Hostname: page-component-84b7d79bbc-2l2gl Total loading time: 0 Render date: 2024-07-27T04:40:20.455Z Has data issue: false hasContentIssue false

Platinum-group minerals in the Selukwe Subchamber, Great Dyke, Zimbabwe: implications for PGE collection mechanisms and post-formational redistribution

Published online by Cambridge University Press:  05 July 2018

Bronwen M. Coghill
Affiliation:
Department of Geology, University of Natal, P.O. Box 375, Pietermaritzburg 3200, South Africa
Allan H. Wilson
Affiliation:
Department of Geology, University of Natal, P.O. Box 375, Pietermaritzburg 3200, South Africa

Abstract

This paper presents the results of microprobe investigations of the Platinum-Group Elements (PGE) of the Selukwe Subchamber, Great Dyke, Zimbabwe. The PGE are associated with base metal sulphides in the uppermost pyroxenites of the Ultramafic Sequence of the Great Dyke. The following minerals have been indentified: bismuthotellurides (moncheite, maslovite, michenerite, kotulskite and polarite); arsenides (sperrylite); and sulphides and sulpharsenides (cooperite, laurite, braggite and hollingworthite). Platinum Group Minerals (PGM) occur in three distinct textural environments: (1) at the boundary of sulphides and silicates/hydrosilicates, (2) entirely enclosed within sulphides, and (3) entirely enclosed within silicate or hydrosilicate minerals. The stratigraphic distribution, environments and textures of the PGM have important genetic implications, and cannot be explained by a single process. A multi-process model for the petrogenesis of the PGE mineralisation in terms of complexation and intermediate compound formation is proposed. The primary mineralising events were due to orthomagmatic processes, but the observed textures are the result of microscale remobilisation of PGM components by trapped interstitial fluids (bydromagmatic processes).

Type
Mineralogy
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Balhaus, C. G. and Stumpfl, E. F. (1986) Sulphide and platinum mineralisation in the Merensky Reef: evidence from hydrous silicates and fluid inlcusions. Contrib. Mineral. Petrol., 94, 193204.Google Scholar
Barnes, S. J. and Naldrett, A. J. (1985) Geochemistry of the J-M (Howland) Reef of the Stillwater Complex, Minneapolis Adit area. I. Sulfide chemistry and sulfide-olivine equilibrium. Econ. Geol. 80, 627–45.Google Scholar
Barnes, S. J., McIntyre, J. R., Nisbet, B. W., and Williams, C. R. (1990) Platinum Group Element Mineralisation in the Munni Munni Complex, Western Australia. Contrib. Mineral. Petrol., 42, 141–64.Google Scholar
Beaudoin, G., Laurent, R., and Ohnenstetter, D. (1990) First report of platinum-group minerals at Blue Lake, Labrador Trough, Quebec. Can. Mineral., 28, 409–18.Google Scholar
Boudreau, A. E. (1988) Investigations of the Stillwater Complex IV. The role of volatiles in the petrogenesis of the J-M Reef, Minneapolis Adit section. Ibid., 26, 193-208.Google Scholar
Boudreau, A. E. Mathez, E. A., and McCallum, I. S. (1986) Halogen geochemistry of the Stillwater and Bushveld Complexes: Evidence for Transport of the Platinum-Group Elements by CI-Rich Fluids. J. Petrol., 27, 967–86.Google Scholar
Brynard, H. J., De Villiers, J. P. R., and Viljoen, E. A. (1976) A Mineral Investigation of the Merensky Reef of the Western Platinum Mine, near Marikana, South Africa. Econ. Geol., 71, 12991307.Google Scholar
Buchanan, D. L. (1988) Platinum-Group Element Exploration. Elsevier, Amsterdam, 2135.Google Scholar
Cabri, L. J. and Laflamme, J. H. G. (1976) The mineralogy of the Platinum-Group Elements from some copper-nickel deposits of the Sudbury area, Ontario. Econ. Geol., 71, 115495.Google Scholar
Cabri, L. J. and Laflamme, J. H. G. (1981) Analyses of Minerals containing Platinum-Group Elements. In Platinum-Group Elements: Mineralogy, Geology, Recovery (L. J. Cabri, ed.). Can. Inst. of Min. & Met., Montreal, 151-74.Google Scholar
Cabri, L. J. and Laflamme, J. H. G. Stewart, J. M., Turner, K., and Skinner, B. J. (1978) On cooperite, braggite and vysotskite. Am. Mineral., 63, 832–9.Google Scholar
Cabri, L. J. Rowland, J. F., Laflamme, J. H. G., and Stewart, J. M. (1979) Keithconnite, telluropalladinite and other Pd-Pt tellurides from the Stillwater Complex, Montana. Can. Mineral., 17, 589–94.Google Scholar
Campbell, I. H. and Barnes, S. J. (1984) A model for the geochemistry of the platinum-group elements in magmatic sulphide deposits. Ibid., 22, 151-60.Google Scholar
Campbell, I. H. and Naldrett, A. J. (1979) The influence of silicate:sulphide ratios on the geo-chemistry of magmatic sulphides. Econ. Geol., 74, 1503–6.Google Scholar
Campbell, I. H. and Barnes, S. J. (1983) A model for the origin of the platinum-rich sulphide horizons in the Bushveld and Stillwater Complexes. J. Petrol., 24, 133–85.Google Scholar
Cousins, C. A. and Vermakk, C. F. (1976) The contribution of South African ore deposits to the geochemistry of the Platinum-Group Metals. Econ. Geol., 71, 287305.Google Scholar
Davis, G. and Tredoux, M. (1985) The platinum-group element and gold contents of the marginal rocks and sills of the Bushveld Complex. ibid., 80, 838-48.Google Scholar
Evans, D. M. and Buchanan, D. L. (1991) Application of petrographic studies to MSZ platinum-group element and base-metal mineralisation at Zinca prospect, Great Dyke, Zimbabwe. Trans. Instn. Min. Metall. (Sect. B: Appl. earth sci.), 100, B216-26.Google Scholar
Hakli, T. A., Hönninen, E., Vuorelainen, Y., and Papunen, H. (1976) Platinum-Group Minerals in the Hikura Nickel Deposit Finland. Econ. Geol., 71, 1206–13.Google Scholar
Harney, D. M. W. and Merkle, R. K. W. (1990) Pt-Pd minerals from the Upper Zone of the eastern Bushveld Complex, South Africa. Can. Mineral., 28, 619528.Google Scholar
Haughton, D. R., Roeder, P. L. and Skinner, B. J. (1974) Solubility of sulphur in mafic magmas. Econ. Geol., 69, 451–7.Google Scholar
Haynes, L. (1983) The platinum mineralogy of the Great Dykes; some observations and new infor-mation. Inst. Mining Research Annual Report, Univ. Zimbabwe.Google Scholar
Helz, R. T. (1985) Interactions of sulphide-saturated basalts with PtFe and PdAgFe alloy capsules: experimental observations. Can. Mineral., 23, 326.Google Scholar
Johan, Z., Ohnenstetter, D., and Naldrett, A. J. (1989) Platinum-group minerals and associated oxides and base metal sulphides of the Main Sulphide Zone, Great Dyke, Zimbabwe. In Abstracts—5th International Platinum Symposium (H. Papunen, ed.), Bull. Geol. Soc. Finland, No. 61, Pt.1, 53-4.Google Scholar
Lightfoot, B. (1926) Platinum in Southern Rhodesia. South. Rhod. Geol. Surv. Short Report, 19, 13 pp.Google Scholar
Lightfoot, B. (1927) Traverses along the Great Dyke of Southern Rhodesia. South. Rhod. Geol. Surv. Short Report, 21.Google Scholar
Lindsay, N. M. (1988) The processing and recovery of the platinum-group elements. Unpubl. Ph.D. Thesis, Univ. of the Witwatersrand, Johannesburg.Google Scholar
Macdonald, A. J. (1987) Ore Deposit Models #12. The Platinum-Group Element Deposits: classification and genesis. Geoscience Canada, 14, 155–66.Google Scholar
Makovicky, E., Karup-Moller, S., Makovicky, M. and Rose-Hansen, J. (1990) Experimental Studies on the Phase Systems Fe-Ni-Pd-S and Fe-Pt-Pd-As-S Applied to PGE Deposits. Mineral. Petrol., 42, 307–19.Google Scholar
McCallum, M. E., Loucks, R. R., Carlson, R. R., Cooley, E. F. and Doerge, T. A. (1976) Platinum metals associated with hydrothermal copper ores of the New Rambler Mine, Medicine Bow Mountains, Wyoming. Econ. Geol., 71, 1429–50.Google Scholar
Naldrett, A. J. and Wilson, A. H. (1989) Distribution and controls of platinum group element mineralisation in Cyclic Unit 1 of the Great Dyke, Zimbabwe. In Abstracts—5th International Platinum Symposium (H. Papunen, ed.). Bull. Geol. Soc. Finland, 61, Pt. 1,3.Google Scholar
Naldrett, A. J. and Wilson, A. H. (1990) Horizontal and vertical variations in noble-metal distribution in the Great Dyke of Zim-babwe: A model for the origin of the PGE mineralisation by fractional segregation. Chem. Geol., 88, 279300.Google Scholar
Naldrett, A. J. Brugmann, G. E., and Wilson, A. H. (1990) Models for the concentration of PGE in layered intrusions. Can. Mineral., 28, 389408.Google Scholar
Peach, C. L., Mathez, E. A. and Keays, R. R. (1989) Sulfide melt-silicate melt distribution coefficients for the noble metals as deduced from MORBS. In Abstracts—5th International Platinum Symposium (H. Papunen, ed.). Bull. Geol. Soc. Finland, 61, Pt. 1,58.Google Scholar
Podmore, F. and Wilson, A. H. (1987) A reappraisal of the structure, geology and emplacement of the Great Dyke, Zimbabwe. In Mafic Dyke Swarms (H. C. Halls and W. F. Fahrig, eds.). Geol. Assoc. Canada Sp. Paper, 34, 317–30.Google Scholar
Prendergast, M. D. (1990) Platinum-group minerals and hydrosilicate ‘alteration’ in Wedza-Mimosa Platinum Deposit, Great Dyke, Zimbabwe—genetic and metallurigical implications. Trans. Instn. Min. Metall. (Sect. B: Appl. earth sci.), 99, B91-105.Google Scholar
Prendergast, M. D. (1991) The Wedza-Mimosa platinum deposit, Great Dyke, Zimbabwe: layering and stratiform PGE mineralisation in a narrow mafic magma chamber. Geol. Mag., 128, 235–49.Google Scholar
Prendergast, M. D. and Keays, R. R. (1989) Controls of platinumgroup element mineralisation and the origin of the PGE-rich Main Sulphide Zone in the Wedza Subchamber of the Great Dyke, Zimbabwe: implications for the genesis of, and exploration for, stratiform PGE mineralisation in layered intrusions. In Magmatic Sulphides—The Zimbabwe Volume (M. D. Prendergast and M. J. Jones, eds.). The Inst. of Min. & Met., London, 43-69.Google Scholar
Prendergast, M. D. and Wilson, A. H. (1989) The Great Dyke of Zimbabwe—II: Mineralisation and mineral deposits. In Magmatic Sulphides—The Zimbabwe Volume (M. D. Prendergast and M. J. Jones, eds.). The Inst. of Min. & Met., London, 21-42.Google Scholar
Raedeke, L. W. and Vian, R. W. (1986) A three-dimensional view of mineralisation in the Stillwater J-F Reef. Econ. Geol., 81, 1187–95.Google Scholar
Schweigart, H. (1967) Rhodesian Platinum. Union Carbide Corporation progress report, September 15, 4 pp.Google Scholar
Schweigart, H. and Fasso, F. J. (1967) Rhodesian Platinum. Union Carbide Corporation progress report, October 15, 15 pp.Google Scholar
Skinner, B. J., Luce, F. D., Dill, J. A., Ellis, D. E., Hagan, H. A. Lewis, D. M., Odell, D. A., Sverjensky, D. A. and Williams, N. (1976) Phase relations in ternary portions of the system Pt-Pd-Fe-As-S. Econ. Geol., 71, 1469–75.Google Scholar
Stumpfl, E. F. and Balhaus, C. G. (1986) Stratiform platinum deposits: New data and concepts, Fortschr, Miner., 64, 205–14.Google Scholar
Vermaak, C. F. (1976) The Merensky Reef—thoughts on its environment and genesis. Econ. Geol., 71, 1270–98.Google Scholar
Vermaak, C. F. and Hendriks, L. P. (1976) A review of the mineralogy of the Merensky Reef, with special reference to new data on the precious metal minera-logy. Ibid., 71, 1244-69.Google Scholar
Wagner, P. A. (1929) Platinum deposits and mines of South Africa. C. Struik, (Pty) Ltd, Cape Town, 338 PP.Google Scholar
Wilson, A. H. (1982) The geology of the Great ‘Dyke', Zimbabwe: the Ultramafic Rocks. J. Petrol., 23, 240–92.Google Scholar
Wilson, A. H. (1992) The geology of the Great Dyke, Zimbabwe: crystallisation, layering and cumulate formation in the P1 Pyroxenite of Cyclic Unit 1 of the Darwendale Subchamber. Ibid., 33, 611—63.Google Scholar
Wilson, A. H. and Prendergast, M. D. (1989) The Great Dyke of Zimbabwe: I: Tectonic setting, stratigraphy, petrology, structure, emplacement and crystallisation. In Magmatic Sulphides—The Zimbabwe Volume (M. D. Prendergast and M. J. Jones, eds.). The Inst. of Min. & Met., London, 1-20.Google Scholar
Wilson, A. H. and Tredoux, M. (1990) Lateral and vertical distribution of the platinum group elements, and petrogenetic controls on the sulphide mineralisation, in the P1 Pyroxenite layer of the Darwendale Subchamber of the Great Dyke, Zimbabwe. Econ. Geol., 85, 556–84.Google Scholar
Wilson, A. H. Naldrett, A. J., and Tredoux, M. (1989) Distribution and controls of platinum-group element and base metal mineralisation in the Darwendale Subchamber of the Great Dyke, Zimbabwe. Geology, 17, 649-52.Google Scholar
Zealley, A. E. V. (1918) The occurrence of platinum in Southern Rhodesia. South Rhod. Geol. Surv. Short Report, 3.Google Scholar
Zientek, M. L., Fries, T. L. and Vian, R. W. (1990) As, Bi, Hg, S, Sb, Sn and Te geochemistry of the J-M Reef, Stillwater Complex, Montana: constraints on the origin of PGE-enriched sulphides in layered intrusions. In Geochemistry of Platinum-Group Elements, (C. E. Dunn, G. C. Curtin, and G. E. M. Hall, eds.). J. Geochem. Explor., 37, 5173.Google Scholar