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Crystal structures of some double hydroxide minerals

Published online by Cambridge University Press:  05 July 2018

H. F. W. Taylor
H. F. W. Taylor*
Affiliation:
Department of Chemistry, University of Aberdeen, Scotland
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Summary

Three groups of minerals are discussed, which are typified by pyroaurite and sjögrenitc, hydrocalumite, and ettringite. All show interesting structural features. In the pyroaurite-sjögrenite group, brucite-likc layers carrying a net positive charge alternate with layers in which the oxygen atoms of carbonate groups and water molecules are statistically distributed on a single set of sites; other anions may replace the carbonate, especially in synthetic phases. Hydrocalumite and related synthetic phases also have layer structures in which positively charged main layers alternate with intermediate layers containing anions and water molecules; the anions occur in cavities and their nature can again vary widely. In the ettringite group, the structures are based on positively charged columns, between which occur channels containing anions and sometimes also water molecules. This group includes thaumasite, the only natural mineral known to contain silicon six-coordinated by oxygen that is not a high-pressure phase. The thermal dehydration behaviour in each group is briefly considered.

Type
Research Article
Information
Mineralogical Magazine , Volume 39 , Issue 304 , December 1973 , pp. 377 - 389
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1973

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References

Ahmed, (S. J.), Dent Glasser, (L. S.), and Taylor, (H. F. W.), 1969. Proc. 5th Int. Syrup. Chem. Cement, Tokyo 1968, 2, 118.Google Scholar
Ahmed, (S. J.), Dent Glasser, (L. S.), and Taylor, (H. F. W.) and TAYLOR (H. F. W,), 1967. Nature, 215, 622.CrossRefGoogle Scholar
Allmann, (R.), 1968a. Acta Cryst. B24, 972.CrossRefGoogle Scholar
Allmann, (R.) 1968b. Neues Jahrb. Min., Monatsh., 140.Google Scholar
Allmann, (R.) 1969. Ibid. 552.Google Scholar
Allmann, (R.). 1970. Chimia, 24, 99.Google Scholar
Allmann, (R.) and Donnay, (J. D. H.), 1969. Amer. Min., 54, 296.Google Scholar
Allmann, (R.) and Donnay, (J. D. H.), and Jepsen, (H. P.), 1969. Neues Jahrb. Min., Monatsh., 544.Google Scholar
Allmann, (R.) and Donnay, (J. D. H.), and Lohse, (H.-H.), 1966. Ibid. 161.Google Scholar
Aminoff, (G.) and Broome, (B.), 1930. Handl. Kungl. Vetensk., 9 (3, no. 5), 23.Google Scholar
Bannister, (F. A.), HEY, (M. H.), and Bernal, (J. D.), 1936. Min. Mag., 24, 324.Google Scholar
Bernal, (J. D.), Dasgupta, (D. R ) , and Mackay, (A. L.), 1959. Clay Min. Bull., 4, 15.CrossRefGoogle Scholar
Bissert, (G.) and Liebau, (F.), 1969. Naturwiss., 56, 212.CrossRefGoogle Scholar
Brown, (G.) and Gastuche, (M. C), 1967. Clay Min., 7, 193.CrossRefGoogle Scholar
Buttler, (F. G.), Dent Glasser, (L. S.), and TAYLOR (H, F. W.), 1959. Journ. Amer. Ceram. Soc, 42, 121.CrossRefGoogle Scholar
Courtois, (A.), Dusausoy, (Y.), Laffaille, (A.), and Protas, (J.), 1968. Compt. Rend. Acad. Sci. Paris D266, 1911.Google Scholar
Dilthey, (W.), 1903. Ber. deutsch. chem. Ges., 36, 923, 1595.CrossRefGoogle Scholar
Dosch, (W.), 1967. Neues Jahrb. Min. Abh., 106, 200.Google Scholar
Dosch, (W.) and ZUR Strassen, (H.), 1967. Zement-Kalk-Gips, 20, 392.Google Scholar
Edge, (R. A.) and Taylor, (H. F. W.), 1969. Nature, 224, 363.CrossRefGoogle Scholar
Edge, (R. A.) 1971. Ada Cryst. B27, 594.Google Scholar
Feitknecht, (W.), and Buser, (H. W.), 1951. Helv. Chim. Ada, 34, 128.CrossRefGoogle Scholar
Fenoglio, (M.), 1938. Periodico Min., 16, 1.Google Scholar
Frondel, (C), 1941. Amer. Min., 26, 295.Google Scholar
Gastuche, (M. C), Brown, (G.), and Mortland, (M. M.), 1967. Clay Min., 7, 177.CrossRefGoogle Scholar
Gaudefroy, (C), Granger, (M.-M.), Permingeat, (F.), and Protas, (J.), 1968. Bull. Soc. franf. Crist., 91, 43.Google Scholar
Granger, (M.-M.) and Protas, (J.), 1966. Compt. Rend. Acad. Sci. Paris D262, 1037.Google Scholar
Granger, (M.-M.) 1969. Ada Cryst. B25, 1943.Google Scholar
Heddle, (M. F.), 1879. Min. Mag. 2, 106.Google Scholar
Ingram, (L.) and Taylor, (H. F. W.), 1967. Ibid. 36, 465.CrossRefGoogle Scholar
Jambor, (J. L.) and Boyle, (R. W.), 1964. Canad. Min., 8, 116.Google Scholar
Kirov, (G. N.) and Poulieff, (C. N.), 1968. Min. Mag., 36, 1003.Google Scholar
Kohls, (D. W.) and Rodda, (J. L.), 1967. Amer. Min., 52, 1261.Google Scholar
Kuzel, (H. J.), 1969. Proc. 5th Int. Symp. Chem. Cement, Tokyo, 1968, 2, 92.Google Scholar
Laffaille, (A.) and Protas, (J.), 1970. Compt. Rend. Acad. Sci. Paris D270, 2151.Google Scholar
Lapham, (D. M.), 1965. Amer. Min., 50, 1708.Google Scholar
LEA, (S. G.) and Mackay, (A. L.), 1967. Min. Mag., 36, xxxiv (abstract only).Google Scholar
LE BEL, (F.) and Grasland, (G.), 1969. Proc. 5th Int. Symp. Chem. Cement, Tokyo, 1968, 2, 79.Google Scholar
Levi, (G. R.) and Peyronel, (G.), 1935. Zeits. Krist., 92, 190.Google Scholar
Liebau, (F.), and Hesse, (K.-F.), 1969. Naturwiss., 56, 634.CrossRefGoogle Scholar
Moenke, (H.), 1964. Ibid. 51, 239.CrossRefGoogle Scholar
Moore, (A. E.) and Taylor, (H. F. W.), 1968. Nature, 218, 1048.CrossRefGoogle Scholar
Moore, (A. E.) and Taylor, (H. F. W.), 1970. Ada Cryst. B26, 386.Google Scholar
Moore, (P. B.), 1971. Lithos, 4, 213.CrossRefGoogle Scholar
Mumpton, (F. A.), Jaffe, (H. W.), and Thompson, (C. S.), 1965. Amer. Min., 50, 1893.Google Scholar
Otto, (H. H.), 1968. Naturwiss., 55, 387.CrossRefGoogle Scholar
Pastor-Rodriguez, (J.) and Taylor, (H. F. W.), 1971. Min. Mag., 38, 286.CrossRefGoogle Scholar
Rosenheim, (A.), Raibmann, (B.), and Schendel, (G.), 1931. Zeits. anorg. allg. Chem., 196, 160.CrossRefGoogle Scholar
Ross, (G. J.) and Kodama, (H.), 1967. Amer. Min., 52, 1036.Google Scholar
Rouxhet, (P. G.) and Taylor, (H. F. W.), 1969. Chimia, 23, 480.Google Scholar
Sadran, (G.) and Cottin, (B.), 1969. Proc. 5th Int. Symp. Chem. Cement, Tokyo, 1968, 2, 84.Google Scholar
Schwiete, (H. E.) and Ludwig, (U.), 1969. Ibid. 2, 37.CrossRefGoogle Scholar
Stampfl, (P. P.), 1969. Corros. Sci., 9, 185.CrossRefGoogle Scholar
Taylor, (H. F. W.), 1969. Min. Mag., 37, 338.CrossRefGoogle Scholar
Tilley, (C. E.), Megaw, (H. D.), and Hey, (M. H.), 1934. Ibid. 23, 607.CrossRefGoogle Scholar
Welin, (E.), 1956. Ark. Min. Geol., 2, 137 Google Scholar