Hostname: page-component-68945f75b7-9klrw Total loading time: 0 Render date: 2024-08-06T09:11:01.610Z Has data issue: false hasContentIssue false

CO2 capture and biomethane obtention using activated carbon filter of animal origin

Published online by Cambridge University Press:  25 September 2018

AC Pina
Affiliation:
Laboratorio de Fisicoquímica de Superficies, DETEMA, Facultad de Química, Universidad de la República, Uruguay
N Tancredi
Affiliation:
Laboratorio de Fisicoquímica de Superficies, DETEMA, Facultad de Química, Universidad de la República, Uruguay
M Baldan
Affiliation:
Instituto Nacional de Pesquisas Espaciais, Av. dos Astronautas 1758 – Jardim da Granja – São José dos Campos (SP) – Brasil
JS Marcuzzo
Affiliation:
Instituto Nacional de Pesquisas Espaciais, Av. dos Astronautas 1758 – Jardim da Granja – São José dos Campos (SP) – Brasil
A Amaya*
Affiliation:
Laboratorio de Fisicoquímica de Superficies, DETEMA, Facultad de Química, Universidad de la República, Uruguay
*
*Corresponding author: aamaya@fq.edu.uy Tel: (598) 91300709
Get access

Abstract

Carbon fibers and activated carbon fibers are materials of high industrial interest. When presented as a felt, its use becomes easier and more practical. This work aims to study the conditions for obtaining and characterizing an activated carbon felt, using sheep wool as a precursor. The wool felt was oxidized, carbonized in nitrogen atmosphere and activated in water vapor. The working temperatures were selected through thermogravimetric analysis. The products and intermediates were characterized through thermogravimetric analysis, infrared spectroscopy, scanning electron microscopy, Raman spectroscopy and nitrogen adsorption-desorption. The products were assessed as potential sorbents for methane-carbon dioxide separation by adsorption kinetics measurements at different pressures. Results revealed a high influence of the carbonization temperature on the physicochemical and textural properties of the products. The adsorption kinetics and capacities of the gases showed that selectivities in separation were related to both felt carbonization temperature and gas pressure. This work revealed that activated carbon wool felts are a good alternative to synthetic fibers felt and they can be used for methane/carbon dioxide separation.

Type
Articles
Copyright
Copyright © Materials Research Society 2018 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Pickering, K., Efendi, M., Le, T. (2016) A review of recent developments in natural fiber composites and their mechanical performance. Composites: Part A 83:98112.CrossRefGoogle Scholar
Andersen, S. (2016) Nano carbon supported platinum catalyst interaction behavior with perfluorosulfonic acid ionomer and their interface structures. Applied Catalysis B: Environmental 181:146155.CrossRefGoogle Scholar
Ye, J., Liu, Z., Lai, C., Lo, C., Lee, C. (2016) Diameter effect of electro spun carbon fiber support for the catalysis of Pt nanoparticles in glucose oxidation. Chemical Engineering Journal 283:304312.CrossRefGoogle Scholar
Hwang, S., Choi, W., Lin, S. (2016) Hydrogen storage characteristics of carbon fibers derived from rice straw and paper mulberry. Materials Letters 167:1821.CrossRefGoogle Scholar
Shimekit, B., Mukhtar, H., Murugesan, T. (2011) Prediction of the relative permeability of gases in mixed matrix membranes. Journal of Membrane Science 373:152159.CrossRefGoogle Scholar
Tagliabue, M., Farrusseng, D., Valencia, S., Aguado, S., Ravon, U., Rizzo, C., Corma, A., Mirodatos, C. (2009) Natural gas treating by selective adsorption: Material science and chemical engineering interplay. Chemical Engineering Journal 155:553566.CrossRefGoogle Scholar
Favvas, E.P., Katsaros, F.K., Papageorgiou, S.K., Sapalidis, A.A., Mitropoulos, A.Ch. (2017) A review of the latest development of polyimide-based membranes for CO2 separations. Reactive and Functional Polymers, 120:104130.CrossRefGoogle Scholar
Jeon, Y.W., Shin, M.S. (2017) Separation of biogas using newly prepared cellulose acetate hollow fiber membranes. Energy Procedia, 136:219224.CrossRefGoogle Scholar
Macias-Garcia, A., Cuerda-Correa, E., Olivares-Marinb, M., Diaz-Paralejo, A. y Diaz-Dieza, M. A. (2012) Industrial Crops and Products 35: 105110.CrossRefGoogle Scholar
Kim, H.; Jeong, N., Han, S. (2012) Applied Catalysis B: Environmental 116:113114.Google Scholar
Rosas, J.; Bedia, J.; Rodríguez-Mirasol, J.; Cordero, T. (2009) HEMP-derived activated carbon fibers by chemical activation with phosphoric acid. Fuel. 88:1926CrossRefGoogle Scholar
Hoa Phan, N., Rio, S., Faur, C., Le Coq, L., Le Cloirec, P., Hong Nguyen, T. (2006) Production of fibrous activated carbons from natural cellulose (jute, coconut) fibers for water treatment applications. Carbon 44:25692577.CrossRefGoogle Scholar
Marcuzzo, J., Otani, C., Polidoro, H., Otani, S., Rodrígues, L. (2011) Use of carbon fiber produced from textile PAN for cleaning water pollution. Anais do V Congresso Brasileiro de Carbono 97101.Google Scholar
Altoé, G., Canto, L., Castro, L. (2011) Effects of stabilization conditions on microstructure and chemical composition of carbon fibers obtained from petroleum pitch, temperature and residence time. Anais do V Congresso Brasileiro de Carbono 124128.Google Scholar
Kil, H.S., Jang, S.Y., Ko, S., Jeon, Y.P., Kim, H.C., Joh, H.I., Lee, S. (2018) Effects of stabilization variables on mechanical properties of isotropic pitch based carbon fibers. Journal of Industrial and Engineering Chemistry, 58: 349356.CrossRefGoogle Scholar
Amaya, A., Pina, A.C., García, L., Tancredi, N., Marcuzzo, J. (2015) Production and characterization of carbon felt from wool. Carbon 2015.Google Scholar
Park, S.J. (2015) Carbon Fibers. Springer Series in Materials Science 210.Google Scholar
Hassan, M.M., Schiermeister, L., Staiger, M.P. (2015) Sustainable Production of Carbon Fiber: Effect of Crosslinking in Wool Fiber on Carbon Yields and Morphologies of Derived Carbon Fiber. ACS Sustainable Chem. Eng. 311:26602668.CrossRefGoogle Scholar
Hassan, M.M., Schiermeister, L., Staiger, M.P. (2015) Thermal, chemical and morphological properties of carbon fibers derived from chemically pre-treated wool fibers. RSC Advances, 5: 5535355362.CrossRefGoogle Scholar
Gao, Q., Liu, H., Cheng, C., Li, K., Zhang, J., Zhang, C., Li, Y. (2013) Preparation and characterization of activated carbon from wool waste and the comparison of muffle furnace and microwave heating methods. Powder Technology, 249: 234240.CrossRefGoogle Scholar
Chen, W., Liu, X., He, R.L., Lin, T., Zeng, Q.F., Wang, X.G. (2013) Activated carbon powders from wool fibers. Powder Technology 234:7683.CrossRefGoogle Scholar
Dubinin, M. M. (1979) Characterization of Porous Solids. London: The Society of Chemical Industry.Google Scholar
Kim, N., Bhattacharyya, D. (2016) Development of fire resistant wool polymer composites: mechanical performance and fire simulation with design perspectives. Materials and Design, 106:391403.CrossRefGoogle Scholar
Monier, M., Nawar, N., Abdel-Latif, D. (2012) Preparation and characterization of chelating fibers based on natural wool for removal of Hg(II), Cu(II) and Co(II) metal ions from aqueous solutions. Journal of Hazardous Materials, 184(1-3): 118–25.CrossRefGoogle Scholar
Xu, W., Ke, G., Wu, J., Wang, X. (2006) Modification of wool fiber using steam explosion. European Polymer Journal 42:21682173.CrossRefGoogle Scholar
Baldan, M.R., Almeida, E.C., Azevedo, A.F, Goncalves, E.S., Rezende, M.C., Ferreira, N.G. (2007) Raman validity for crystallite size La determination on reticulated vitreous carbon with different graphitization index. Applied Surface Science 254: 600603.CrossRefGoogle Scholar
Brunauer, S., Emmett, P., Teller, E. (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc. 60:309319CrossRefGoogle Scholar
Rouquerol, J., Rouquerol, F., Llewellyn, P., Maurin, G., Sing, K.S.W. (2013) Adsorption by Powders and Porous Solids: Principle, Methodology and Applications. 2nd Edition, Academic Press, New York.Google Scholar
Farnam, M, Mukhtar, H., Shariff, A. (2016) Analysis of the influence of CMS variable percentages on pure PES membrane gas separation performance. Procedia Engineering 148:12061212.CrossRefGoogle Scholar
Aroua, M.K., WanDaud, W.A., Yin, C.A., Adinata, D. (2008) Adsorption Capacities of Carbon Dioxide, Oxygen, Nitrogen and Methane on Carbon Molecular Basket Derived from Polyethyleneimine Impregnation on Microporous Palm Shell Activated Carbon. Separation and Purification Technology 62:609613.CrossRefGoogle Scholar