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The first proof of protonated anion tetrahedra in the tsumcorite-type compounds

Published online by Cambridge University Press:  05 July 2018

T. Mihajlović  and
H. Effenberger
T. Mihajlović*
Affiliation:
Institut für Mineralogie und Kristallographie, Universität Wien, Geozentrum, Althanstr. 14, A-1090 Wien, Austria
H. Effenberger
Affiliation:
Institut für Mineralogie und Kristallographie, Universität Wien, Geozentrum, Althanstr. 14, A-1090 Wien, Austria
*
*E-mail: tamara.mihajlovic@univie.ac.at
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Abstract

Hydrothermal synthesis produced the new compound SrCo2(AsO4)(AsO3OH)(OH)(H2O). The compound belongs to the tsumcorite group (natural and synthetic compounds with the general formula M(1)M(2)2(XO4)2(H2O,OH)2; M(1)1+,2+,3+ = Na, K, Rb, Ag, NH4, Ca, Pb, Bi, Tl; M(2)2+,3+ = Al, Mn3+, Fe3+, Co, Ni, Cu, Zn; and X5+,6+ = P, As, V, S, Se, Mo). It represents (1) the first Sr member, (2) the until now unknown [7]-coordination for the M(1) position, (3) the first proof of (partially) protonated arsenate groups in this group of compounds, and (4) a new structure variant.

The crystal structure of the title compound was determined using single-crystal X-ray diffraction data. The compound is monoclinic, space group P21/a, with a = 9.139(2), b = 12.829(3), c = 7.522(2) Å, β = 114.33(3)°, V = 803.6(3) Å3, Z = 4 [wR2 = 0.065 for 3530 unique reflections]. The hydrogen atoms were located experimentally.

Keywords

SrCo2(AsO4)(AsO3OH)(OH)(H2O)tsumcorite grouphydrothermal synthesiscrystal structurehydrogen bondsprotonated arsenate
Type
Research Article
Information
Mineralogical Magazine , Volume 68 , Issue 5 , October 2004 , pp. 757 - 767
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2004

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