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The geochemical and isotopic composition of ground waters in West Bengal: tracing ground-surface water interaction and its role in arsenic release

Published online by Cambridge University Press:  05 July 2018

M. Lawson*
Affiliation:
School of Earth, Atmospheric and Environmental Sciences, University of Manchester M13 9PL, UK
C. J. Ballentine
Affiliation:
School of Earth, Atmospheric and Environmental Sciences, University of Manchester M13 9PL, UK
D. A. Polya
Affiliation:
School of Earth, Atmospheric and Environmental Sciences, University of Manchester M13 9PL, UK
A. J. Boyce
Affiliation:
SUERC, Rankine Avenue, Scottish Enterprise Technology Park, East Kilbride G75 0QF, UK
D. Mondal
Affiliation:
School of Earth, Atmospheric and Environmental Sciences, University of Manchester M13 9PL, UK
D. Chatterjee
Affiliation:
University of Kalyani, Kalyani, Nadia, West Bengal, 741235, India
S. Majumder
Affiliation:
University of Kalyani, Kalyani, Nadia, West Bengal, 741235, India
A. Biswas
Affiliation:
University of Kalyani, Kalyani, Nadia, West Bengal, 741235, India

Abstract

In many areas of south and south-eastern Asia, concentrations of As in ground water have been found to exceed the WHO maximum concentration limit of 10 μg/l. This is adversely affecting the health of millions of people and has grave current and future health implications. It has recently been suggested that extensive abstraction of ground water in these areas may accelerate the release of As to ground water. This study uses geochemical and isotopic data to assess this hypothesis. The area investigated in this study is in the Chakdaha block of the Nadia District, West Bengal. The ground water is predominantly of the Ca-Mg-HCO3 type, although some samples were found to contain elevated concentrations of Na, Cl and SO4. This is thought to reflect a greater degree of water-rock interaction at the locations of these particular samples. Arsenic concentrations exceeded the national limit of 50 μg/l in 13 of the 22 samples collected. Four of the 13 samples with high As were recovered from tubewells with depths of 60 m or more. Shallow ground water samples were found to have a stable isotopic composition which falls subparallel to the Global Meteoric Water Line. This probably represents a contribution of evaporated surface water to the ground water, possibly from surface ponds or re-infiltrating irrigation water. Deep ground water, conversely, was shown to have a composition that closely reflects that of meteoric water. The data presented in this study suggest that, whilst the drawdown of surface waters may drive As release in shallow ground waters, it is not responsible for driving As release in deep ground water. However, local abstraction may have resulted in changes in the ground water flow regime of the area, with contaminated shallow ground waters being drawn into previously uncontaminated deep aquifers.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2008

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References

Balga, P. and Kaiser, J. (1996) India's spreading health crisis draws global arsenic experts. Science, 274, 174–175.Google Scholar
Berg, M., Tranm, H.C., Nguyen, T.C., Pham, H.V., Schertenleib, R. and Giger, W. (2001) Arsenic contamination of ground and drinking water in Vietnam: a human health threat. Environmental Science and Technology, 35, 2621–2626.CrossRefGoogle Scholar
Berg, M., Stengel, C. Trang, P.T.K., Viet, P.H., Sampson, M.L., Leng, M., Samreth, S. and Fredericks, D. (2007) Magnitude of arsenic pollution in the Mekong and Red River Deltas — Cambodia and Vietnam. Science of the Total Environment, 372, 413–425.CrossRefGoogle ScholarPubMed
BGS and DPHE (2001) Arsenic contamination of groundwater in Bangladesh, hi: British Geological Survey Report. WC/00/1. (Kinniburgh, D. G. and Smedley, P. L., editors). British Geological Survey, UK.Google Scholar
Chakraborty, A.K. and Sana, K.C. (1987) Arsenical dermatosis from tubewell water in West Bengal, India. Indian Journal of Medical Research, 85, 326–334.Google Scholar
Charlet, L. and Polya, D.A. (2006) Arsenic in shallow reducing groundwaters in southern Asia: an environmental health disaster. Elements, 2, 91–96.CrossRefGoogle Scholar
Gonfiantini, R., Dincer, T. and Derekoy, A.M. (1974) Environmental isotope hydrology in the Honda Region, Algeria. Pp. 293–316 in: Isotope Techniques in Groundwater Hydrology 1974. IAEA, Vienna.Google Scholar
Harvey, C.F., Swartz, C.H., Badruzzaman, A.B.M., Keon-Blute, N., Yu, W., Ashraf, A.M., Jay, J., Beckie, R., Niedan, V., Brabander, D., Oates, P.M., Ashfaque, K.N., Islam, S., Hemond, H.F., and Ahmed, M.F. (2002) Arsenic mobility and ground-water extraction in Bangladesh. Science, 298, 1602–1606.CrossRefGoogle ScholarPubMed
Islam, F.S., Gault, A.G., Boothman, C, Polya, D.A., Charnock, J.M., Chatterjee, D. and Lloyd, J.R. (2004) Role of metal-reducing bacteria in arsenic release from Bengal delta sediments. Natur. 430, 68–71.CrossRefGoogle ScholarPubMed
Polya, D.A., Gault, A.G., Diebe, N., Feldman, P., Rosenboom, J.W., Gilligan, E., Fredericks, D., Milton, A.H., Sampson, M., Rowland, H.A.L., Lythgoe, P.R., Jones, J.C., Middleton, C. and Cooke, D.A. (2005) Arsenic hazard in shallow Cambodian groundwaters. Mineralogical Magazine, 69, 807–823.CrossRefGoogle Scholar
van Geen, A., Ahmed, KM., Seddique, A.A. and Shamsudduha, M. (2003) Community wells to mitigate the current arsenic crisis in Bangladesh. Bulletin of the World Health Organization, 82, 632–638.Google Scholar