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Spheniscidite, a new phosphate mineral from Elephant Island, British Antarctic Territory

Published online by Cambridge University Press:  05 July 2018

M. J. Wilson
Affiliation:
Department of Mineral Soils, the Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen
D. C. Bain
Affiliation:
Department of Mineral Soils, the Macaulay Institute for Soil Research, Craigiebuckler, Aberdeen

Abstract

Spheniscidite is a new phosphate mineral occurring in a soil profile in an area of nesting penguins on Elephant Island. It is the NH4-dominant analogue of leucophosphite and has the formula (NH4,K)(Fe3+,Al)2 (PO4)2(OH) · 2H2O. It is monoclinic, P21/n with unit cell parameters a = 9.75, b = 9.63, c = 9.70 Å, β = 102° 34′, and Z = 4. The strongest X-ray lines are 6.79(100), 5.99(90), 3.05(45), 7.62(40) Å. Spheniscidite is thought to have formed by the interaction of ammonium phosphate solutions from penguin guano with micaceous and chloritic minerals in the soil. The name is for Sphenisciformes, the order name for penguins, and has been approved by the IMA Commission on New Minerals and Mineral Names.

Type
Mineralogy
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1986

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References

Arlidge, E.Z., Farmer, V.C. Mitchell, B.D., and Mitchell, W.A. (1963) J. Appl. Chem, 13, 17-27.CrossRefGoogle Scholar
Lehr, J.R., Brown, E.H., Frazier, A.W., Smith, J.P., and Thrasher, R.D. (1967) Crystallographic Properties of Fertilizer Compounds. Chem. Eng. Bull. No. 6. Tennessee Valley Authority.Google Scholar
Lindberg, M.L. (1957) Am. Mineral. 42, 214-21. Google Scholar
Norrish, K., and Hutton, J.T. (1969) Geochim. Cosmochim. Ada, 33, 431-53.CrossRefGoogle Scholar
Tatur, A., and Barczuk, A. (1985) Antarctic Nutrient Cycles and Food Webs.(W. R. Siegfried P.R. Condy, and R. M. Laws, eds.). Springer-Verlag, Berlin, Heidelberg.Google Scholar
Wilson, M.J., and Bain, D.C. (1976) Am. Minera, 61, 1027-8.Google Scholar