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Effect of crystal composition and growth rate on sector zoning in solid solutions grown from aqueous solutions

Published online by Cambridge University Press:  05 July 2018

A. G. Shtukenberg ,
YU. O. Punin  and
O. I. Artamonova
A. G. Shtukenberg*
Affiliation:
Crystallography Department, Geological Faculty, St.Petersburg State University, Universitetskaya emb., 7/9, 199034 St.Petersburg, Russia
YU. O. Punin
Affiliation:
Crystallography Department, Geological Faculty, St.Petersburg State University, Universitetskaya emb., 7/9, 199034 St.Petersburg, Russia
O. I. Artamonova
Affiliation:
Crystallography Department, Geological Faculty, St.Petersburg State University, Universitetskaya emb., 7/9, 199034 St.Petersburg, Russia
*
* E-mail: shtukenberg@mail.ru
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Abstract

Sector zoning in solid solutions of Tutton’s salts (NH4)2M(SO4)2.6H2O (M = Co, Ni, Zn, Mg) and nitrates of divalent metals Me(NO3)2 (Me = Sr, Pb, Ba) grown from low-T aqueous solutions under controlled conditions is studied. The effect of crystal composition and growth rate (supersaturation) on the intersector difference in concentrations of isomorphic components is examined experimentally and modelled theoretically based on the phenomenological approach to crystallization in a ‘solid solution—aqueous solution’ system. Calculations show a predominating contribution of the selective adsorption phenomena in the formation of a sector-zoned crystal with usually minor, but sometimes a major contribution of growth kinetics.

Keywords

sector zoningsolid solutioncrystallizationselective adsorptiondistribution coefficientgrowth kinetics.
Type
Research Article
Information
Mineralogical Magazine , Volume 73 , Issue 3 , June 2009 , pp. 385 - 398
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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Footnotes

†

Pcurrently at: Porto Conte Ricerche srl SP 55 Porto Conte-Capo Caccia, km 8,300 Loc. Tramariglio, Alghero I-07041 Sassari, Italy

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