Hostname: page-component-77c89778f8-fv566 Total loading time: 0 Render date: 2024-07-17T18:13:19.378Z Has data issue: false hasContentIssue false

Analysis of PEDOT:PSS Films After Sulfuric Acid Treatment on Silicon and Fused Silica using FT-IR and UV-VIS

Published online by Cambridge University Press:  08 March 2016

Emma G. Langford
Affiliation:
Department of Chemistry and Biochemistry, James Madison University, Harrisonburg, Virginia 22807
Kenneth D. Shaughnessy
Affiliation:
Department of Physics and Astronomy, James Madison University, Harrisonburg, Virginia 22807
Thomas C. Devore
Affiliation:
Department of Chemistry and Biochemistry, James Madison University, Harrisonburg, Virginia 22807
David Lawrence
Affiliation:
Department of Integrated Science and Technology, James Madison University, Harrisonburg, Virginia 22807
Costel Constantin*
Affiliation:
Department of Physics and Astronomy, James Madison University, Harrisonburg, Virginia 22807
*
Get access

Abstract

Thin films of organic semiconductor PEDOT:PSS deposited onto silicon and fused silica substrates. These films were then treated with sulfuric acid (H2SO4) for various amounts of time (i.e., 10, 20, 40, 60, and 80 minutes). Preliminary results obtained with FT-IR, UV-VIS, and Van DerPauw conductivity methods suggest that the H2SO4 removes the PSS isonomer from the PEDOT:PSS system. This PSS removal also induces a decrease in film thickness.

Type
Articles
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Hecht, D. Hu, L. Irvin, G. Adv. Mater. 23, 14821513 (2011).Google Scholar
López-Sandoval, I. Cruz-Cruz, I. Reyes-Reyes, M. Thin Solid Films 513, 385390 (2013).Google Scholar
Kemerick, M. van Reenen, S. Scheepers, M. van de Ruit, K. Bollen, D. ORGEL. 15, 37103714 (2014).Google Scholar
Yang, Y. Ouyang, J. Chu, C. Chen, F. Xu, Q. Adv. Funct. Mater. 15, 203208 (2005).Google Scholar
van der Pauw, L.J., Philips Res. Repts. 13 (1958) 19.Google Scholar
Martin, D. C.. Cho, W.. Wu, J.. Shim, B. S.. Kuan, W.. Mastroianni, S. E.. Young, W.. Kuo, C.. Epps, T. H.. PCCP. 17, 51155123 (2015).Google Scholar
Wu, J. (2011). Morphology of Poly(3,4-ethylene dioxythiophene) (PEDOT) Thin Films, Crystals, Cubic Phases, Fibers and Tubes (unpublished doctoral dissertation). University of Michigan, Ann Arbor, Michigan.Google Scholar
Kim, N., Kee, S., Lee, S. H. , Lee, B. H., Kahng, Y. H., Jo, Y-R., Kim, B-J., and Lee, K, Adv. Mater. 26, 2268 (2014).Google Scholar