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Arthurite, a new copper—iron arsenate from Cornwall

Published online by Cambridge University Press:  14 March 2018

R. J. Davis
Affiliation:
Department of Mineralogy, British Museum (Natural History) London, S.W. 7
M. H. Hey
Affiliation:
Department of Mineralogy, British Museum (Natural History) London, S.W. 7

Summary

Thin apple-green crusts on several specimens from Hingston Down Consols mine, Calstock, Cornwall, proved to consist of a new mineral, alone or intimately mixed with pharmacosiderite (which it closely resembles), or with an unidentified mineral of the alunite-beudantite group having a 7·04, c 16·6 Å, or with both. The new mineral, for which the name arthurite is proposed, for Sir Arthur Russell and Mr. Arthur W. G. Kingsbury, who independently collected material and suggested that it might be new, gives X-ray powder photographs with their three strongest lines at 4·28, 4·81, and 6·97 Å ; the photographs could be satisfactorily indexed on a monoclinic unit-cell with a 10·09, b 9·62, c 5·55o Å (all ± 0·01 Å), β 92·2° ± 0·2° and containing [Cu2Fe4(AsO4)3(OH)7.6H2O]. Chemical analysis on 1·1 mg gave: CuO 16·8, Fe2O3 32·4, As2O5 34·3, H2O 16·5 % (reduced to 100 % after deduction of 27·4 % quartz) ; sp. gr. 3·2 (calc. 3·07). Under the microscope arthurite is pale olive-green and very finely granular; n 1·78, birefringence low to moderate.

Type
Research Article
Copyright
Copyright © 1964, The Mineralogical Society

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References

page note 3P This mineral has a7.04, c16-6 ∼, rather near the cell-dimensions of hidalgoite; it proved to be too closely associated with arthurite and pharmacosiderite to give useful analytical data.

page note 939 The samples taken for X-ray study were usually only about 10-30 /xg; samples of 1-3 mg were collected for chemical analysis with some difficulty.

page note 941 Vand, V., Acta Cryst., 1948, vol. 1, p. 290.CrossRefGoogle Scholar