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Alteration of the properties of bentonite by reaction with amines

Published online by Cambridge University Press:  14 March 2018

John W. Jordan
John W. Jordan*
Affiliation:
Industrial Fellowship on Lead sustained by the National Lead Company at Mellon Institute, Pittsburgh, Pa
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Extract

The affinity between certain organic compounds and clays has been known for many years. Lloyd reported the adsorptive capacity of fuller's earth for alkaloids in 1916 without theorizing extensively about the mechanism. Smith reacted organic bases and their salts with bentonite and presented evidence that the reaction was one of base-exchange or metathesis, while Hauser has discovered that certain organic compounds of bentonite have the property of swelling and dispersing in organic liquids. This paper reports observations on the rather striking conversion of bentonite from the hydrophilic to the organophilic condition and proposes a mechanism to explain the observed phenomena.

Type
Research Article
Information
Mineralogical magazine and journal of the Mineralogical Society , Volume 28 , Issue 205 , June 1949 , pp. 598 - 605
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1949

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References

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