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Statistically Rigorous Silver Nanowire Diameter Distribution Quantification by Automated Electron Microscopy and Image Analysis

Published online by Cambridge University Press:  13 February 2019

Clifford S. Todd Open the ORCID record for Clifford S. Todd [Opens in a new window] ,
William A. Heeschen ,
Peter Y. Eastman  and
Ellen C. Keene
Clifford S. Todd*
Affiliation:
Analytical Science, The Dow Chemical Company, 1897 Building, Midland, MI 48667, USA
William A. Heeschen
Affiliation:
Analytical Science, The Dow Chemical Company, 1897 Building, Midland, MI 48667, USA
Peter Y. Eastman
Affiliation:
Analytical Science, The Dow Chemical Company, 400 Arcola Road, Collegeville, PA 19426, USA
Ellen C. Keene
Affiliation:
Analytical Science, The Dow Chemical Company, 1897 Building, Midland, MI 48667, USA
*
*Author for correspondence: Clifford S. Todd, E-mail: CTodd2@Dow.com
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Abstract

Silver nanowire (AgNW) diameters are typically characterized by manual measurement from high magnification electron microscope images. Measurement is monotonous and has potential ergonomic hazards. Because of this, statistics regarding wire diameter distribution can be poor, costly, and low-throughput. In addition, manual measurements are of unknown uncertainty and operator bias. In this paper we report an improved microscopy method for diameter and yield measurement of nanowires in terms of speed/automation and reduction of analyst variability. Each step in the process to generate these measurements was analyzed and optimized: microscope imaging conditions, sample preparation for imaging, image acquisition, image analysis, and data processing. With the resulting method, average diameter differences between samples of just a few nanometers can be confidently and statistically distinguished, allowing the identification of subtle incremental improvements in reactor processing conditions, and insight into nucleation and growth kinetics of AgNWs.

Keywords

biasdiameter distributionimage analysisnanowiressilver
Type
Materials Applications
Information
Microscopy and Microanalysis , Volume 25 , Issue 3 , June 2019 , pp. 630 - 638
Copyright
Copyright © Microscopy Society of America 2019 

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Footnotes

†

Retired.

References

Al-Saidi, W, Feng, H & Fichthorn, A (2013). Binding of polyvinylpyrrolidone to Ag surfaces: Insight into a structure-directing agent from dispersion-corrected density functional theory. J Phys Chem C 117, 1163–1171.Google Scholar
Athens, GL, McGough, PT, Lunn, JD, Wang, W, Kuo, TC, Todd, C, Goss, JM, Collins, RM, Malek, A & Calverley, EM (2015). Hydrothermal synthesis of silver nanowires and application as transparent conductive materials. Advanced Materials: TechConnect Briefs 1, 211–214. Available at https://briefs.techconnect.org/papers/hydrothermal-synthesis-of-silver-nanowires-and-application-as-transparent-conductive-materials/Google Scholar
Bari, B, Lee, J, Jang, T, Won, P, Ko, SH, Alamgir, K, Arshad, M & Guo, LJ (2016). Simple hydrothermal synthesis of very-long and thin silver nanowires and their application in high quality transparent electrodes. J Mater Chem A 4, 11365–11371.10.1039/C6TA03308CGoogle Scholar
Hu, L, Kim, HS, Lee, J-Y, Peumans, P & Cui, Y (2010). Scalable coating and properties of transparent, flexible, silver nanowire electrodes. ACS Nano 4, 2955–2963.10.1021/nn1005232Google Scholar
Khaligh, HH, Liew, K, Han, Y, Abukhdeir, NM & Goldthorpe, IA (2015). Silver nanowire transparent electrodes for liquid crystal-based smart windows. Sol Energy Mater Sol Cells 132, 337–341.10.1016/j.solmat.2014.09.006Google Scholar
Khanarian, G, Joo, J, Liu, X-Q, Eastman, P, Werner, D, O'Connel, K & Trefonas, P (2013). The optical and electrical properties of silver nanowire mesh films. J Appl Phys 114, 024302.10.1063/1.4812390Google Scholar
Langley, D, Giusti, G, Mayousse, C, Celle, C, Bellet, D & Simonato, J-P (2013). Flexible transparent conductive materials based on silver nanowire networks: A review. Nanotechnology 24, 452001.10.1088/0957-4484/24/45/452001Google Scholar
Li, CH & Tam, PKS (1998). An iterative algorithm for minimum cross entropy thresholding. Pattern Recognit Lett 18, 771–776.Google Scholar
Luo, L-B, Yu, S-H, Qian, H-S & Zhou, T (2005). Large-scale fabrication of flexible silver/cross-linked poly(vinyl alcohol) coaxial nanocables by a facile solution approach. J Am Chem Soc Commun 127, 2822–2823.10.1021/ja0428154Google Scholar
Lunn, J & Malek, A (2015). Methods of Manufacturing High Aspect Ratio Silver Nanowires. Patent US9034075 B2.Google Scholar
Pirsalami, S, Zebarjad, SM & Daneshmanesh, H (2017). An overview of metallic nanowire networks, promising building blocks for next generation transparent conductors: Emergence, fundamentals and challenges. J Electron Mater 46, 4707–4715.10.1007/s11664-017-5467-zGoogle Scholar
Rasband, W (2018). ImageJ Software. National Institutes of Health, USA. Available at http://imagej.nih.gov/ij/ (retrieved March 5, 2018).Google Scholar
Sun, Y, Mayers, B, Herricks, T & Xia, Y (2003). Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence. Nano Lett 3, 955–960.10.1021/nl034312mGoogle Scholar
Yang, W, Li, J, Zhong, Y, Qian, H, Li, Z & Hu, Y (2013). Facile Cl-mediated hydrothermal synthesis of large-scale Ag nanowires from AgCl hydrosol. CrystEngComm 15, 2598–2600.Google Scholar
Zhou, Y, Al-Saidi, W & Fichthorn, A (2013). Comparison of the binding of polyvinylpyrrolione and polyethylene oxide to Ag surfaces: Elements of a successful structure-directing agent. J Phys Chem C 117, 11444–11448.Google Scholar
Zhu, J-J, Kan, C-X, Wan, J-G, Han, M & Wang, G-H (2011). High-yield synthesis of uniform Ag nanowires with high aspect ratios by introducing the long-chain PVP in an improved polyol process. J Nanomater 2011, 982547. Available at http://dx.doi.org/10.1155/2011/982547Google Scholar
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