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Ionic-Liquid-Based Polyurethane Dispersions for Stabilizing Graphene in Water

Published online by Cambridge University Press:  19 August 2019

Harshit Gupta  and
John Texter Open the ORCID record for John Texter [Opens in a new window]
Harshit Gupta
Affiliation:
Coatings Research Institute, School of Engineering, Eastern Michigan University, Ypsilanti, MI 48197, USA
John Texter*
Affiliation:
Coatings Research Institute, School of Engineering, Eastern Michigan University, Ypsilanti, MI 48197, USA
*
*(Email: jtexter@emich.edu)
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Abstract

Aqueous auto-dispersing polyurethane dispersions (PUDs) have recently been reported to form nanoparticulate dispersions at up to 25% by weight. Their incorporation of an ionic-liquid (IL) monomer, 1-hydroxyundecyl-3-methyl imidazolium bromide (HOC11C1ImBr) as a chain-terminating group appears to account for their auto-dispersing ability, and these PUD nanoparticles bear similarity to IL-based nanolatexes that have provided thermodynamically stable aqueous dispersions of nanocarbons. We demonstrate that these HOC11C1ImBr-based PUDs stabilize aqueous graphene dispersions at 1% by weight graphene in ultrasonicated top-down liquid phase exfoliation. Their formation quantitatively follows an analytical model of exfoliation kinetics of layered materials and a stretched exponential kinetic model. Such dispersions are ideally formulated for making nanocomposites composed of similar or compatible PUDs and other condensation polymers.

Keywords

grapheneintercalationoptical propertiesphase transformation
Type
Articles
Information
MRS Advances , Volume 4 , Issue 41-42: Electronics and Photonics , 2019 , pp. 2289 - 2298
Copyright
Copyright © Materials Research Society 2019 

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Footnotes

§

Present Address: Axalta Coating Systems, Global Innovation Center, 1050 Constitution Avenue, Philadelphia, PA 19112, USA

References

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