed.), (pp. 205252). New York: Wiley-VCH.
Kotera, M. & Suga, H. (1988). A simulation of keV electron scattering in a charged up specimen. J Appl Phys 63, 261268.Google Scholar
O'Reilly, E.P. & Robertson, J. (1983). Theory of defects in vitreous silicon dioxide. Phys Rev B, 27, 37803795.Google Scholar
Reimer, L., Golla, U., Bongeler, R.M.K., Schindler, B., & Senkel, R. (1992). Charging of bulk specimens insulating layers and free-supporting films in scanning electron microscopy. Optik 92, 1422.Google Scholar
Stevens-Kalceff, M.A. (2000). Electron irradiation induced radiolytic oxygen generation and micro-segregation in silicon dioxide polymorphs. Phys Rev Lett 84, 31373140.Google Scholar
Stevens-Kalceff, M.A. (2001). Micromodification of silicon dioxide in a variable pressure/environmental scanning electron microscope. Appl Phys Lett 79, 30503052.Google Scholar
Stevens-Kalceff, M.A., Phillips, M.R., & Moon, A.R. (1996). Electron irradiation induced changes in the surface topography of silicon dioxide. J Appl Phys 80, 43084314.Google Scholar
Stevens-Kalceff, M.A., Thorogood, G.T., & Short, K. (1999). Charge trapping and defect segregation in quartz. J Appl Phys 86, 205208.Google Scholar
Sugimura, H., Ishida, Y., Hayashi, K., Takai, O., & Nakagiri, N. (2002). Potential shielding by the surface water layer in Kelvin probe force microscopy. Appl Phys Lett 80, 14591461.Google Scholar