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Visible Light Photodiodes and Photovoltages from Detonation Nanodiamonds

Published online by Cambridge University Press:  09 February 2016

Bohuslav Rezek ,
Stepan Stehlik ,
Alexander Kromka ,
Jean-Charles Arnault ,
Martin Weis  and
Jan Jakabovic
Bohuslav Rezek*
Affiliation:
Institute of Physics ASCR, Cukrovarnicka10, Prague 6, Czech Republic Faculty of Electrical Engineering, Czech Technical University, Technicka 2, Prague 6, Czech Republic
Stepan Stehlik
Affiliation:
Institute of Physics ASCR, Cukrovarnicka10, Prague 6, Czech Republic
Alexander Kromka
Affiliation:
Institute of Physics ASCR, Cukrovarnicka10, Prague 6, Czech Republic
Jean-Charles Arnault
Affiliation:
Diamond Sensors Laboratory, CEA LIST, F-91191 Gif sur Yvette, France
Martin Weis
Affiliation:
Institute of Electronics and Photonics, Slovak University of Technology, Ilkovičova 3, Bratislava, Slovakia
Jan Jakabovic
Affiliation:
Institute of Electronics and Photonics, Slovak University of Technology, Ilkovičova 3, Bratislava, Slovakia
*
*(Email: rezek@fzu.cz)
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Abstract

Macroscopic and microscopic photovoltage characteristics of detonation nanodiamonds (DNDs) with distinct surface terminations are presented. Organic photodiodes are fabricated based on P3HT+DNDs mixture (50 wt%). We compare effect of hydrogen and oxygen termination of DNDs. Compared to photodiodes without DNDs the current-voltage characteristics of photodiodes with O-DNDs in dark and under AM 1.5 illumination show reduced dark current, and higher photocurrent and open circuit voltage. H-DNDs shunt the photodiodes, which is attributed to their surface conductivity. Kelvin probe force microscopy detects a reproducible photovoltage of around 5 mV generated by a green laser (532 nm) on both types of pristine DNDs. Thus although conductivity of H-DNDs may represent a problem for photodiodes, both types of DNDs alone can function as miniature energy conversion devices.

Keywords

diamondnanostructurephotovoltaic
Type
Articles
Information
MRS Advances , Volume 1 , Issue 14: Energy and Sustainability , 2016 , pp. 971 - 975
Copyright
Copyright © Materials Research Society 2016 

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References

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