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Porous Carbon/CeO2 Nanoparticles Hybrid Material for High-Capacity Super-Capacitors

Published online by Cambridge University Press:  13 June 2017

Hoejin Kim ,
Mohammad Arif Ishtiaque Shuvo ,
Hasanul Karim ,
Manjula I Nandasiri ,
Ashleigh M Schwarz ,
Murugesan Vijayakumar ,
Juan C. Noveron ,
Tzu-liang Tseng  and
Yirong Lin
Hoejin Kim*
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
Mohammad Arif Ishtiaque Shuvo
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
Hasanul Karim
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
Manjula I Nandasiri
Affiliation:
Pacific Northwest National Laboratory, Richland, WA 99352, USA
Ashleigh M Schwarz
Affiliation:
Pacific Northwest National Laboratory, Richland, WA 99352, USA
Murugesan Vijayakumar
Affiliation:
Pacific Northwest National Laboratory, Richland, WA 99352, USA
Juan C. Noveron
Affiliation:
Department of Chemistry, University of Texas at El Paso, El Paso, TX 79968, USA.
Tzu-liang Tseng
Affiliation:
Department of Industrial, Systems, and Manufacturing, University of Texas at El Paso, El Paso, TX 79968, USA.
Yirong Lin
Affiliation:
Department of Mechanical Engineering, University of Texas at El Paso, El Paso, TX 79968, USA.
*
*(Email: hkim4@miners.utep.edu)
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Abstract

The increasing demand for energy storage devices has propelled research for developing efficient super-capacitors (SC) with long cycle life and ultrahigh energy density. Carbon-based materials are commonly used as electrode materials for SC. Herein, we report a new approach to improve the SC performance utilizing a Porous Carbon/Cerium Oxide nanoparticle (PC-CON) hybrid as electrode material synthesized via a low temperature hydrothermal method. Through this approach, charges can be stored not only via electrochemical double layer capacitance (EDLC) from PC but also through pseudo-capacitive effect from CeO2 nanoparticles (NPs). The electrode-electrolyte interaction due to the electrochemical properties of the electrolyte provides an enhanced voltage window for the SC. Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), and X-Ray Diffraction (XRD) measurements were used for the characterization of this PC/CeO2 hybrid material system. The testing results have shown that a maximum of 500% higher specific capacitance could be obtained using PC/CeO2 instead of using PC only.

Keywords

transmission electron microscopy (TEM)thermogravimetric analysis (TGA)scanning electron microscopy (SEM)
Type
Articles
Information
MRS Advances , Volume 2 , Issue 46: Soft Materials and Biomaterials , 2017 , pp. 2471 - 2480
Copyright
Copyright © Materials Research Society 2017 

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